Person: Urroz Unzueta, José Carlos
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Urroz Unzueta
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José Carlos
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Ingeniería
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0000-0001-8432-3242
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Publication Open Access Conversion of a commercial gasoline vehicle to run bi-fuel (hydrogen-gasoline)(Elsevier, 2012) Sáinz Casas, David; Diéguez Elizondo, Pedro; Sopena Serna, Carlos; Urroz Unzueta, José Carlos; Gandía Pascual, Luis; Ingeniería; IngeniaritzaBi-fuel internal combustion engine vehicles allowing the operation with gasoline or diesel and hydrogen have great potential for speeding up the introduction of hydrogen in the transport sector. This would also contribute to alleviate the problem of urban air pollution. In this work, the modifications carried out to convert a Volkswagen Polo 1.4 into a bi-fuel (hydrogen-gasoline) car are described. Changes included the incorporation of a storage system based on compressed hydrogen, a machined intake manifold with a low-pressure accumulator where the hydrogen injectors were assembled, a new electronic control unit managing operation on hydrogen and an electrical junction box to control the change from a fuel to another. Change of fuel is very simple and does not require stopping the car. Road tests with hydrogen fuel gave a maximum speed of 125 km/h and an estimated consumption of 1 kg of hydrogen per 100 km at an average speed of 90 km/h. Vehicle conversion to bi-fuel operation is technically feasible and cheap.Publication Open Access Acoustic and psychoacoustic levels from an internal combustion engine fueled by hydrogen vs. gasoline(Elsevier, 2022) Arana Burgui, Miguel; San Martín Murugarren, Ricardo; Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Gandía Pascual, Luis; Zientziak; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate PublikoaWhereas noise generated by road traffic is an important factor in urban pollution, little attention has been paid to this issue in the field of hydrogen-fueled vehicles. The objective of this study is to analyze the influence of the type of fuel (gasoline or hydrogen) on the sound levels produced by a vehicle with an internal combustion engine. A Volkswagen Polo 1.4 vehicle adapted for its bi-fuel hydrogen-gasoline operation has been used. Tests were carried out with the vehicle when stationary to eliminate rolling and aerodynamic noise. Acoustics and psychoacoustics levels were measured both inside and outside the vehicle. A slight increase in the noise level has only been found outside when using hydrogen as fuel, compared to gasoline. The increase is statistically significant, can be quantified between 1.1 and 1.7 dBA and is mainly due to an intensification of the 500 Hz band. Loudness is also higher outside the vehicle (between 2 and 4 sones) when the fuel is hydrogen. Differences in sharpness and roughness values are lower than the just-noticeable difference (JND) values of the parameters. Higher noise levels produced by hydrogen can be attributed to its higher reactivity compared to gasoline.Publication Open Access Conversion of a gasoline engine-generator set to a bi-fuel (hydrogen/gasoline) electronic fuel-injected power unit(Elsevier, 2011) Sáinz Casas, David; Diéguez Elizondo, Pedro; Urroz Unzueta, José Carlos; Sopena Serna, Carlos; Guelbenzu Michelena, Eugenio; Pérez Ezcurdia, Amaya; Benito Amurrio, Marta; Marcelino Sádaba, Sara; Arzamendi, G.; Gandía Pascual, Luis; Ingeniería; IngeniaritzaThe modifications performed to convert a gasoline carbureted engine-generator set to a bi-fuel (hydrogen/gasoline) electronic fuel-injected power unit are described. Main changes affected the gasoline and gas injectors, the injector seats on the existing inlet manifold, camshaft and crankshaft wheels with their corresponding Hall sensors, throttle position and oil temperature sensors as well as the electronic management unit. When working on gasoline, the engine-generator set was able to provide up to 8 kW of continuous electric power (10 kW peak power), whereas working on hydrogen it provided up to 5 kW of electric power at an engine speed of 3000 rpm. The air-to-fuel equivalence ratio (λ) was adjusted to stoichiometric (λ = 1) for gasoline. In contrast, when using hydrogen the engine worked ultra-lean (λ = 3) in the absence of connected electric load and richer as the load increased. Comparisons of the fuel consumptions and pollutant emissions running on gasoline and hydrogen were performed at the same engine speed and electric loads between 1 and 5 kW. The specific fuel consumption was much lower with the engine running on hydrogen than on gasoline. At 5 kW of load up to 26% of thermal efficiency was reached with hydrogen whereas only 20% was achieved with the engine running on gasoline. Regarding the NOx emissions, they were low, of the order of 30 ppm for loads below 4 kW for the engine-generator set working on hydrogen. The bi-fuel engine is very reliable and the required modifications can be performed without excessive difficulties thus allowing taking advantage of the well-established existing fabrication processes of internal combustion engines looking to speed up the implementation of the energetic uses of hydrogen.Publication Open Access Comparative performance of coke oven gas, hydrogen and methane in a spark ignition engine(Elsevier, 2020) Ortiz Imedio, Rafael; Ortiz, A.; Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Gorri, D.; Gandía Pascual, Luis; Ortiz, I.; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; IngenieríaIn this study, coke oven gas (COG), a by-product of coke manufacture with a high volumetric percentage of H2 and CH4, has been identified as auxiliary support and promising energy source in stationary internal combustion engines. Engine performance (power and thermal efficiency) and emissions (NOx, CO, CO2 and unburned hydrocarbons) of COG, pure H2 and pure CH4 have been studied on a Volkswagen Polo 1.4 L port-fuel injection spark ignition engine. Experiments have been done at optimal spark advance and wide open throttle, at different speeds (2000–5000 rpm) and various air-fuel ratios (λ) between 1 and 2. The obtained data revealed that COG combines the advantages of pure H2 and pure CH4, widening the λ range of operation from 1 to 2, with very good performance and emissions results comparable to pure gases. Furthermore, it should be highlighted that this approach facilitates the recovery of an industrial waste gas.Publication Open Access Experimental study of the performance and emission characteristics of an adapted commercial four-cylinder spark ignition engine running on hydrogen-methane mixtures(Elsevier, 2014) Diéguez Elizondo, Pedro; Urroz Unzueta, José Carlos; Marcelino Sádaba, Sara; Pérez Ezcurdia, Amaya; Benito Amurrio, Marta; Sáinz Casas, David; Gandía Pascual, Luis; Ingeniería; IngeniaritzaThe use of hydrogen/methane mixtures with low methane contents as fuels for internal combustion engines (ICEs) may help to speed up the development of the hydrogen energy market and contribute to the decarbonization of the transportation sector. In this work, a commercial 1.4 L four-cylinder Volkswagen spark-ignition engine previously adapted to operate on pure hydrogen has been fueled with hydrogen/methane mixtures with 5–20 vol.% methane (29.6–66.7 wt.%). An experimental program has been executed by varying the fuel composition, air-to-fuel ratio (λ), spark advance and engine speed. A discussion of the results regarding the engine performance (brake torque, brake mean effective pressure, thermal efficiency) and emissions (nitrogen oxides, CO and unburned hydrocarbons) is presented. The results reveal that λ is the most influential variable on the engine behavior due to its marked effect on the combustion temperature. As far as relatively high values of λ have to be used to prevent knock, the effect on the engine performance is negative. In contrast, the specific emissions of nitrogen oxides decrease due to a reduced formation of thermal NOx. A clear positive effect of reducing the spark advance on the specific NOx emissions has been observed as well. As concerns CO and unburned hydrocarbons (HCs), their specific emissions increase with the methane content of the fuel mixture, as expected. However, they also increase as λ increases in spite of the lower fuel concentration due to a proportionally higher reduction of the power. Finally, the effect of the increase of the engine speed is positive on the CO and HCs emissions but negative on that of NOx due to improved mixing and higher temperature associated to intensified turbulence in the cylinders.Publication Open Access Gaseous fueling of an adapted commercial automotive spark-ignition engine: simplified thermodynamic modeling and experimental study running on hydrogen, methane, carbon monoxide and their mixtures(Elsevier, 2023) Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Arzamendi Manterola, María Cruz; Arana Burgui, Miguel; Gandía Pascual, Luis; Ingeniería; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Zientziak; Universidad Pública de Navarra / Nafarroako Unibertsitate PublikoaIn the present work, methane, carbon monoxide, hydrogen and the binary mixtures 20 % CH4–80 % H2, 80 % CH4–20 % H2, 25 % CO–75 % H2 (by volume) were considered as fuels of a naturally aspirated port-fuel injection four-cylinder Volkswagen 1.4 L spark-ignition (SI) engine. The interest in these fuels lies in the fact that they can be obtained from renewable resources such as the fermentation or gasification of residual biomasses as well as the electrolysis of water with electricity of renewable origin in the case of hydrogen. In addition, they can be used upon relatively easy modifications of the engines, including the retrofitting of existing internal combustion engines. It has been found that the engine gives similar performance regardless the gaseous fuel nature if the air–fuel equivalence ratio (λ) is the same. Maximum brake torque and mean effective pressure values within 45–89 N⋅m and 4.0–8.0 bar, respectively, have been obtained at values of λ between 1 and 2 at full load, engine speed of 2000 rpm and optimum spark-advance. In contrast, the nature of the gaseous fuel had great influence upon the range of λ values at which a fuel (either pure or blend) could be used. Methane and methane-rich mixtures with hydrogen or carbon monoxide allowed operating the engine at close to stoichiometric conditions (i.e. 1 < λ < 1.5) yielding the highest brake torque and mean effective pressure values. On the contrary, hydrogen and hydrogen-rich mixtures with methane or carbon monoxide could be employed only in the very fuel-lean region (i.e. 1.5 < λ < 2). The behavior of carbon monoxide was intermediate between that of methane and hydrogen. The present study extends and complements previous works in which the aforementioned fuels were compared only under stoichiometric conditions in air (λ = 1). In addition, a simple zero-dimensional thermodynamic combustion model has been developed that allows describing qualitatively the trends set by the several fuels. Although the model is useful to understand the influence of the fuels properties on the engine performance, its predictive capability is limited by the simplifications made.Publication Open Access Characterization of combustion anomalies in a hydrogen-fueled 1.4 L commercial spark-ignition engine by means of in-cylinder pressure, block-engine vibration, and acoustic measurements(Elsevier, 2018) Diéguez Elizondo, Pedro; Urroz Unzueta, José Carlos; Sáinz Casas, David; Machin, J.; Arana Burgui, Miguel; Gandía Pascual, Luis; Institute for Advanced Materials and Mathematics - INAMAT2Abnormal combustion phenomena are among the main hurdles for the introduction of hydrogen in the transportation sector through the use of internal combustion engines (ICEs). For that reason the challenge is to guarantee operation free from combustion anomalies at conditions close to the ones giving the best engine output (maximum brake torque and power). To this end, an early and accurate detection of abnormal combustion events is decisive in order to allow the electronic control unit deciding suitable correcting actions. In this work, an automotive size 4-cylinder 1.4 L naturally aspirated port-fuel injection spark ignition Volkswagen engine adapted to run on hydrogen has been investigated. Three distinct methods (in-cylinder pressure, block-engine vibration and acoustic measurements) have been employed to detect abnormal combustion phenomena provoked through the enrichment of the hydrogen-air mixture fed to the cylinders under a wide range of engine speeds (1000–5000 rpm). It has been found that the high-frequency components of the in-cylinder pressure and block engine acceleration signals obtained after a Fourier transform analysis can be used for very sensitive detection of knocking combustion cycles. In the case of the ambient noise measurements, a spectral analysis in terms of third octave bands of the signal recorded by a microphone allowed an accurate characterization. Combustion anomalies could be detected through more intense octave bands at frequencies between 250 Hz and 4 kHz in the case of backfire and between 8 kHz and 20 kHz for knock. Computational fluid dynamics simulations performed indicated that some characteristics of the engine used such as the cylinder valves dimensions and the hydrogen flow rate delivered by the injectors play important roles conditioning the likelihood of suffering backfire events.Publication Open Access Conversion of a commercial spark ignition engine to run on hydrogen: performance comparison using hydrogen and gasoline(Elsevier, 2010) Sopena Serna, Carlos; Diéguez Elizondo, Pedro; Sáinz Casas, David; Urroz Unzueta, José Carlos; Guelbenzu, E.; Gandía Pascual, Luis; Ingeniería; IngeniaritzaThe modifications performed to convert the spark ignition gasoline-fueled internal combustion engine of a Volkswagen Polo 1.4 to run with hydrogen are described. The car is representative of small vehicles widely used for both city and interurban traffic. Main changes included the inlet manifold, gas injectors, oil radiator and the electronic management unit. Injection and ignition advance timing maps were developed for lean mixtures with values of the air to hydrogen equivalence ratio (λ) between 1.6 and 3. The established engine control parameters allowed the safe operation of the hydrogen-fueled engine (H2ICE) free of knock, backfire and pre-ignition as well with reasonably low NOx emissions. The H2ICE reached best brake torque of 63 Nm at 3800 rpm and maximum brake power of 32 kW at 5000 rpm. In general, the brake thermal efficiency of the H2ICE is greater than that of gasoline-fueled engine except for the H2ICE working at very lean conditions (λ = 2.5) and high speeds (above 4000 rpm). A significant effect of the spark advance on the NOx emissions has been found, specially for relatively rich mixtures (λ < 2). Small changes of spark advance with respect to the optimum value for maximum brake torque give rise to an increase of pollutant emissions. It has been estimated that the hydrogen-fueled Volkswagen Polo could reach a maximum speed of 140 km/h with the adapted engine. Moreover, there is enough reserve of power for the vehicle moving on typical urban routes and routes with slopes up to 10%.Publication Open Access Comparative study of supported Ni and Co catalysts prepared using the All-in-One method in the hydrogenation of CO2: effects of using (Poly)Vinyl Alcohol (PVA) as an additive(MDPI, 2024) Navarrete Rodríguez, Luisa Fernanda; Atienza Martínez, María; Reyero Zaragoza, Inés; Urroz Unzueta, José Carlos; Amorrortu, Oihana; Sanz Iturralde, Oihane; Montes, Mario; Garcés, Siby I.; Bimbela Serrano, Fernando; Gandía Pascual, Luis; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; IngeniaritzaTwo series of Ni and Co catalysts supported onto La-Al2O3 were prepared and the CO2 hydrogenation reactions investigated. The catalytic performance was evaluated in terms of the evolution with the reaction temperature of the CO2 conversion and product (CH4 and CO) yields, as well as specific activities (TOF) and apparent activation energies. CH4 was the favored product over both metals while the TOF for CH4 formation was about three times higher for Ni than Co at 240–265 °C. Metallic particle size effects were found, with the TOF for CH4 formation decreasing over both Ni and Co as the mean metallic size decreased. In contrast, the TOF for CO formation tended to increase at a decreasing particle size for the catalysts with the smallest Ni particle sizes. The apparent activation energies for Ni and Co were very similar and significantly decreased to values of 73–79 kJ/mol when the metallic dispersion increased. The catalysts were prepared using the all-in-one method, resulting in (poly)vinyl alcohol (PVA) being a key additive that allowed us to enhance the dispersion of Ni and Co to give very effective catalysts. This comparative study joins the few existing ones in the literature in which catalysts based on these metals operated under strictly the same reaction conditions.