Liberal Olleta, Íñigo
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Liberal Olleta
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Íñigo
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Ingeniería Eléctrica, Electrónica y de Comunicación
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ISC. Institute of Smart Cities
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Publication Open Access Radiative cooling properties of portlandite and tobermorite: two cementitious minerals of great relevance in concrete science and technology(American Chemical Society, 2023-06-23) Dolado, Jorge S.; Goracci, Guido; Arrese-Igor, Silvia; Ayuela, Andrés; Torres Betancourt, Angie Tatiana; Liberal Olleta, Íñigo; Beruete Díaz, Miguel; Gaitero, Juan J.; Cagnoni, Matteo; Cappelluti, Federica; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISCAlthough concrete and cement-based materials are the most engineered materials employed by mankind, their potential for use in daytime radiative cooling applications has yet to be fully explored. Due to its complex structure, which is composed of multiple phases and textural details, fine-tuning of concrete is impossible without first analyzing its most important ingredients. Here, the radiative cooling properties of Portlandite (Ca(OH)2) and Tobermorite (Ca5Si6O16(OH)2·4H2O) are studied due to their crucial relevance in cement and concrete science and technology. Our findings demonstrate that, in contrast to concrete (which is a strong infrared emitter but a poor sun reflector), both Portlandite and Tobermorite exhibit good radiative cooling capabilities. These results provide solid evidence that, with the correct optimization of composition and porosity, concrete can be transformed into a material suitable for daytime radiative cooling.Publication Open Access Enhancing the infrared and visible emission properties of calcium silicate hydrate for radiative cooling using metamaterials(IEEE, 2022) Lezaun Capdevila, Carlos; Dolado, Jorge S.; Torres García, Alicia E.; Pérez Escudero, José Manuel; Liberal Olleta, Íñigo; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio IngeniaritzarenTwo periodic structures composed of metal cylinders with different orientations are used to improve the solar reflection of calcium silicate hydrate (CSH) while maintaining its atmospheric emission. Interesting effects have been found when the distance between bars is small, suggesting that lattice effects, arising from the interaction between the rods could be leveraged in the design of these metamaterials. The size of the metal bars is selected based on state of the art micro-manufacturing techniques. This study limits its scope to a CSH gel model; i.e. the most important component of cement-based materials. Further research will be undertaken to consider a best description of the dielectric function of concrete.