Open Access
Functionalized electrospun fibers for the design of novel hydrophobic and anticorrosive surfaces
(MDPI, 2018) Rivero Fuente, Pedro J.; Yurrita Silanes, David; Berlanga Labari, Carlos; Rodríguez Trías, Rafael; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, Navarre-PRO-UPNA18 (6107)
In this work, a novel coating was deposited on aluminum alloy samples by using a combination of electrospinning and chemical vapor deposition (CVD-silanization) techniques in order to create a functionalized film with an enhancement of both corrosion resistance and hydrophobicity. The electrospinning technique makes the fabrication of highly crosslinked electrospun fibers possible by the combination of both poly(acrylic acid) and beta-cyclodextrin, respectively, which can be easily functionalized in a further step by using the CVD-silanization process due to the evaporation of a hydrophobic molecule such as 1H,1H,2H,2H-Perflurodecyltriethoxysilane. In addition, the resultant electrospun fibers with a high degree of insolubility have been successfully fabricated and metal oxide nanoparticles (TiO(2)NPs) have been incorporated into the electrospun polymeric solution in order to improve the corrosion protection. The surface morphology has been determined by using light optical microscopy, atomic force microscopy, scanning electron microscopy, and water contact angle (WCA) measurements. The corrosion resistance has been evaluated by using both potentiodynamic polarization and pitting corrosion tests. Finally, the results related to WCA measurements after CVD-silanization corroborate that the surfaces have been successfully functionalized with a hydrophobic behavior in comparison with the electrospinning process, showing a considerable difference in the roughness.
Open Access
Hydrophobic and corrosion behavior of sol-gel hybrid coatings based on the combination of TiO2 NPs and fluorinated chains for aluminum alloys protection
(MDPI, 2018) Rivero Fuente, Pedro J.; Maeztu Redin, Juan Deyo; Berlanga Labari, Carlos; Miguel, Adrián; Rodríguez Trías, Rafael; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, Navarre-PRO-UPNA18-6107-FRRRIO
In this work, layers of a sol-gel hybrid matrix doped with metal oxide nanoparticles (TiO2 NPs) have been deposited on flat samples of AA6061-T6 aluminum alloy using the dip-coating technique, with the aim of obtaining coatings with better anti-corrosive and hydrophobic properties. Two different organic modified silica alkoxides, namely 3-(glycidyloxypropyl)trimethoxysilane (GPTMS) and methyltriethoxysilane (MTEOS), have been used for an adequate entrapment of the metal oxide nanoparticles. In addition, a fluorinated metal-alkoxide precursor has also been added to the hybrid matrix in order to improve the hydrophobic behavior. The experimental results corroborate that the presence of these TiO2 NPs play an important role in the development of the sol-gel hybrid coatings. The water contact angle (WCA) measurements, as well as pencil hardness tests indicate that TiO2 NPs make a considerable increase in the resultant hydrophobicity possible, with better mechanical properties of the coatings. The coating thickness has been measured by cross-section scanning electron microscopy (SEM). In addition, a glow discharge optical emission spectroscopy (GD-OES) analysis has been carried out in order to corroborate the adequate entrapment of the TiO2 NPs into the sol-gel coatings. Finally, potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) have been performed in order to evaluate the corrosion resistance of the coatings. All the results provide insights into the efficacy of the developed sol-gel hybrid coatings for anticorrosive purposes with good mechanical properties.
Open Access
Evaluation of functionalized coatings for the prevention of ice accretion by using icing wind tunnel tests
(MDPI, 2020) Rivero Fuente, Pedro J.; Rodríguez Trías, Rafael; Larumbe Abuin, Silvia; Monteserín, María; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, PJUPNA1929
Ice accretion presents serious safety issues, as airplanes are exposed to supercooled water droplets both on the ground and while flying through clouds in the troposphere. Prevention of icing is a main concern for both developers and users of aircraft. The successful solution of this problem implies the combination of active and passive methods and the use of advanced sensors for early detection of icing and monitoring of ice accretion and de-icing processes. This paper focuses on the development of passive solutions. These include advanced anti-icing coatings deposited by a variety of chemical methods including sol-gel, advanced paints based on polyester combined with fluorinated derivatives and applied by electrostatic spray deposition and conventional silicone-based paints modified by adding alumina nanoparticles. Water contact angle has been measured in all cases, demonstrating the hydrophobic character of the coatings. An ice accretion test has been carried out in a laboratory scale icing wind tunnel (IWT) located in a cold climate chamber. Three different studies have been undertaken: ice accretion measurement, durability of the anti-icing behavior after several icing/de-icing cycles and ice adhesion testing by means of the double lap shear test (DLST) methodology. All the studied coatings have shown significant anti-icing behavior which has been maintained, in some cases, beyond 25 cycles. Although these results are still far from any possible application for aeronautic components, they provide interesting insights for new developments and validate the laboratory scale tests.

Rivero Fuente, Pedro J.

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