Open Access
Experimental and computational investigation of passive heat exchangers to enhance the performance of a geothermal thermoelectric generator
(Elsevier, 2024) Pascual Lezaun, Nerea; Alegría Cía, Patricia; Araiz Vega, Miguel; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
Thermoelectric devices hold significant promise for generating electricity from geothermal heat, enabling the powering of measuring equipment in remote locations without the need for moving parts. Nevertheless, most developed geothermal thermoelectric generators employ fans and pumps to enhance heat transfer, thereby compromising the robustness and reliability inherent to thermoelectricity. Furthermore, there is a lack of research on passive heat exchangers for geothermal thermoelectric generators, particularly in studying their operation under a wide range of meteorological conditions. Therefore, this paper conducts a comprehensive analysis of passive heat exchangers for the cold side of the generators. Phase-change-based heat exchangers differing in their length and fluid are studied experimentally, along with a fin dissipator. Additionally, the influence of wind velocity on heat transfer and mechanical requirements is further explored through a Computational Fluid Dynamics model. The most significant outcome is quantifying the impact of the design parameters and operational variables on the electrical production of the thermoelectric generator. Accordingly, this research aims to broaden the application of these generators to extreme environments, such as Deception Island in Antarctica. Under average operational conditions, generators incorporating 400 mm water heat pipes generate 0.95 W per thermoelectric module, while those incorporating heat pipes with methanol achieve an average of 0.70 W. Moreover, water and methanol-based systems produce 120% and 60% more power than generators using a fin dissipator. Nonetheless, for temperatures beyond -6.5 °C, water might freeze and the methanol-based heat exchangers become more suitable.
Open Access
New opportunities for electricity generation in shallow hot dry rock fields: a study of thermoelectric generators with different heat exchangers
(Elsevier, 2019) Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Institute of Smart Cities - ISC
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In order to leverage shallow hot dry rock (HDR) fields, the present paper proposes an alternative to enhanced geothermal systems (EGS): thermoelectric generators. Based on the conditions of Timanfaya National Park, a prototype has been built to experimentally analyze the feasibility of the proposed solution. The prototype is composed by a two phase closed thermosyphon (TPCT) as hot side heat exchanger, two thermoelectric modules, and it considers different cold side heat exchangers: fin dissipators assisted by a fan and loop thermosyphons, both with various geometries. Experiments have demonstrated that loop thermosyphons represent the best alternative due to their low thermal resistance and, especially, due to their lack of auxiliary consumption, leading to a maximum net power generation of 3.29 W per module with a temperature difference of 180 °C (200 °C in the hot side and 20 °C as ambient temperature), 54% more than with fin dissipators. Hence, there exists a new opportunity for electricity generation in shallow hot dry rock fields: thermoelectric generators with biphasic thermosyphons as heat exchangers, a patented and robust solution.
Open Access
Geothermal thermoelectric generator for Timanfaya National Park
(2019) Catalán Ros, Leyre; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In the case of shallow Hot Dry Rock (HDR) fields, thermoelectric generators can entail a sustainable alternative to Enhanced Geothermal Systems (EGS). The present work studies two configurations of thermoelectric generators for Timanfaya National Park (Spain), one of the most important Hot Dry Rock fields in the world, with temperatures of 500°C at only 3 meters deep. The first configuration includes biphasic thermosyphons as heat exchangers for both sides, leading to a completely passive thermoelectric generator. The second configuration uses fin dissipators as cold-side heat exchangers.
Open Access
Improvements in the cooling capacity and the COP of a transcritical CO 2 refrigeration plant operating with a thermoelectric subcooling system
(Elsevier, 2019) Astrain Ulibarrena, David; Merino Vicente, Amaya; Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Sánchez, Daniel; Cabello, Ramón; Llopis, R.; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Restrictive environmental regulations are driving the use of CO 2 as working fluid in commercial vapour compression plants due to its ultra-low global warming potential (GWP 100 = 1) and its natural condition. However, at high ambient temperatures transcritical operating conditions are commonly achieved causing low energy efficiencies in refrigeration facilities. To solve this issue, several improvements have been implemented, especially in large centralized plants where ejectors, parallel compressors or subcooler systems, among others, are frequently used. Despite their good results, these measures are not suitable for small-capacity systems due mainly to the cost and the complexity of the system. Accordingly, this work presents a new subcooling system equipped with thermoelectric modules (TESC), which thanks to its simplicity, low cost and easy control, results very suitable for medium and small capacity plants. The developed methodology finds the gas-cooler pressure and the electric voltage supplied to the TESC system that maximizes the overall COP of the plant taking into account the ambient temperature, the number of thermoelectric modules used and the thermal resistance of the heat exchangers included in the TESC. The obtained results reveal that, with 20 thermoelectric modules, an improvement of 20% in terms of COP and of 25.6% regarding the cooling capacity can be obtained compared to the base cycle of CO 2 of a small cooling plant refrigerated by air. Compared to a cycle that uses an internal heat exchanger IHX, the improvements reach 12.2% and 19.5% respectively.
Open Access
400 W facility of geothermal thermoelectric generators from hot dry rocks on the Canary Islands
(Elsevier, 2025-06-01) Alegría Cía, Patricia; Pascual Lezaun, Nerea; Catalán Ros, Leyre; Araiz Vega, Miguel; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Geothermal energy has a great potential to be harnessed and requires a boost in technologies to enhance its use. The Canary Islands have a great dependence on fossil fuels, and Lanzarote has important geothermal anomalies currently unexploited due to the absence of water in the soil, what hinders the use of vapour turbines. This work presents the development of the first facility of geothermal thermoelectric generators operating in the world. This novel generators are producing 400 W of power in Timanfaya National Park. It has three geothermal thermoelectric generators, each with 4 thermosyphons per borehole and 40 thermoelectric modules that directly transform heat into electricity. This facility, with the advantages of geothermal energy such as continuity and independence on the weather, requires low maintenance because it does not require moving parts nor water consumption. That makes feasible for the first time to harness the geothermal potential in Lanzarote, producing an electric energy of 9.4 kWh per day, which means 3.42 MWh per year. The field installation of this novel technology has enabled to accurately calculate the Levelized Cost of Energy, which is 0.22 €/kWh. Although a 29% decrease in the power generated by thermoelectric module was detected when installing a GTEG with 40 modules with respect to a GTEG with 10 modules, this decrease is compensated by the fact that by installing more modules, the electrical production per borehole is optimized, reducing the LCOE. The developed facility will avoid the emission of 2.3 tons of CO2 and is totally respectful with the environment if compared to conventional geothermal power plants.
Open Access
Experimental validation and development of an advanced computational model of a transcritical carbon dioxide vapour compression cycle with a thermoelectric subcooling system
(Elsevier, 2022) Casi Satrústegui, Álvaro; Aranguren Garacochea, Patricia; Sánchez, Daniel; Araiz Vega, Miguel; Cabello, Ramón; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
The inclusion of a thermoelectric subcooler as an alternative to increment the performance of a vapour compression cycle has been proved promising when properly designed and operated for low-medium power units. In this work, a computational model that simulates the behaviour of a carbon dioxide transcritical vapour compression cycle in conjunction with a thermoelectric subcooler system is presented. The computational tool is coded in Matlab and uses Refprop V9.1 to calculate the properties of the refrigerant at each point of the refrigeration cycle. Working conditions, effect of the heat exchangers of the subcooling system, temperature dependent thermoelectric properties, thermal contact resistances and the four thermoelectric effects are taken into account to increment its accuracy. The model has been validated using experimental data to prove the reliability and accuracy of the results obtained and shows deviations between the ±7% for the most relevant outputs. Using the validated computational tool a 13.6 % COP improvement is predicted when optimizing the total number of thermoelectric modules of the subcooling system. The computational experimentally validated tool is properly fit to aid in the design and operation of thermoelectric subcooling systems, being able to predict the optimal configuration and operation settings for the whole refrigeration plant.
Open Access
Experimental and computational study on thermoelectric generators using thermosyphons with phase change as heat exchangers
(Elsevier, 2017) Araiz Vega, Miguel; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Mekanika, Energetika eta Materialen Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería Mecánica, Energética y de Materiales
An important issue in thermoelectric generators is the thermal design of the heat exchangers since it can improve their performance by increasing the heat absorbed or dissipated by the thermoelectric modules. Due to its several advantages, compared to conventional dissipation systems, a thermosyphon heat exchanger with phase change is proposed to be placed on the cold side of thermoelectric generators. Some of these advantages are: high heat-transfer rates; absence of moving parts and lack of auxiliary con- sumption (because fans or pumps are not required); and the fact that these systems are wickless. A com- putational model is developed to design and predict the behaviour of this heat exchangers. Furthermore, a prototype has been built and tested in order to demonstrate its performance and validate the compu- tational model. The model predicts the thermal resistance of the heat exchanger with a relative error in the interval [?8.09;7.83] in the 95% of the cases. Finally, the use of thermosyphons with phase change in thermoelectric generators has been studied in a waste-heat recovery application, stating that including them on the cold side of the generators improves the net thermoelectric production by 36% compared to that obtained with finned dissipators under forced convection.
Open Access
Simulation of thermoelectric heat pumps in nearly zero energy buildings: why do all models seem to be right?
(Elsevier, 2021) Martínez Echeverri, Álvaro; Díaz de Garayo, Sergio; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Catalán Ros, Leyre; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
The use of thermoelectric heat pumps for heat, ventilation, and air conditioning in nearly-zero-energy buildings is one of the most promising applications of thermoelectrics. However, simulation works in the literature are predominately based on the simple model, which was proven to exhibit significant deviations from experimental results. Nine modelling techniques have been compared in this work, according to statistical methods based on uncertainty analysis, in terms of predicted coefficient of performance and cooling power. These techniques come from the combination of three simulation models for thermoelectric modules (simple model, improved model, electric analogy) and five methods for implementing the thermoelectric properties. The main conclusion is that there is no statistical difference in the mean values of coefficient of performance and cooling power provided by these modelling techniques under all the scenarios, at 95% level of confidence. However, differences appear in the precision of these results in terms of uncertainty of the confidence intervals. Minimum values of uncertainty are obtained when the thermal resistance ratio approaches 0.1, being ±8% when using temperature-dependent expressions for the thermoelectric properties, ±18% when using Lineykin's method, and ± 25% when using Chen's method. The best combination is that composed of the simple model and temperature-dependent expressions for the thermoelectric properties. Additionally, if low values of resistance ratio are anticipated, empirical expressions from the literature can be used for the thermal resistance of the heat exchangers; for high values, though, experimental tests should be deployed, especially for the heat exchanger on the hot side.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(2021) Alegría Cía, Patricia; Rodríguez García, Antonio; Catalán Ros, Leyre; Astrain Ulibarrena, David; Araiz Vega, Miguel; Ingeniería; Institute of Smart Cities - ISC; Ingeniaritza
Nowadays, geothermal energy in shallow hot dry rocks is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Enhanced behaviour of a passive thermoelectric generator with phase change heat exchangers and radiative cooling
(Elsevier, 2023) Astrain Ulibarrena, David; Jaramillo-Fernández, Juliana; Araiz Vega, Miguel; Francone, Achille; Catalán Ros, Leyre; Jacobo-Martín, Alejandra; Alegría Cía, Patricia; Sotomayor-Torres, Clivia M.; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Heat exchangers are essential to optimize the efficiency of Thermoelectric Generators (TEGs), and heat pipes without fans have proven to be an advantageous design as it maintains the characteristic robustness of thermoelectricity, low maintenance and lack of moving parts. However, the efficiency of these heat exchangers decreases under natural convection conditions, reducing their heat transfer capacity and thus thermoelectric power production. This work reports on a novel heat exchanger that combines for the first time, phase change and radiative cooling in a thermoelectric generator to improve its efficiency and increase the production of electrical energy, specially under natural convection. For this, two thermoelectric generators with heat-pipes on their cold sides have been tested: one with the radiative coating and the other without it. Their thermal resistances have been determined and the electric power output was compared under different working conditions, namely, natural convection and forced convection indoors and outdoors. The experimental tests show a clear reduction of the heat exchanger thermal resistance thanks to the radiative coating and consequently, an increase of electric production 8.3 % with outdoor wind velocities of 1 m/s, and up to 54.8 % under free convection conditions. The application of the radiative surface treatment is shown to result in a more stable electrical energy production, suppressing the drastic decrease in the generated electric power that occurs in thermoelectric generators when they work under free convection.