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Pérez de Landazábal Berganzo, José Ignacio

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Pérez de Landazábal Berganzo

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José Ignacio

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Ciencias

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InaMat2. Instituto de Investigación en Materiales Avanzados y Matemáticas

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0000-0003-1172-6141

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1681

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Now showing 1 - 10 of 12
  • PublicationOpen Access
    Influence of structural defects on the properties of metamagnetic shape memory alloys
    (MDPI, 2020) Pérez de Landazábal Berganzo, José Ignacio; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Lambri, Osvaldo Agustín; López García, Javier; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias
    The production of µ-particles of Metamagnetic Shape Memory Alloys by crushing and subsequent ball milling process has been analyzed. The high energy involved in the milling process induces large internal stresses and high density of defects with a strong influence on the martensitic transformation; the interphase creation and its movement during the martensitic transformation produces frictional contributions to the entropy change (exothermic process) both during forward and reverse transformation. The frictional contribution increases with the milling time as a consequence of the interaction between defects and interphases. The influence of the frictional terms on the magnetocaloric effect has been evidenced. Besides, the presence of antiphase boundaries linked to superdislocations helps to understand the spin-glass behavior at low temperatures in martensite. Finally, the particles in the deformed state were introduced in a photosensitive polymer. The mechanical damping associated to the Martensitic Transformation (MT) of the particles is clearly distinguished in the produced composite, which could be interesting for the development of magnetically-tunable mechanical dampers.
  • PublicationOpen Access
    Monitoring structural transformations in metamagnetic shape memory alloys by non-contact GMI technology
    (IOP Publishing, 2023) Beato López, Juan Jesús; La Roca, Paulo Matías; Algueta-Miguel, Jose M.; Garayo Urabayen, Eneko; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Gómez Polo, Cristina; Pérez de Landazábal Berganzo, José Ignacio; Ciencias; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Zientziak; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
    Different applications based on metamagnetic shape memory alloy (MSMA) require monitoring the evolution of the martensitic transformation (MT) to optimize the actuation mechanism. To avoid interaction with the active material, a non-contact technique would be ideal. Nevertheless, non-contact detection involves complex methods like diffraction, optical analysis, or electromagnetic technology. The present work demonstrates that the MT can be monitored without interaction with the active material using a low-cost technology based on the Giant Magnetoimpedance (GMI) effect. The GMI sensor is based on a (CoFe)SiB soft magnetic wire submitted to an alternating current and whose second harmonic voltage variation allows to detect changes in the strength of the stray magnetic fields linked to the metamagnetic phase transition. The sensor has been tested using the MT of a NiMnInCo MSMA. A specific application for environmental temperature control using the non-contact GMI sensor is proposed.
  • PublicationOpen Access
    Magnetic behavior in commercial iron-silicon alloys controlled by the dislocation dynamics at temperatures below 420 K
    (Elsevier, 2021) Lambri, Osvaldo Agustín; Weidenfeller, B.; Bonifacich, Federico Guillermo; Pérez de Landazábal Berganzo, José Ignacio; Cuello, G.J.; Weidenfeller, L.; Recarte Callado, Vicente; Zelada, Griselda Irene; Riehemann, W.; Ciencias; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
    A decrease of the temperature dependent coercive forces up to around 370 K is discovered in iron silicon alloys, both in quenched samples and in samples which were previously thermally treated to achieve the highest magnetic quality. Alloys of composition Fe-6 wt.% Si and Fe-3 wt.% Si are studied. This reduction in the coercive force is controlled by an increase in the mobility of the domain walls due to the increase in the dislocation's mobility enhanced by the movement of vacancies. It is worthwhile to mention that this reduction in coercive force is only present at these slightly elevated temperatures which are markedly smaller than the usual annealing temperatures for heat treatment of iron silicon alloys while it disappears again at room temperature. Neutron thermodiffraction, magnetic hysteresis loops tracer and mechanical spectroscopy are used as experimental techniques.
  • PublicationOpen Access
    Polycaprolactone/MSMA composites for magnetic refrigeration applications
    (Wiley, 2024-09-06) Sánchez-Alarcos Gómez, Vicente; Khanna, Deepali; La Roca, Paulo Matías; Recarte Callado, Vicente; Lambri, Fernando Daniel; Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Royo Silvestre, Isaac; Urbina Yeregui, Antonio; Pérez de Landazábal Berganzo, José Ignacio; Ciencias; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2
    A high filling load (62% weight) printable magnetic composite has been elaborated from the dispersion of magnetocaloric Ni45Mn36.7In13.3Co5 metamagnetic shape memory alloy microparticles into a PCL polymer matrix. The composite material has been prepared by solution method, resulting in a very homogeneous particles dispersion into the matrix. The structural transitions in the polymer are not affected by the addition of the metallic microparticles, which in turn results in a significant increase of the mechanical consistency. The good ductility of the elaborated composite allows its extrusion in flexible printable filaments, from which 3D pieces with complex geometries have been grown. The heat transfer of the composite material has been assessed from finite element simulation. In spite of the achievable magnetocaloric values are moderated with respect to the bulk, numerical simulations confirm that, in terms of heat transference, a PCL/Ni-Mn-In-Co wire is more efficient than a bulk Ni-Mn-In-Co cubic piece containing the same amount of magnetic active material. The quite good magnetocaloric response of the composite and the possibility to print high surface/volume ratio geometries make this material a promising candidate for the development of heat exchangers for clean and efficient magnetic refrigeration applications.
  • PublicationOpen Access
    Effect of high-energy ball-milling on the magnetostructural properties of a Ni45Co5Mn35Sn15 alloy
    (Elsevier, 2021) López García, José Luis; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Rodríguez Velamazán, José Alberto; Unzueta, Iraultza; García, José Ángel; Plazaola, Fernando; La Roca, Paulo Matías; Pérez de Landazábal Berganzo, José Ignacio; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Gobierno de Navarra / Nafarroako Gobernua, PC017-018 AMELEC
    The effect of high-energy ball-milling on the magnetostructural properties of a Ni45Co5Mn35Sn15 alloy in austenitic phase at room temperature has been analyzed by neutron and high-resolution X-ray diffraction. The ball milling promotes a mechanically-induced martensitic transformation as well as the appearance of amorphous-like non-transforming regions, following a double stage; for short milling times (below 30 min), a strong size reduction and martensite induction occur. On the opposite, for longer times, the increase of strains predominates and consequently a larger amount of non-transforming regions appears. The effect of the microstructural defects brought by milling (as dislocations) on both the enthalpy change at the martensitic transformation and the high field magnetization of the austenite has been quantitatively estimated and correlated to the internal strains. Contrary to what occurs in ternary Ni-Mn-Sn alloys, the mechanically-induced defects do not change the ferromagnetic coupling between Mn atoms, but just cause a net reduction on the magnetic moments.
  • PublicationOpen Access
    Martensitic transformation controlled by electromagnetic field: from experimental evidence to wireless actuator applications
    (Elsevier, 2022) Garayo Urabayen, Eneko; La Roca, Paulo Matías; Gómez Polo, Cristina; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Pérez de Landazábal Berganzo, José Ignacio; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Gobierno de Navarra / Nafarroako Gobernua
    Mechanical actuators based on shape memory alloys (SMA) are becoming a key component in the development of novel soft robotic applications and surgically implantable devices. Their working principle relies in the temperature induced martensitic transformation (MT), which is responsible of the actuation mechanism. In this work, we found experimental evidence to show that the martensitic transformation can be controlled by electromagnetic field (EF) by a wireless process in ferromagnetic shape memory alloys. It is shown that the martensitic transformation can be driven by an external EF (frequency 45 kHz) while the specific absorption rate (SAR), which was determined through real-time dynamic magnetization measurements, allows the instantaneous monitoring of the transformation evolution. On the basis of the obtained results, we propose a strategy to achieve a battery-free wireless SMA actuator that can be remotely controlled. This concept can be applicable to other SMA material that exhibit a similar magneto-structural phase transition
  • PublicationOpen Access
    Magnetically activated 3D printable polylactic acid/polycaprolactone/magnetite composites for magnetic induction heating generation
    (Springer, 2023) Galarreta Rodríguez, Itziar; López Ortega, Alberto; Garayo Urabayen, Eneko; Beato López, Juan Jesús; La Roca, Paulo Matías; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Gómez Polo, Cristina; Pérez de Landazábal Berganzo, José Ignacio; Ciencias; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
    Additive manufacturing technology has attracted the attention of industrial and technological sectors due to the versatility of the design and the easy manufacture of structural and functional elements based on composite materials. The embedding of magnetic nanoparticles in the polymeric matrix enables the development of an easy manufacturing process of low-cost magnetically active novel polymeric composites. In this work, we report a series of magnetic composites prepared by solution casting method combining 5 to 60 wt.% of 140 ± 50 nm commercial Fe3O4 nanoparticles, with a semi-crystalline, biocompatible, and biodegradable polymeric blend made of polylactic acid (PLA) and polycaprolactone (PCL). The composites were extruded, obtaining 1.5 ± 0.2 mm diameter continuous and flexible filaments for fused deposition modelling 3D printing. The chemical, magnetic, and calorimetric properties of the obtained filaments were investigated by differential scanning calorimetry, thermogravimetric analysis, magnetometry, and scanning electron microscopy. Furthermore, taking advantage of the magnetic character of the filaments, their capability to generate heat under the application of low-frequency alternating magnetic fields (magnetic induction heating) was analyzed. The obtained results expose the versatility of these easy manufacturing and low-cost filaments, where selecting a desired composition, the heating capacity can be properly adjusted for those applications where magnetic induction plays a key role (i.e., magnetic hyperthermia, drug release, heterogeneous catalysis, water electrolysis, gas capture, or materials synthesis).
  • PublicationEmbargo
    High functional 3D printed PCL/FSMA magnetic composites
    (IOP Publishing, 2024) Lambri, Fernando Daniel; Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Khanna, Deepali; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Sánchez-Alarcos Gómez, Vicente; Lambri, Melania Lucila; Zelada, Griselda Irene; Ciencias; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2
    The capacity of adaptability of a three-dimensional-printed composite of polycaprolactone-based containing micro-particles of ferromagnetic shape memory alloy of composition Ni45Mn36.7In13.3Co5 was determined. Composites exhibit an increase in both damping and modulus values up to around 11%, at temperatures close to 325 K, when applying a magnetic field of 120 kA m−1. In addition, composites show also an increase in the damping values of around 50% at temperatures near 333 K, related to the martensitic transformation, which is promoted by an increase in the oscillating strain from 0.5 × 10−4 up to 2 × 10−4 and when applying a magnetic field of 120 kA m−1. Moreover, the maximum temperature of use of the composite can be increased by means of a magnetic field. These adaptability qualities make this functional composite attractive, for the vibration control at elevated temperatures as well as the potential applications in magnetocaloric devices.
  • PublicationOpen Access
    Analysis of the strain misfit between matrix and inclusions in a magnetically tunable composite
    (Elsevier, 2021) Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Lambri, Fernando Daniel; Bozzano, P. B.; Recarte Callado, Vicente; Sánchez-Alarcos Gómez, Vicente; Pérez de Landazábal Berganzo, José Ignacio; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
    A magnetically tunable composite has been elaborated by embedding microparticles of a metamagnetic shape memory alloy on a photo curable resin. The strain misfit between the polymeric matrix and the inclusions has been analysed within Eshelby formalism. Results show the non-appearance of active microcracks at the interfaces where strains are induced by the martensitic transformation in the microparticles. Even though the martensitic transformation is well detected, the values of misfit β coefficient indicate that the matrix accommodates all the stresses induced by the inclusions. A stable surface interaction between particles and matrix is also confirmed during thermal cycles. It is also demonstrated that the damping capacity of the composites can be tuned by combining oscillating strain, fillers content and magnetic field. The proposed model could be applied to analyse the mechanical stability in polymer matrix composites in which fillers undergo a first order transition with volume change and associated deformation.
  • PublicationOpen Access
    Magnetically tunable damping in composites for 4D printing
    (Elsevier, 2021) Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Recarte Callado, Vicente; Sánchez-Alarcos Gómez, Vicente; Pérez de Landazábal Berganzo, José Ignacio; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
    Composite materials are being used in the design of new devices to produce more functional, cheap and on-demand products. In particular, 3D printing technology based on composites opens a huge field enabling the freedom of design and the ability to manufacture complex structures. In this context, the analysis of the functional properties of printable composites is of great importance. The work is focused on the analysis of the mechanical damping of a composite made with different concentrations of a Ni45Mn36.7In13.3Co5 metamagnetic shape memory alloy into an UV-curing polymer. The composites provide a bulk material containing very brittle metallic μ-particles that can be handled for technological applications. Damping and dynamic modulus of the composites were modified with small magnetic fields below 100 kA/m, proving that the damping capacity can be tuned by applying an external magnetic field. From the measurements, it has been also possible to determine the intrinsic damping and moduli of the alloy particles, which show the characteristic properties linked to the MT. These preliminary results allow proposing this composite material as a potential functional material to be used in the design of printable devices for magneto-mechanical damping applications.