Open Access
Effect of Cu substitution on the magnetic and magnetic induction heating response of CdFe₂O₄ spinel ferrite
(Elsevier, 2020) Ghasemi, R.; Echeverría Morrás, Jesús; Pérez de Landazábal Berganzo, José Ignacio; Beato López, Juan Jesús; Naseri, M.; Gómez Polo, Cristina; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias
In this work, a comparative study of the effect of Cu on the structural, magnetic and magnetic induction heating response in CdFe2O4 spinel is presented. The ceramic nanoparticles (Cu1−xCdxFe2O4; 0 ≤ x ≤ 1) were synthesized by co-precipitation from Cu(II), Cd(II) and Fe(III) salts. The samples, characterized by X-ray diffractometry, display the characteristic spinel cubic structure (space group Fm3m) where CdO is detected as main secondary phase (≈ 16% weight for x = 1). A high degree of nanoparticle agglomeration is inferred from the Transmission Electron Microscopy (TEM) images, as a consequence of the employed synthesis procedure. Regarding the magnetic properties, superparamagnetic behavior at room temperature can be disregarded according to the low field magnetization response (ZFC-FC curves). For 0.4 ≤ x ≤ 0.8 ratios, the samples display maximum values in the magnetic moment that should be correlated to the cation distribution between the octahedral and tetrahedral sites. Maximum magnetization values lead to an enhancement in the magnetic induction heating response characterized by highest heating temperatures under the action of an ac magnetic field. In particular, maximum SAR values are estimated for x = 0.8 as a combined effect of high magnetic moment, low dc coercive field (high susceptibility). Although these Cu-Cd ferrite nanoparticles display moderate SAR values (around 0.7 W/g), the control of the maximum heating temperatures through the cation distribution (composition) provides promising properties to be used as nanosized heating elements (i.e. hyperthermia agents).
Open Access
Giant direct and inverse magnetocaloric effect linked to the same forward martensitic transformation
(Springer Nature, 2017) Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Sánchez-Alarcos Gómez, Vicente; Beato López, Juan Jesús; Rodríguez Velamazán, José Alberto; Sánchez Marcos, J.; Gómez Polo, Cristina; Cesari, Eduard; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física
Metamagnetic shape memory alloys have aroused considerable attraction as potential magnetic refrigerants due to the large inverse magnetocaloric effect associated to the magnetic-field-induction of a reverse martensitic transformation (martensite to austenite). In some of these alloys, the austenite phase can be retained on cooling under high magnetic fields, being the retained phase metastable after field removing. Here, we report a giant direct magnetocaloric effect linked to the anomalous forward martensitic transformation (austenite to martensite) that the retained austenite undergoes on heating. Under moderate fields of 10 kOe, an estimated adiabatic temperature change of 9 K has been obtained, which is (in absolute value) almost twice that obtained in the conventional transformation under higher applied fields. The observation of a different sign on the temperature change associated to the same austenite to martensite transformation depending on whether it occurs on heating (retained) or on cooling is attributed to the predominance of the magnetic or the vibrational entropy terms, respectively.
Open Access
Magnetic transition in nanocrystalline soft magnetic alloys analyzed via ac inductive techniques
(American Physical Society, 2004) Gómez Polo, Cristina; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Vázquez, M.; Hernando, A.; Física; Fisika; Gobierno de Navarra / Nafarroako Gobernua
The magnetic transition in a FeSiBCuNb nanocrystalline alloy, associated with the decoupling of ferromagnetic crystallites around the Curie point of the residual amorphous matrix, is analyzed in this work through the temperature dependence of the ac axial magnetic permeability and impedance of the samples. The temperature dependence of both complex magnitudes presents a maximum in the irreversible contribution at a certain transition temperature. While for low values of the exciting ac magnetic field the transition temperature lies below the Curie temperature of the amorphous phase, a shift above this Curie point is observed increasing the amplitude of the applied ac magnetic field. The detected field dependence is interpreted taking into account the ac nature of the inductive characterization techniques and the actual temperature dependence of the coercivity of the samples.
Open Access
Tailoring the structural and magnetic properties of Co-Zn nanosized ferrites for hyperthermia applications
(Elsevier, 2018) Gómez Polo, Cristina; Recarte Callado, Vicente; Cervera Gabalda, Laura María; Beato López, Juan Jesús; López García, Javier; Rodríguez Velamazán, José Alberto; Ugarte Martínez, María Dolores; Mendonça, E. C.; Duque, J. G. S.; Zientziak; Estatistika, Informatika eta Matematika; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Estadística, Informática y Matemáticas; Gobierno de Navarra / Nafarroako Gobernua
A comparative study of the magnetic properties (magnetic moment, magnetocrystalline anisotropy) and hyperthermia response in Co-Zn spinel nanoparticles is presented. The CoxZn1-xFe2O4 nanoparticles (x = 1, 0.5, 0.4, 0.3, 0.2 and 0.1) were synthesized by co-precipitated method and the morphology and mean crystallite size (around 10 nm) of the nanoparticles were analysed by TEM Microscopy. Regarding the magnetic characterization (SQUID magnetometry), Co-Zn nanoparticles display at room temperature anhysteretic magnetization curves, characteristic of the superparamagnetic behavior. A decrease in the blocking temperature, T-B, with Zn content is experimentally detected that can be ascribed to the reduction in the mean nanoparticle size as x decreases. Furthermore, the reduction in the magnetocrystalline anisotropy with Zn inclusion is confirmed through the analysis of TB versus the mean volume of the nanoparticles and the law of approach to saturation. Maximum magnetization is achieved for x = 0.5 as a result of the cation distribution between octahedral and tetrahedral spinel sites, analysed by neutron diffraction studies. The occurrence of a canted spin arrangement (Yafet-Kittel angle) is introduced to properly fit the magnetic spinel structures. Finally, the heating capacity of these spinel ferrites is analyzed under ac magnetic field (magnetic hyperthermia). Maximum SAR (Specific Absorption Rate) values are achieved for x = 0.5 that should be correlated to the maximum magnetic moment of this composition.
Open Access
A comprehensive analysis of the absorption spectrum of conducting ferromagnetic wires
(IEEE, 2012) Liberal Olleta, Íñigo; Ederra Urzainqui, Íñigo; Gómez Polo, Cristina; Labrador Otamendi, Alberto; Pérez de Landazábal Berganzo, José Ignacio; Gonzalo García, Ramón; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Física; Fisika
A detailed analysis of the absorption spectrum of conductive ferromagnetic wires is presented. The absorption spectrum is computed from the solution to the scattering problem, and circuit models are formulated to clarify the interplay between losses, skin-effect and wire geometry. Both infinitely-long wires and the axial resonances introduced by finite-length wires are considered. The theoretical results are validated experimentally through measurements within a metallic rectangular waveguide.
Open Access
Thrust actuator with passive restoration force for wide gap magnetic bearings
(Elsevier, 2019) Royo Silvestre, Isaac; Beato López, Juan Jesús; Castellano Aldave, Jesús Carlos; Gómez Polo, Cristina; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias
Active thrust magnetic bearings provide an axial force to balance the moving parts of machines. However, most devices produce null or unbalancing passive forces. Furthermore, reported designs usually feature very small axial and radial gaps. This paper presents a thrust actuator for wide axial gaps that produces both passive and active restoring axial forces. It features a long biconical rotor and a stator housing a single winding and two permanent magnets. Simulations are done using finite-element-analysis (FEA) and compared to magnetic circuit analysis and experimental results from a prototype with a diameter of 48 mm and 20 mm axial displacement.
Open Access
Giant stress impedance magnetoelastic sensors employing soft magnetic amorphous ribbons
(MDPI, 2020) Beato López, Juan Jesús; Urdaniz Villanueva, Juan Garikoitz; Pérez de Landazábal Berganzo, José Ignacio; Gómez Polo, Cristina; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Gobierno de Navarra / Nafarroako Gobernua, VITICS, IIM14244.RI1
Soft magnetic amorphous alloys obtained via rapid quenching techniques are widely employed in different technological fields such as magnetic field detection, bio labeling, non-contact positioning, etc. Among them, magnetoelastic applications stand out due to excellent mechanical properties exhibited by these alloys, resulting from their amorphous structure, namely, their high Young modulus and high tensile strength. In particular, the giant stress impedance (GSI) effect represents a powerful tool to develop highly sensitive magnetoelastic sensors. This effect is based on the changes in the high-frequency electric impedance as the result of the variation in magnetic permeability of the sample under the action of mechanical stresses. In this work, the GSI effect is analyzed in two soft magnetic ribbons ((Co0.93 Fe0.07)75 Si12.5 B12.5 and (Co0.95 Fe0.05)75 Si12.5 B12.5) for the subsequent development of two practical devices: (i) the characterization of the variations in the cross-section dimensions of irregularly shaped elements, and (ii) the design of a flow meter for measuring the rate of flow of water through a pipe.
Open Access
Fe-C nanoparticles obtained from thermal decomposition employing sugars as reducing agents
(Elsevier, 2020) Cervera Gabalda, Laura María; Pérez de Landazábal Berganzo, José Ignacio; Garayo Urabayen, Eneko; Monteserín, María; Larumbe Abuin, Silvia; Martín, F.; Gómez Polo, Cristina; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The aim of the work is to present a comparative analysis (structural and magnetic) of Fe-C nanocomposites obtained by the thermal decomposition of sugars (fructose, glucose and sucrose) employing FeCl3 as Fe3+ precursor. The thermal decomposition was followed through Thermogravimetry (TGA) and Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction, High Resolution Transmission Electron Microscopy (HRTEM) and Raman spectroscopy. The results indicate the reduction of Fe3+ under the performed thermal treatments and the achievement at high annealing temperatures of Fe-C nanostructures (coexistence of α-Fe and Fe3C nanoparticles surrounded by a carbon matrix). The magnetic characterization performed by dc SQUID magnetometry, shows an antiferromagnetic response in the initial stages of the decomposition process, and a ferromagnetic behavior linked to the Fe-based nanoparticles. The magnetic induction heating was analyzed through the ac hysteresis loops. Moderate Specific Absorption Rate (SAR) is obtained in Fe-C nanoparticles (~ 70 W/gFe), ascribed to the large nanoparticle size. The combination of porous carbon structure and ferromagnetic response of the Fe-C nanoparticles (i.e. local temperature increase under ac magnetic field) enlarge the emerging applications of these carbonaceous nanocomposites.
Open Access
Theoretical modeling and experimental verification of the scattering from a ferromagnetic microwire
(IEEE, 2011) Liberal Olleta, Íñigo; Ederra Urzainqui, Íñigo; Gómez Polo, Cristina; Labrador Otamendi, Alberto; Pérez de Landazábal Berganzo, José Ignacio; Gonzalo García, Ramón; Física; Fisika; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa
This contribution presents a theoretical modelling of the scattering of ferromagnetic microwires in free-space and inside a rectangular waveguide, providing both an analytical solution and a physical interpretation of the problem. Special attention is devoted to the impact of the microwire radius and its magnetic properties. Theoretical results have been experimentally verified measuring the reflection, absorption and transmission coefficients of a ferromagnetic microwire inside a rectangular waveguide.
Open Access
A combination of a vibrational electromagnetic energy harvester and a giant magnetoimpedance (GMI) sensor
(MDPI, 2020) Beato López, Juan Jesús; Royo Silvestre, Isaac; Algueta-Miguel, Jose M.; Gómez Polo, Cristina; Zientziak; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Ciencias; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
An energy harvesting device combined with a giant magnetoimpedance (GMI) sensor is presented to analyze low frequency vibrating systems. An electromagnetic harvester based on magnetic levitation is proposed for the electric power generation. The device is composed of two fixed permanent magnets at both ends of a cylindrical frame, a levitating magnet acting as inertial mass and a pick-up coil to collect the induced electromotive force. At the resonance frequency (10 Hz) a maximum electrical power of 1.4 mW at 0.5 g is generated. Moreover, an amorphous wire was employed as sensor nucleus for the design of a linear accelerometer prototype. The sensor is based on the GMI effect where the impedance changes occur as a consequence of the variations of the effective magnetic field due to an oscillating magnetic element. As a result of the magnet’s periodic motion, an amplitude modulated signal (AM) was obtained, its amplitude being proportional to mechanical vibration amplitude (or acceleration). The sensor’s response was examined for a simple ferrite magnet under vibration and compared with that obtained for the vibrational energy harvester. As a result of the small amplitudes of vibration, a linear sensor response was obtained that could be employed in the design of low cost and simple accelerometers.