Open Access
Annual energy performance of a thermoelectric heat pump combined with a heat recovery unit to HVAC one passive house dwelling
(Elsevier, 2022) Díaz de Garayo, Sergio; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
This paper proposes a HVAC system that integrates a thermoelectric heat pump with a double flux ventilation system and a sensible heat recovery unit able to provide heating, cooling and ventilation to a 74.3 m2 Passive House certified dwelling in Pamplona (Spain). This study computationally investigates the energy performance of the system and the comfort conditions of the dwelling for one year long. The thermoelectric HVAC system maintains adequate comfort conditions with an indoor temperature between 20–23 °C in wintertime and 23–25 °C during summer, thanks to the precise control of the voltage supplied to the thermoelectric heat pump that can regulate the heating/cooling capacity from 5 to 100 %. The system consumes 1143.3 kWh/y (15.3 kWh/m2y) of electric energy, that can be provided by 4 photovoltaic panels of 250 Wp each. This system is then compared with a vapor compression heat pump with a COP of 4.5. The vapor compression system reduces the electric energy consumption by 36.1 % with respect to the thermoelectric system, which allows saving only 270 Wp (1–2 PV panels). This demonstrates the promising application of thermoelectricity for HVAC in passive houses.
Open Access
Impact of a thermoelectric subcooler heat exchanger on a carbon dioxide transcritical refrigeration facility
(Elsevier, 2022) Casi Satrústegui, Álvaro; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Alegría Cía, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsita
To improve the performance of vapour compression refrigeration cycles, the inclusion of a thermoelectric subcooler for low-medium power units has been the focus of recent studies due to its robustness, compactness and simplicity of operation. In thermoelectric systems, it has been demonstrated that the heat exchangers used in the hot and cold side of the thermoelectric modules have a critical impact in the performance of the system. This influence has not yet been studied for thermoelectric subcooling systems in vapour compression cycles. This work, for the first time, evaluates the impact that the heat exchangers of a thermoelectric subcooler, included in a transcritical carbon dioxide refrigeration cycle, have, in the performance of the refrigeration cycle. The influence is quantified in terms of: optimum working conditions, coefficient of performance and cooling capacity. The results show that, through an optimization of the heat exchangers of the thermoelectric subcooler, the performance improvements on the coefficient of performance using this technology are boosted from 11.96 to 14.75 % and the upgrade in the cooling capacity of the system rises from 21.4 to 26.3 %. Moreover, the optimum gas-cooler working pressure of the system is reduced and the optimum voltage supplied to the thermoelectric modules increases.
Open Access
Design and optimization of thermoelectric generators for harnessing geothermal anomalies: a computational model and validation with experimental field results
(Elsevier, 2024) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Erro Iturralde, Irantzu; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Thermoelectric generators have been recently proved to be a feasible alternative to harness hot dry rock fields with very promising results transforming the geothermal heat into electricity. This research deepens in the study of these generators, developing a versatile computational model that serves as a tool to design and optimize this type of thermoelectric generators. This tool is important to develop this thermoelectric technology on a large scale, to produce clean and renewable electrical energy especially in the Timanfaya National Park, in Lanzarote (Spain), where some of the most important shallow geothermal anomalies in the world are located, in order to promote self-consumption in this zone. However, it could be employed in other areas with different boundary conditions. The model, based in the finite difference method applied to the thermal-electrical analogy of a geothermal thermoelectric generator, has been validated with the experimental field results of two thermoelectric generators installed in two different zones of geothermal anomalies. It has achieved a relative error of less than 10% when predicting the power and between 0.5–1.6% in the annual energy generation, what makes it a very reliable and useful computational tool. The developed model has been employed for the first time to estimate the electrical energy that could be generated if harnessing the characterized area of anomalies in Lanzarote. Here, given the continuity of geothermal energy, 7.24 GWh per year could be generated, which means annually 1.03 MWh/m2.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(Elsevier, 2022) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Rodríguez García, Antonio; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Nowadays, geothermal energy in shallow hot dry rock fields is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. However, the efficiency of a thermoelectric generator depends highly on the heat exchangers. In this work, a novel geothermal thermoelectric generator is experimentally developed, characterizing different configurations of biphasic heat exchangers to obtain low thermal resistances that allow the maximum efficiency in the thermoelectric modules. As a result, robust and passive heat exchangers were obtained with thermal resistances of 0.07 K/W and 0.4 K/W in the hot and cold sides, respectively. The geothermal thermoelectric generator was built with the most effective heat exchangers and was experimented under different temperature and convection conditions, generating 36 W (17 W by a prototype with 10 modules and 19 W by a prototype with 6 modules) for a temperature difference of 160 °C between the heat source and the environment. Furthermore, the experimental development showed that it is possible to increase electricity generation with a more compact generator, since a decrease in the number of modules from 10 to 6 increases the efficiency from 3.72% to 4.06%. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Prospects of autonomous volcanic monitoring stations: experimental investigation on thermoelectric generation from fumaroles
(MDPI, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Padilla, Germán D.; Hernández, Pedro A.; Pérez, Nemesio M.; García de la Noceda, Celestino; Albert, José F.; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 °C. Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 °C. The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 °C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.
Open Access
Influence of temperature and aging on the thermal contact resistance in thermoelectric devices
(Springer, 2020) Rodríguez García, Antonio; Pérez Artieda, Miren Gurutze; Beisti Antoñanzas, Irene; Astrain Ulibarrena, David; Martínez Echeverri, Álvaro; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
During thermal design in the first phases development, thermoelectric systems, such as thermoelectric generators, the most important parameter affecting the performance is thermal resistance of the components. This paper focusses on the thermal contact resistance (TCR), analyzing the influence of aging and temperature on different thermal interface materials (TIMs), i.e., thermal paste, graphite and indium. In previous papers, TCR has been studied depending on parameters such as surface roughness, bonding pressure, thermal conductivity and surface hardness. However, in thermoelectric applications, a relevant aspect to consider when choosing a TIM is aging due to thermal stress. The exposure of this type of material to high temperatures for long periods of time leads to deterioration, which causes an increase in the TCR impairing the conduction of the heat flow. Therefore, there is a need to study the behavior of TIMs exposed to temperatures typical in thermoelectric generators to make a correct selection of the TIM. It has been observed that exposure to temperatures of around 180°C induces a significant increase in the thermal impedance of the three TIMs under study, although this effect is much more relevant for thermal paste. The contact, comprising steel, thermal paste and ceramic, presents a 300% increase in the thermal impedance after 70 days of aging, whereas that exceeds 185% for the contact of aluminum, thermal paste and ceramic. In the tests with exposure temperature of 60°C, there is no observed decrease in the thermal impedance.
Open Access
Experimental study of a multistage thermoelectric heat pump using different internal heat exchangers
(2021) Erro Iturralde, Irantzu; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniería; Institute of Smart Cities - ISC; Ingeniaritza
The current need to carry out an energy transition towards a 100 % renewable horizon places the energy storage as the key. Thermal energy storage has the potential to be an optimal technology. Nowadays electrical resistors are used to convert electrical energy to termal energy by heating an air flux which is stored afterwards. In this work, it is proposed to use a multistage thermoelectric heat pump (MS-TEHP) to do this energy conversion. It has been experimentally analyzed and compared the performance of two MS-TEHP with different internal heat exchangers. With this preliminary research, it has been demonstrated the feasibility of this novel thermoelectric technology which aim is to improve the energy conversión process for thermal energy storage.
Open Access
Design and analysis of a two-stage cascade system for heating and hot water production in nearly zero-energy buildings using thermoelectric technology
(MDPI, 2024-12-16) Ordóñez, Javier ; Díaz de Garayo, Sergio; Martínez Echeverri, Álvaro; Algarra Pérez, Fernando; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Gobierno de Navarra / Nafarroako Gobernua
This paper proposes an innovative system that integrates two thermoelectric heat pumps (one air–water and the other water–water) with two thermal storage tanks at different temperatures to provide heating and domestic hot water to a 73.3 m2 passive-house-certified dwelling in Pamplona (Spain). The air–water thermoelectric heat pump extracts heat from the ambient air and provides heat to a tank at intermediate temperature, which supplies water to a radiant floor. The water–water heat pump takes heat from this tank and provides heat to the other tank, at higher temperature, which supplies domestic hot water. The system performance and comfort conditions are computationally analyzed during the month of January under the climate of Pamplona and under different European climates. The COP of the system lays between 1.3 and 1.7, depending on the climate, because of the low COP of the air–water thermoelectric heat pump. However, it is able to provide water for the radiant floor and to maintain the temperature of the dwelling above 20 °C 99.8% of the time. Moreover, it provides domestic hot water at a temperature above 43 °C 99.9% of the time. Noteworthy is the fact that the water–water heat pump presents a COP close to 4, which opens up the possibilities of working in combination with more efficient heat pumps for the first stage.
Open Access
Experimental assessment of a thermoelectric subcooler included in a transcritical CO2 refrigeration plant
(Elsevier, 2021-05-25) Aranguren Garacochea, Patricia; Sánchez, Daniel; Casi Satrústegui, Álvaro; Cabello, Ramón; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
This study brings an experimental research that has tested a real transcritical CO2 vapor compression cycle that includes a thermoelectric subcooler at the exit of the gas-cooler of the refrigeration plant. The aforementioned technology hybridization increases the COP of refrigeration systems as long as the subcooling system is properly designed and operated. The experimental facility studied has been tested under constant ambient conditions (30 °C and relative humidity of 55%) and maintaining the evaporating temperature at -10 °C; while the voltage supplied to the thermoelectric modules and the thermal resistances of the heat exchangers located at the thermoelectric subcooler have been experimentally modified. The voltage supplied to the fans located at these heat exchangers was modified implying thermal performance deviation of the heat exchangers and a variation on the power consumption of the cooling facility. The results show an experimental increase on the COP of 11.3% while the cooling capacity increases a 15.3% when the thermoelectric modules are supplied with 2 V and the fans with 9 V. Moreover, the importance of optimizing the voltage supplied to the thermoelectric modules and to the auxiliary consumption of the thermoelectric subcooler is addressed along this research.
Open Access
Thermoelectric generator for high temperature geothermal anomalies: experimental development and field operation
(Elsevier, 2023) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In the current climate and energy context, it is important to develop technologies that permit increase the use of renewable sources such as geothermal energy. Enhancing the use of this renewable source is particularly important in some places, due to its availability and the enormous dependence on fossil fuels, as is the case of the Canary Islands. This work proposes the use of thermoelectric generators with heat exchangers working by phase change to transform the heat from the shallow high temperature geothermal anomalies on the island of Lanzarote directly into electricity, since the use of conventional geothermal power plants would not be possible because they would damage the protected environment. To bring this proposal to reality, this work has succeeded in developing and field-installing a geothermal thermoelectric generator that operates without moving parts thanks to its phase-change heat exchangers. This robust generator do not require maintenance nor auxiliary consumption, and produces a minimal environmental impact, it is noiseless, and the use of water as working fluid makes it completely harmless. The developed device consists of a thermosyphon as hot side heat exchanger, thermoelectric modules and cold side heat exchangers also based in phase change. Tests were carried out in the laboratory at various heat source temperatures and varying the number of thermoelectric modules. It was determined that installing more modules decreases the efficiency per module (from 4.83% with 4 modules to 4.59% with 8 modules at a temperature difference between sources of 235 °C), but for the number of modules tested the total power increases, so the field installation was carried out with 8 modules. After the good results in the laboratory, it was satisfactorily installed at Timanfaya National Park (Lanzarote, Spain) in a borehole with gases at 465 °C. This generator presents a maximum output power of 36 W (4.5 W per module), and is generating 286.94 kWh per year, demonstrating the great potential of the developed thermoelectric generators to build a larger-scale renewable installation.