Person: UrsĂșa Rubio, Alfredo
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UrsĂșa Rubio
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Alfredo
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IngenierĂa ElĂ©ctrica, ElectrĂłnica y de ComunicaciĂłn
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ISC. Institute of Smart Cities
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0000-0001-6240-8659
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3245
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Publication Open Access State of health estimation of second-life lithium-ion batteries under real profile operation(Elsevier, 2022) Braco Sola, Elisa; San MartĂn Biurrun, Idoia; Sanchis GĂșrpide, Pablo; UrsĂșa Rubio, Alfredo; Stroe, Daniel-Ioan; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; IngenierĂa ElĂ©ctrica, ElectrĂłnica y de ComunicaciĂłn; Gobierno de Navarra / Nafarroako Gobernua; Universidad PĂșblica de Navarra / Nafarroako Unibertsitate PublikoaThe economic viability of second-life (SL) Li-ion batteries from electric vehicles (EVs) is still uncertain nowadays. Assessing the internal state of reused cells is key not only at the repurposing stage but also during their SL operation. As an alternative of the traditional capacity tests used to this end, the estimation of State of Health (SOH) allows to reduce the testing time and the need of equipment, thereby reinforcing the economic success of SL batteries. However, the estimation of SOH in real SL operation has been rarely analysed in literature. This contribution aims thus to cover this gap, by focusing on the experimental assessment of SOH estimation in reused modules from Nissan Leaf EVs under two SL scenarios: a residential household with self-consumption and a fast charge station for EVs. By means of partial charge and experimental data from cycling and calendar ageing tests, accuracy and robustness of health indicators is firstly assessed. Then, SOH estimation is carried out using real profiles, covering a SOH range from 91.3 to 31%. Offline assessment led to RMSE values of 0.6% in the residential profile and 0.8% in the fast charge station, with a reduction in testing times of 85% compared to a full capacity test. In order to avoid the interruption of battery operation, online assessment in profiles was also analysed, obtaining RMSE values below 1.3% and 3.6% in the residential and charging station scenarios, respectively. Therefore, the feasibility of SOH estimation in SL profiles is highlighted, as it allows to get accurate results reducing testing times or even without interrupting normal operation.Publication Open Access Fast capacity and internal resistance estimation method for second-life batteries from electric vehicles(Elsevier, 2023) Braco Sola, Elisa; San MartĂn Biurrun, Idoia; Sanchis GĂșrpide, Pablo; UrsĂșa Rubio, Alfredo; IngenierĂa ElĂ©ctrica, ElectrĂłnica y de ComunicaciĂłn; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Universidad PĂșblica de Navarra / Nafarroako Unibertsitate PublikoaThe success of second-life (SL) Li-ion batteries from electric vehicles is still conditioned by their technical and economic viability. The knowledge of the internal parameters of retired batteries at the repurposing stage is key to ensure their adequate operation and to enlarge SL lifetime. However, traditional characterization methods require long testing times and specific equipment, which result in high costs that may jeopardize the economic viability of SL. In the seek of optimizing the repurposing stage, this contribution proposes a novel fast characterization method that allows to estimate capacity and internal resistance at various state of charge for reused cells, modules and battery packs. Three estimation models are proposed. The first of them is based on measurements of AC resistance, the second on DC resistance and the third combines both resistance types. These models are validated in 506 cells, 203 modules and 3 battery packs from different Nissan Leaf vehicles. The results achieved are satisfactory, with mean absolute percentage errors (MAPE) below 2.5% at cell and module level in capacity prediction and lower than 2.4% in resistance estimation. Considering battery pack level, MAPE is below 4.2% and 1.8% in capacity and resistance estimation respectively. With the proposed method, testing times are reduced from more than one day to 2 min per cell, while energy consumption is lowered from 1.4 kWh to 1 Wh. In short, this study contributes to the reduction of repurposing procedures and costs, and ultimately to the success of SL batteries business model.Publication Open Access Experimental assessment of first- and second-life electric vehicle batteries: performance, capacity dispersion, and aging(IEEE, 2021) Braco Sola, Elisa; San MartĂn Biurrun, Idoia; Berrueta Irigoyen, Alberto; Sanchis GĂșrpide, Pablo; UrsĂșa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; IngenierĂa ElĂ©ctrica, ElectrĂłnica y de ComunicaciĂłn; Universidad PĂșblica de Navarra / Nafarroako Unibertsitate Publikoa; Gobierno de Navarra / Nafarroako GobernuaNowadays, the reuse of electric vehicle batteries is considered to be a feasible alternative to recycling, as it allows them to benefit from their remaining energy capacity and to enlarge their lifetime. Stationary applications, such as self-consumption or off-grid systems support, are examples of second-life (SL) uses for retired batteries. However, reused modules that compose these batteries have heterogeneous properties, which limit their performance. This article aims to assess the influence of degradation in modules from electric vehicles, covering three main aspects: performance, capacity dispersion, and extended SL behavior. First, a complete characterization of new and reused modules is carried out, considering three temperatures and three discharge rates. In the second stage, intra- and intermodule capacity dispersions are evaluated with new and reused samples. Finally, the behavior during SL is also analyzed, through an accelerated cycling test so that the evolution of capacity and dispersion are assessed. Experimental results show that the performance of reused modules is especially undermined at low temperatures and high current rates, as well as in advanced stages of aging. The intramodule dispersion is found to be similar in reused and new samples, while the intermodule differences are nearly four times greater in SL.Publication Open Access Characterization and capacity dispersion of lithium-ion second-life batteries from electric vehicles(IEEE, 2019) Braco Sola, Elisa; San MartĂn Biurrun, Idoia; Sanchis GĂșrpide, Pablo; UrsĂșa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; IngenierĂa ElĂ©ctrica, ElectrĂłnica y de ComunicaciĂłn; Gobierno de Navarra / Nafarroako GobernuaNowadays, electric vehicle batteries reutilization is considered such as a feasible alternative to recycling, as it allows to benefit from their remaining energy and to enlarge their lifetime. Stationary applications as self-consumption or isolated systems support are examples of possible second life uses for these batteries. However, the modules that compose these batteries have very heterogeneous properties, and therefore condition their performance. This paper aims to characterize and analyze the existing capacity dispersion of Nissan Leaf modules that have reached the end of their lifetime on their original application and of new modules of this Electric Vehicle, in order to establish a comparison between them.Publication Open Access Experimental assessment of cycling ageing of lithium-ion second-life batteries from electric vehicles(Elsevier, 2020) Braco Sola, Elisa; San MartĂn Biurrun, Idoia; Berrueta Irigoyen, Alberto; Sanchis GĂșrpide, Pablo; UrsĂșa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; IngenierĂa ElĂ©ctrica, ElectrĂłnica y de ComunicaciĂłn; Gobierno de Navarra / Nafarroako Gobernua, 0011â1411â2018â000029 GERA; Universidad PĂșblica de Navarra / Nafarroako Unibertsitate Publikoa, ReBMS PJUPNA1904The reutilization of batteries from electric vehicles allows to benefit from their remaining energy capacity and to increase their lifespan. The applications considered for the second life of these batteries are less demanding than electric vehicles regarding power and energy density. However, there is still some uncertainty regarding the technical and economic viability of these systems. In this context, the study of the ageing and lifetime of reused batteries is key to contribute to their development. This paper assesses the experimental cycle ageing of lithium-ion modules from different Nissan Leaf through accelerated cycling tests on their second life. The evolution of the internal parameters during ageing and the correlation between them are shown, including the analysis of best fitting curves. In addition, a second-life end-of-life criterion is proposed, based on capacity and internal resistance measurements during cells ageing, which can be applied to real application in order to prevent safety issues. By estimating future values from degradation trends and checking latter measurements, the ageing knee is identified. Results show that the modules operate for at least 2033 equivalent full cycles before reaching their ageing knee. This would mean more than 5 years of operation in a real second-life application, such as a photovoltaic self-consumption installation with daily cycling. Moreover, it is shown that a traditional cell characterisation based on capacity and internal resistance measurements is not enough to predict the durability of a cell during its second life.