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García Castillo, Jesús María

García Castillo, Jesús María

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https://academica-e.unavarra.es/handle/2454/49075

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García Castillo

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Jesús María

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Ciencias

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InaMat2. Instituto de Investigación en Materiales Avanzados y Matemáticas

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0000-0001-6632-097X

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Mielgo, Antonia

1 Badiola, Eider

1 García Castillo, Jesús María

1 Iriarte, Igor

1 Odriozola Ibarguren, José Manuel

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Asymmetric organocatalysis

1 Brønsted bases

1 Michael reactions

1 Quaternary stereocenters

1 Stereoselective protonation

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Open Access
Asymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalent
(Wiley, 2016) Iriarte, Igor; Vera, Silvia; Badiola, Eider; Mielgo, Antonia; Oiarbide, Mikel; García Castillo, Jesús María; Odriozola Ibarguren, José Manuel; Palomo, Claudio; Química Aplicada; Kimika Aplikatua
An efficient, highly diastereo- and enantioselective assembly of acyclic carbonyl fragments possessing nonadjacent all-carbon tertiary/quaternary stereoarrays is reported based on a Brønsted base catalyzed Michael addition/a-protonation sequence involving a-cyanoacetates and 2,4-dimethyl-4-hydroxypenten-3-one as novel methacrylate equivalent.

Con la colaboración del Ministerio de Ciencia e Innovación y de la Fundación Española para la Ciencia y la Tecnología (FECYT).

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