Listar Dpto. Química Aplicada - Kimika Aplikatua Saila por fecha de publicación
Mostrando ítems 1-20 de 38
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Development of Ni/Lahexaaluminates from aluminum saline slags applied as catalysts in the dry reforming of methane
(2021) Tesis doctoral / Doktoretza tesiaThe general objective of this work is to study the synthesis methods, structural and morphological behavior of hexaaluminates and their performance as catalysts in the dry reforming reaction of methane from aluminum salt ... -
α-Hydroxy ketones as masked ester donors in Brønsted base catalyzed conjugate additions to nitroalkenes
The catalyst-controlled enantioselective direct addition reaction of enolizable esters and related carboxylic acid derivatives to p electrophiles remains a difficult synthetic transformation. In this study, the suitability ... -
Kinetics of the acid-catalyzed hydrolysis of tetraethoxysilane (TEOS) by 29Si NMR spectroscopy and mathematical modeling
Tetraethoxysilane (TEOS) is widely used to synthesize siliceous material by the sol–gel process. However, there is still some disagreement about the nature of the limiting step in the hydrolysis and condensation reactions. ... -
Outstanding performance of rehydrated Mg-Al hydrotalcites as heterogeneous methanolysis catalysts for the synthesis of biodiesel
There is still a need for active, selective and stable heterogeneous catalysts for the synthesis of biodiesel. In this work, magnesium-aluminium hydrotalcites with Mg/Al molar ratios within the 1.5–5 range were synthesized ... -
Estrategias del alumnado de Educación Secundaria para estimar la densidad
La densidad, o concentración de materia, es un concepto muy relevante pero que genera muchas dificultades de comprensión. Para medir la competencia en la estimación de la densidad del alumnado de la ESO, se pasó un ... -
Synthesis of zeolite a from metakaolin and its application in the adsorption of cationic dyes
The present work reports the synthesis of zeolites from two metakaolins, one derived from the white kaolin and the other derived from the red kaolin, found in a deposit in the city of São Simão (Brazil). The metakaolins ... -
Desarrollo de catalizadores de cobalto y rodio para la producción de gas de síntesis por oxidación parcial de metano
Los procesos Gas-to-Liquid (GTL), basados en la transformación de gas natural en hidrocarburos sintéticos, son de gran interés para la valorización de los nuevos recursos que emergen actualmente fruto de la aparición de ... -
Microwave-assisted pillaring of a montmorillonite with al-polycations in concentrated media
A montmorillonite has been intercalated with Al3+ polycations, using concentrated solutions and clay mineral dispersions. The reaction has been assisted by microwave radiation, yielding new intercalated solids and leading ... -
Application of eco-design and life cycle assessment standards for environmental impact reduction of an industrial product
Eco-design is included within the framework of the standard for “Environmental management systems—Guidelines for incorporating Eco-design” (ISO 14006:2011). Eco-design process, as defined in standard, has six steps: (i) ... -
Preparation of Al/Fe-pillared clays: effect of the starting mineral
Four natural clays were modified with mixed polyoxocations of Al/Fe for evaluating the effect of the physicochemical properties of the starting materials (chemical composition, abundance of expandable clay phases, cationic ... -
Therapeutic applications of rose hips from different rosa species
Rosa species, rose hips, are widespread wild plants that have been traditionally used as medicinal compounds for the treatment of a wide variety of diseases. The therapeutic potential of these plants is based on its ... -
Materiales funcionales imprimibles para aplicaciones electrónicas
Las técnicas de impresión inkjet presentan un gran potencial en el sector de la electrónica impresa, ya que permiten el depósito de materiales funcionales sobre sustratos de diferente naturaleza permitiendo fabricar ... -
Reacciones de acoplamiento C-C activadas por nanopartículas y carbenos de paladio generados desde sales de piridina-imidazolio
Esta memoria aborda el estudio profundo de nuevos catalizadores activos en las reacciones de acoplamiento basados en complejos de Pd(II) con ligandos derivados de 1-(2-piridil)imidazol-2-ilideno y de nanopartículas de Pd(0) ... -
Fiber optic sensors based on hybrid phenyl-silica xerogel films to detect n-hexane: determination of the isosteric enthalpy of adsorption
We investigated the response of three fiber optic sensing elements prepared at pH 10 from phenyltriethoxysilane (PhTEOS) and tetraethylsilane (TEOS) mixtures with 30, 40, and 50% PhTEOS in the silicon precursor mixture. ... -
Catalytic hydroprocessing of lignin β-O-4 ether bond model compound phenethyl phenyl ether over ruthenium catalysts
The catalytic hydroprocessing of phenethyl phenyl ether (PPE), a model compound of one of the most significant ether linkages within lignin structure, β-O-4, has been studied. Reactions were carried out using two ruthenium-based ... -
Kinetic analysis and CFD simulations of the photocatalytic production of hydrogen in silicone microreactors from water-ethanol mixtures
Silicone microreactors containing microchannels of 500 μm width in a single or triple stack configuration have been manufactured, coated with an Au/TiO2 photocatalyst and tested for the photocatalytic production of hydrogen ... -
Rutas y retos para la valorización de biogás
Las tecnologías de digestión anaerobia para procesar corrientes residuales (fracción orgánica de residuos de vertedero, lodos de estaciones depuradoras de aguas residuales, purines, etc.) han originado un incremento de ... -
Asymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalent
An efficient, highly diastereo- and enantioselective assembly of acyclic carbonyl fragments possessing nonadjacent all-carbon tertiary/quaternary stereoarrays is reported based on a Brønsted base catalyzed Michael ... -
Rosa canina extracts have antiproliferative and antioxidant effects on caco-2 human colon cancer
The in vitro antiproliferative and antioxidant effects of different fractions of Rosa canina hips on human colon cancer cell lines (Caco-2) was studied. The compounds tested were total extract (fraction 1), vitamin C ... -
Eliminación y valorización de CO₂ presente en efluentes gaseosos mediante adsorción y reformado seco de metano
El objetivo general de esta tesis doctoral ha sido la realización de un estudio en adsorción de CO₂ y su utilización en la reacción de reformado de metano como investigación base en las estrategias de eliminación y ...