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Pérez de Landazábal Berganzo, José Ignacio

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Pérez de Landazábal Berganzo

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José Ignacio

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InaMat2. Instituto de Investigación en Materiales Avanzados y Matemáticas

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0000-0003-1172-6141

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2014 - 201912020 - 20212
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Author: Recarte Callado, Vicente × Subject: Metamagnetic shape memory alloys × Item Type: Publication ×

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Now showing 1 - 3 of 3
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    PublicationOpen Access
    Influence of structural defects on the properties of metamagnetic shape memory alloys
    (MDPI, 2020) Pérez de Landazábal Berganzo, José Ignacio; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Lambri, Osvaldo Agustín; López García, Javier; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias
    The production of µ-particles of Metamagnetic Shape Memory Alloys by crushing and subsequent ball milling process has been analyzed. The high energy involved in the milling process induces large internal stresses and high density of defects with a strong influence on the martensitic transformation; the interphase creation and its movement during the martensitic transformation produces frictional contributions to the entropy change (exothermic process) both during forward and reverse transformation. The frictional contribution increases with the milling time as a consequence of the interaction between defects and interphases. The influence of the frictional terms on the magnetocaloric effect has been evidenced. Besides, the presence of antiphase boundaries linked to superdislocations helps to understand the spin-glass behavior at low temperatures in martensite. Finally, the particles in the deformed state were introduced in a photosensitive polymer. The mechanical damping associated to the Martensitic Transformation (MT) of the particles is clearly distinguished in the produced composite, which could be interesting for the development of magnetically-tunable mechanical dampers.
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    PublicationOpen Access
    Long-range atomic order and entropy change at the martensitic transformation in a Ni-Mn-In-Co metamagnetic shape memory alloy
    (MDPI, 2014) Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Pérez de Landazábal Berganzo, José Ignacio; Cesari, Eduard; Rodríguez Velamazán, José Alberto; Física; Fisika
    The influence of the atomic order on the martensitic transformation entropy change has been studied in a Ni-Mn-In-Co metamagnetic shape memory alloy through the evolution of the transformation temperatures under high-temperature quenching and post-quench annealing thermal treatments. It is confirmed that the entropy change evolves as a consequence of the variations on the degree of L21 atomic order brought by thermal treatments, though, contrary to what occurs in ternary Ni-Mn-In, post-quench aging appears to be the most effective way to modify the transformation entropy in Ni-Mn-In-Co. It is also shown that any entropy change value between around 40 and 5 J/kgK can be achieved in a controllable way for a single alloy under the appropriate aging treatment, thus bringing out the possibility of properly tune the magnetocaloric effect.
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    PublicationOpen Access
    Correlation between particle size and magnetic properties in soft-milled Ni45Co5Mn34In16 powders
    (Elsevier, 2021) Khanna, Deepali; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Pérez de Landazábal Berganzo, José Ignacio; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Gobierno de Navarra / Nafarroako Gobernua, PC017-018 AMELEC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
    The effect of microstructural defects induced by mechanical milling has been studied in a Ni–Mn–In–Co metamagnetic shape memory alloy. The martensitic transformation and Curie temperatures do not change with grinding, thus pointing out to a null variation of long range atomic order as a consequence of the deformation. Nevertheless, the enthalpy change of the martensitic transformation highly decreases. This, and the large thermal stabilization of the martensite (with shifts on the temperature of the first reverse martensitic transformation up to 60 K), indicate the presence of a huge amount of internal stresses and microstructural defects in the obtained micro-particles. The presence of such defects considerably affects the saturation magnetization in austenite whereas almost no effect is observed in martensite. The magnetocaloric effect has been evaluated in samples with three different particle sizes. In spite of the MCE value is lower than in the bulk, the broader temperature range for the martensitic transformation in the powders makes the relative cooling power be comparable to that in the bulk. The as-milled micro-particles can be then considered as good preliminary candidates for magnetic refrigeration applications at the microscale.