Open Access
Experimental and computational investigation of passive heat exchangers to enhance the performance of a geothermal thermoelectric generator
(Elsevier, 2024) Pascual Lezaun, Nerea; Alegría Cía, Patricia; Araiz Vega, Miguel; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
Thermoelectric devices hold significant promise for generating electricity from geothermal heat, enabling the powering of measuring equipment in remote locations without the need for moving parts. Nevertheless, most developed geothermal thermoelectric generators employ fans and pumps to enhance heat transfer, thereby compromising the robustness and reliability inherent to thermoelectricity. Furthermore, there is a lack of research on passive heat exchangers for geothermal thermoelectric generators, particularly in studying their operation under a wide range of meteorological conditions. Therefore, this paper conducts a comprehensive analysis of passive heat exchangers for the cold side of the generators. Phase-change-based heat exchangers differing in their length and fluid are studied experimentally, along with a fin dissipator. Additionally, the influence of wind velocity on heat transfer and mechanical requirements is further explored through a Computational Fluid Dynamics model. The most significant outcome is quantifying the impact of the design parameters and operational variables on the electrical production of the thermoelectric generator. Accordingly, this research aims to broaden the application of these generators to extreme environments, such as Deception Island in Antarctica. Under average operational conditions, generators incorporating 400 mm water heat pipes generate 0.95 W per thermoelectric module, while those incorporating heat pipes with methanol achieve an average of 0.70 W. Moreover, water and methanol-based systems produce 120% and 60% more power than generators using a fin dissipator. Nonetheless, for temperatures beyond -6.5 °C, water might freeze and the methanol-based heat exchangers become more suitable.
Open Access
Thermoelectric generator for high temperature geothermal anomalies: experimental development and field operation
(Elsevier, 2023) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In the current climate and energy context, it is important to develop technologies that permit increase the use of renewable sources such as geothermal energy. Enhancing the use of this renewable source is particularly important in some places, due to its availability and the enormous dependence on fossil fuels, as is the case of the Canary Islands. This work proposes the use of thermoelectric generators with heat exchangers working by phase change to transform the heat from the shallow high temperature geothermal anomalies on the island of Lanzarote directly into electricity, since the use of conventional geothermal power plants would not be possible because they would damage the protected environment. To bring this proposal to reality, this work has succeeded in developing and field-installing a geothermal thermoelectric generator that operates without moving parts thanks to its phase-change heat exchangers. This robust generator do not require maintenance nor auxiliary consumption, and produces a minimal environmental impact, it is noiseless, and the use of water as working fluid makes it completely harmless. The developed device consists of a thermosyphon as hot side heat exchanger, thermoelectric modules and cold side heat exchangers also based in phase change. Tests were carried out in the laboratory at various heat source temperatures and varying the number of thermoelectric modules. It was determined that installing more modules decreases the efficiency per module (from 4.83% with 4 modules to 4.59% with 8 modules at a temperature difference between sources of 235 °C), but for the number of modules tested the total power increases, so the field installation was carried out with 8 modules. After the good results in the laboratory, it was satisfactorily installed at Timanfaya National Park (Lanzarote, Spain) in a borehole with gases at 465 °C. This generator presents a maximum output power of 36 W (4.5 W per module), and is generating 286.94 kWh per year, demonstrating the great potential of the developed thermoelectric generators to build a larger-scale renewable installation.
Open Access
Design and optimization of thermoelectric generators for harnessing geothermal anomalies: a computational model and validation with experimental field results
(Elsevier, 2024) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Erro Iturralde, Irantzu; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Thermoelectric generators have been recently proved to be a feasible alternative to harness hot dry rock fields with very promising results transforming the geothermal heat into electricity. This research deepens in the study of these generators, developing a versatile computational model that serves as a tool to design and optimize this type of thermoelectric generators. This tool is important to develop this thermoelectric technology on a large scale, to produce clean and renewable electrical energy especially in the Timanfaya National Park, in Lanzarote (Spain), where some of the most important shallow geothermal anomalies in the world are located, in order to promote self-consumption in this zone. However, it could be employed in other areas with different boundary conditions. The model, based in the finite difference method applied to the thermal-electrical analogy of a geothermal thermoelectric generator, has been validated with the experimental field results of two thermoelectric generators installed in two different zones of geothermal anomalies. It has achieved a relative error of less than 10% when predicting the power and between 0.5–1.6% in the annual energy generation, what makes it a very reliable and useful computational tool. The developed model has been employed for the first time to estimate the electrical energy that could be generated if harnessing the characterized area of anomalies in Lanzarote. Here, given the continuity of geothermal energy, 7.24 GWh per year could be generated, which means annually 1.03 MWh/m2.
Open Access
Thermoelectric heat recovery in a real industry: from laboratory optimization to reality
(Elsevier, 2021) Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Catalán Ros, Leyre; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2018-000101
Thermoelectricity, in the form of thermoelectric generators, holds a great potential in waste heat recovery, this potential has been studied and proved in several laboratory and theoretical works. By the means of a thermoelectric generator, part of the energy that normally is wasted in a manufacturing process, can be transformed into electricity, however, implementing this technology in real industries still remains a challenge and on-site tests need to be performed in order to prove the real capabilities of this technology. In this work, a computational model to simulate the behaviour of a thermoelectric generator that harvest waste heat from hot fumes is developed. Using the computational model an optimal configuration for a thermoelectric generator is obtained, also an experimental study of the performance of different heat pipes working as cold side heat exchangers is carried out in order to optimize the performance of the whole thermoelectric generator, thermal resistances of under 0,25 K/W are obtained. The optimized configuration of the thermoelectric generator has been built, installed and tested under real conditions at a rockwool manufacturing plant and experimental data has been obtained during the 30 days field test period. Results show that 4.6 W of average electrical power are produced during the testing period with an efficiency of 2.38%. Moreover, the computational model is validated using this experimental data. Furthermore, the full harvesting potential of an optimized designed that takes advantage of the whole pipe is calculated using the validated computational model, resulting in 30.8 MWh of energy harvested during a sample year which could meet the demand of 8.34 Spanish average households.
Open Access
Thermoelectric generator with passive biphasic thermosyphon heat exchanger for waste heat recovery: design and experimentation
(MDPI, 2021) Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
One of the measures to fight against the current energy situation and reduce the energy consumption at an industrial process is to recover waste heat and transform it into electric power. Thermoelectric generators can be used for that purpose but there is a lack of experimental studies that can bring this technology closer to reality. This work presents the design, optimizations and development of two devices that are experimented and compared under the same working conditions. The hot side heat exchanger of both generators has been designed using a computational fluid dynamics software and for the cold side of the generators two technologies have been analysed: a finned dissipater that uses a fan and free convection biphasic thermosyphon. The results obtained show a maximum net generation of 6.9 W in the thermoelectric generator with the finned dissipater; and 10.6 W of power output in the generator with the biphasic thermosyphon. These results remark the importance of a proper design of the heat exchangers, trying to get low thermal resistances at both sides of the thermoelectric modules, as well as, the necessity of considering the auxiliary consumption of the equipment employed.
Open Access
Enhanced behaviour of a passive thermoelectric generator with phase change heat exchangers and radiative cooling
(Elsevier, 2023) Astrain Ulibarrena, David; Jaramillo-Fernández, Juliana; Araiz Vega, Miguel; Francone, Achille; Catalán Ros, Leyre; Jacobo-Martín, Alejandra; Alegría Cía, Patricia; Sotomayor-Torres, Clivia M.; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Heat exchangers are essential to optimize the efficiency of Thermoelectric Generators (TEGs), and heat pipes without fans have proven to be an advantageous design as it maintains the characteristic robustness of thermoelectricity, low maintenance and lack of moving parts. However, the efficiency of these heat exchangers decreases under natural convection conditions, reducing their heat transfer capacity and thus thermoelectric power production. This work reports on a novel heat exchanger that combines for the first time, phase change and radiative cooling in a thermoelectric generator to improve its efficiency and increase the production of electrical energy, specially under natural convection. For this, two thermoelectric generators with heat-pipes on their cold sides have been tested: one with the radiative coating and the other without it. Their thermal resistances have been determined and the electric power output was compared under different working conditions, namely, natural convection and forced convection indoors and outdoors. The experimental tests show a clear reduction of the heat exchanger thermal resistance thanks to the radiative coating and consequently, an increase of electric production 8.3 % with outdoor wind velocities of 1 m/s, and up to 54.8 % under free convection conditions. The application of the radiative surface treatment is shown to result in a more stable electrical energy production, suppressing the drastic decrease in the generated electric power that occurs in thermoelectric generators when they work under free convection.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(Elsevier, 2022) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Rodríguez García, Antonio; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Nowadays, geothermal energy in shallow hot dry rock fields is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. However, the efficiency of a thermoelectric generator depends highly on the heat exchangers. In this work, a novel geothermal thermoelectric generator is experimentally developed, characterizing different configurations of biphasic heat exchangers to obtain low thermal resistances that allow the maximum efficiency in the thermoelectric modules. As a result, robust and passive heat exchangers were obtained with thermal resistances of 0.07 K/W and 0.4 K/W in the hot and cold sides, respectively. The geothermal thermoelectric generator was built with the most effective heat exchangers and was experimented under different temperature and convection conditions, generating 36 W (17 W by a prototype with 10 modules and 19 W by a prototype with 6 modules) for a temperature difference of 160 °C between the heat source and the environment. Furthermore, the experimental development showed that it is possible to increase electricity generation with a more compact generator, since a decrease in the number of modules from 10 to 6 increases the efficiency from 3.72% to 4.06%. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Prospects of autonomous volcanic monitoring stations: experimental investigation on thermoelectric generation from fumaroles
(MDPI, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Padilla, Germán D.; Hernández, Pedro A.; Pérez, Nemesio M.; García de la Noceda, Celestino; Albert, José F.; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 °C. Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 °C. The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 °C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.
Open Access
Geothermal thermoelectric generator for Timanfaya National Park
(2019) Catalán Ros, Leyre; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In the case of shallow Hot Dry Rock (HDR) fields, thermoelectric generators can entail a sustainable alternative to Enhanced Geothermal Systems (EGS). The present work studies two configurations of thermoelectric generators for Timanfaya National Park (Spain), one of the most important Hot Dry Rock fields in the world, with temperatures of 500°C at only 3 meters deep. The first configuration includes biphasic thermosyphons as heat exchangers for both sides, leading to a completely passive thermoelectric generator. The second configuration uses fin dissipators as cold-side heat exchangers.
Open Access
New opportunities for electricity generation in shallow hot dry rock fields: a study of thermoelectric generators with different heat exchangers
(Elsevier, 2019) Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Institute of Smart Cities - ISC
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In order to leverage shallow hot dry rock (HDR) fields, the present paper proposes an alternative to enhanced geothermal systems (EGS): thermoelectric generators. Based on the conditions of Timanfaya National Park, a prototype has been built to experimentally analyze the feasibility of the proposed solution. The prototype is composed by a two phase closed thermosyphon (TPCT) as hot side heat exchanger, two thermoelectric modules, and it considers different cold side heat exchangers: fin dissipators assisted by a fan and loop thermosyphons, both with various geometries. Experiments have demonstrated that loop thermosyphons represent the best alternative due to their low thermal resistance and, especially, due to their lack of auxiliary consumption, leading to a maximum net power generation of 3.29 W per module with a temperature difference of 180 °C (200 °C in the hot side and 20 °C as ambient temperature), 54% more than with fin dissipators. Hence, there exists a new opportunity for electricity generation in shallow hot dry rock fields: thermoelectric generators with biphasic thermosyphons as heat exchangers, a patented and robust solution.