Open Access
Technical and environmental characterization of hydraulic and alkaline binders
(Elsevier, 2018) Espuelas Zuazu, Sandra; Echeverria Lazcano, Angel María; Marcelino Sádaba, Sara; Prieto Cobo, Eduardo; Seco Meneses, Andrés; Proyectos e Ingeniería Rural; Landa Ingeniaritza eta Proiektuak; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2017-000176
Portland cement is a widely used binder in construction and building applications because of its good properties. Despite its convenience as construction material, the social demands and policies trends are requesting a lower impact and more sustainable cement manufacturing industry. The most effective ways to reach this goal are the substitution of clinker by different wastes or by-products in the cement composition or the development of more sustainable binders like the alkali activated binders. This work analyzes from a technical and environmental point of view the substitution of a clinker based CEM I common cement for the construction mortars manufacturing. Four common cements with different ground granulated blastfurnace slags (GGBS) or fly ashes (FA) contents as well as fifteen alkali activated binders (AAB) combinations were considered. Fresh consistency, density, compressive strength (CS) tests and life cycle analysis were carried out to state the ability of these different hydraulic and alkaline activated binders for the CEM I substitution. The results obtained demonstrated the technical and environmental convenience of these binders for the construction mortars manufacturing.
Open Access
Sulphate soil stabilisation with magnesium binders for road subgrade construction
(Taylor and Francis, 2020) Seco Meneses, Andrés; Espuelas Zuazu, Sandra; Marcelino Sádaba, Sara; García, Beñat; Del Castillo García, Jesús María; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua
This paper analyzes the ability of magnesium oxide-based additives to stabilise a low bearing gypsum marly soil, in order to reach subgrade requirements. This soil was not adequate for stabilisation with lime or cement because of its high sulphate content. Binders considered in this investigation were composed of three reactive Mg products and by products, both with and without ground granulated blast furnace slags (GGBS). They were compared to two cements and an aerial lime as soil stabilisers in a laboratory investigation and a field trial. Laboratory tests showed that Mg products with GGBS reached strength results close and at times even better than those of cement. One of the Mg products was the only additive able to reduce the natural soil swelling. Leaching tests demonstrated the ability of the Mg products to reduce the soil leaching of substances like calcium, magnesium, sulphate and chloride. In field trials two of the Mg products combined with GGBS met the bearing capacity requirements for subgrades, in accordance with the Spanish standard.
Open Access
Recycled granulates manufacturing from spent refractory wastes and magnesium based binder
(Elsevier, 2023) Seco Meneses, Andrés; Del Castillo García, Jesús María; Perlot, Céline; Marcelino Sádaba, Sara; Espuelas Zuazu, Sandra; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
This paper analyzes the ability of two Spent Refractory Wastes (SRW) for the manufacturing of recycled granulates for construction applications. A binary magnesium oxide and ground granulated blast furnace slag hydraulic binder was considered as an agglomerating agent for the granulates manufacturing. Influence of curing atmosphere was carried out: in air, 20 % CO2 and 100 % CO2 atmosphere up to 28 days. Granulometry, thermal analysis, particle density, bulk density, water absorption and mechanical strength tests were performed to characterize the granulates. SRW showed their ability for the granulates manufacturing. Results demonstrated the existence of a residual reactivity of the wastes considered. A direct relationship between the CO2 content of the curing atmosphere and the granulates hydration degree was observed. Carbonation process increased from 7 days to 28 days and direct relationships were observed between the CO2 content and the carbonation degree as well as between the binder dosage and the carbonation degree. CO2 curing reduced the water absorption and increased the compressive strength of the granulates.
Open Access
Evaluation of the potential of natural mining by-products as constituents of stabilized rammed earth building materials
(MDPI, 2025-05-06) Martín Antunes, Miguel Ángel; Perlot, Céline; Villanueva Roldán, Pedro; Abdallah, Rafik; Seco Meneses, Andrés; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In this investigation, different natural by-products were used to modify the Particle Size Distribution (PSD) of a soil to evaluate their potential in Stabilized Rammed Earth (SRE) building. Three different mixes were manufactured: (i) a mix composed entirely of a clayey soil, (ii) a mix consisting of mining by-products and clayey soil and (iii) a mix entirely based on mining by-products. Unstabilized and stabilized samples of the mixes were manufactured using two cement dosages (2.5% and 5%), and the samples were tested for Unconfined Compressive Strength (UCS), soaked UCS, and wetting and drying tests. Mining by-products demonstrated significant potential in SRE building, as their addition to the clayey soil resulted in higher UCS values compared to the UCS obtained from clayey soil alone. Unstabilized samples lost their integrity during exposure to water. The inclusion of mining by-products also showed potential as, although the mixes did not fully meet the requirements for soaked UCS and the wetting and drying tests, the mix containing both mining by-products and clayey soil retained its integrity in water, unlike the samples composed solely of clayey soil. M3C5 successfully met the requirements for soaked UCS and the wetting and drying tests, further highlighting the great potential of mining by-products in SRE building.
Open Access
Sustainable unﬁred bricks manufacturing from construction and demolition wastes
(Elsevier, 2018) Seco Meneses, Andrés; Omer, Joshua; Marcelino Sádaba, Sara; Espuelas Zuazu, Sandra; Prieto Cobo, Eduardo; Proyectos e Ingeniería Rural; Landa Ingeniaritza eta Proiektuak
The management of construction and demolition wastes is a huge challenge for most Governments. Thegreatest component of such wastes is concrete and masonry fragments or remains. Among the most com-mon approaches to valorization of such w astes is to convert them to recycled aggregates, however thismay be hampered by low quality of some recycled aggregates compared to natural aggregates. This paperpresents the results of experimental investigation where concrete and ceramic remains were used to par-tially substitute clay soil in producing unﬁred bricks. The bricks were then tested for mechanical strength,water absorption freeze-thaw resistance. Additionally the environmental impact of the bricks wasassessed based on Life Cycle Analysis (LCA). It was established that concrete waste could be used to sub-stitute up to 50% of the clay whereas ceramic wastes could only substitute a maximum of 30% of the clay.Blended bricks made from clay and concrete waste mixes had a lower mechanical strength than thosemade from clay and ceramic waste. As regards water absorption, there was no marked differencebetween the two blends of brick however reduction in water resistance was slightly greater in bricks con-taining concrete waste that in those containing ceramic wastes. Also, tests showed that freeze-thawresistance was greater in bricks blended with concrete wastes than in those incorporating ceramicwastes. Life Cycle analyses demonstrated that it is the binder content in the mix that largely determinesthe environmental impact of the blended bricks. Lastly, it was demonstrated that the most desirable tech-nical and environmental credentials of brick material mixes resulted from using the binder combination:CL-90-S+GGBS 2/8.
Embargo
Valorization of mining by-products for rammed Earth construction
(Springer, 2024-07-27) Martín Antunes, Miguel Ángel; Seco Meneses, Andrés; Perlot, Céline; McGregor, F.; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Mining and manufacturing produce large amounts of waste. One effective way for the valorization of many inert wastes or by-products from these industries is their use for the development of sustainable construction materials. This work analyzes the ability of different mix proportions of two by-products from mining, a mining clayed sludge, and a spent foundry sand, for the formulation of a by-products based rammed earth construction material. To achieve this objective an experimental laboratory campaign was developed. First, the physic-chemical properties of both by-products were measured, and the geotechnical properties of clayed sludge especially clay content and granulometry were evaluated. Then, these four by-product materials were combined to create three different combinations of soils with continuous granulometric curves, adequate for rammed earth construction, following the available literature. A Standard Proctor test was carried out to determine the optimum dry density and optimal water content of the mixes. Then, the mechanical strength was characterized by Unconfined Compressive Strength (UCS) tests. The proportions of the materials with higher bulk density show a direct relationship with the UCS values obtained. Water immersion was considered for the characterization of the durability of the developed material. During the durability test, the samples lost their integrity. This work shows the ability of these by-product mixes to produce even more sustainable rammed earth constructions with 100% of recycled constituents, achieving the mechanical strength requirement, not durability ones. Further investigations are required to improve this by-product made soil durability performance.
Open Access
Feasibility of vermicomposting of spent coffee grounds and silverskin from coffee industries: a laboratory study
(MDPI, 2020) González Moreno, Miguel Ángel; Marcelino Sádaba, Sara; Zaratiegui Urdin, Javier; Robles Domínguez, Estrella; Pérez Ezcurdia, Amaya; Seco Meneses, Andrés; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua, VERMICOMPOSTAJE 4.0-VERMIOT (0011-1365-2019-000110)
In the coffee industry, several by-products are generated during the production and consumption of coffee and represent an important waste from an environmental viewpoint. For improving the knowledge about this issue, a laboratory vermicomposting study of coffee silverskin (CS) and spent coffee grounds (SCG) spiked with mature horse manure (HM) in different proportions and using earthwormEisenia andreiwas carried out. The 60-day study focused on biological parameters such as total biomass gain, growth rate, cocoon production, and mortality. This study also investigated whether the vermicompost obtained could be useful and lacked toxicity through a seed germination test using hybrid wheat seeds. Results showed a disparity depending on the type of residue and the mixture used. Best options were those treatments with a medium-low amount of residue; 25% for SCG and 25% or 50% for CS. In addition, lack of toxicity was confirmed in all treatments. In conclusion, it is possible to carry out a vermicomposting of SCG and CS with some specific features.
Open Access
Valorization of insulation cellulose waste as solid biomass fuel
(MDPI, 2021) Espuelas Zuazu, Sandra; Marcelino Sádaba, Sara; García, Beñat; Seco Meneses, Andrés; Del Castillo García, Jesús María; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
This paper investigates the ability of insulation cellulose fiber powder (CFP) to be pelletized for its valorization as biomass fuel. CFP is a waste originating from insulation cellulose manufacturing that lacks any method of valorization because of its boron salts content. A sugar byproduct and lignosulfonate (LS) were considered as binders for the pellet manufacturing process. Physical tests were carried out to characterize the pellets’ performance. Chemical and combustion tests were considered to state the pellets’ potential as a green energy source. Raw CFP showed good ability in its pelletization and durability in the range of 15–30% of moisture content. The pellet’s density decreased as water content increased. Binders increased the pellet’s length before and after the durability test. Binders also increased the CFP pellet’s water absorption, demonstrating a potential decrease in durability against environmental factors. Binders also decreased the lower heating value. Ultimate analysis showed a slight Nitrogen increase in both binder combinations that could potentially raise the pollutant NOx combustion emissions. All the combinations showed adequate combustion characteristics, but binders increased ash production. Additives decreased the CFP volatile matter content and increased the fixed carbon, which could facilitate a more stable combustion. DTA curves showed a mass loss rate decrease in the volatile stage for the binder combinations, which also could be considered as an indicator of a more stable combustion. The ashes’ chemical compositions when analyzed by XPS showed boron contents oscillating between 10.03% and 16.42%, demonstrating the possibility of recovering them from the combustion ashes.
Open Access
Mechanochemical activation of non-conventional precursors for use as suplementary cementitious materials
(Elsevier, 2025-03-15) Seco Meneses, Andrés; Martín Antunes, Miguel Ángel; Espuelas Zuazu, Sandra; Fernández Jiménez, Ana; Prieto Cobo, Eduardo; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
This work analyzes the effect of Mechanochemical Activation (MA) of a Commercial low-grade kaolinite and low- grade illite, a feldspar, a diatomite and a clayey soil (non-commercial) as supplementary cementitious materials. Milling was conducted at different times for up to 360 min. MA decreased the particles size and increased the specific surface area except for low-grade illite. However, prolonged milling produced agglomeration in feldspar, diatomite and clayey soil. MA partially reduced diffractogram peaks and modified the dehydroxylation losses of mass in the thermogravimetric tests. MA's effect over the solubility of SiO 2 and Al 2 O 3 was not conclusive, with differences among aluminosilicate minerals and with no relationships with their physical parameters or chemical structures. Feldspar was the only one not to show Strength Activity Index (SAI) increases due to MA. Low-grade illite, feldspar and diatomite combinations surpassed 75 % on the SAI. No clear relationships were observed between the combinations SAI and their physical parameters, chemical structure or SiO 2 and Al 2 O 3 availability.
Open Access
Experimental study of the valorization of sulfate soils for use as construction material
(MDPI, 2022) Seco Meneses, Andrés; Del Castillo García, Jesús María; Perlot, Céline; Marcelino Sádaba, Sara; Prieto Cobo, Eduardo; Espuelas Zuazu, Sandra; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
This article shows an experimental investigation carried out for the stabilization of a sulfate soil. The stabilization was carried out in two phases: the first phase was the consumption of the sulfate present in the soil through its controlled transformation into ettringite. After this, a modified soil with lower maximum density, greater optimum moisture identified via standard proctor (SP) test, no plasticity and improved unconfined compressive strength (UCS) was obtained. In the second phase, the modified soil was stabilized by the use of different additives rich in oxides of calcium or magnesium, combined with by-products or waste materials containing reactive aluminum or silicon oxides. As a result, the mechanical strength of the modified soil was improved. In this phase, a binary binder composed of a magnesium oxide product and ground granulated blast-furnace slags (GGBS) obtained the highest UCS. The binary binder composed of lime and an alumina filler formed ettringite in the treated soil. This experiment allowed for the validation of a two-phase stabilization process and the non-conventional additives used, mainly magnesium oxide and GGBS, even for high-bearing-requirement pavement layers’ construction.