Person: Urroz Unzueta, José Carlos
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Urroz Unzueta
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José Carlos
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Ingeniería
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0000-0001-8432-3242
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Publication Open Access Gaseous fueling of an adapted commercial automotive spark-ignition engine: simplified thermodynamic modeling and experimental study running on hydrogen, methane, carbon monoxide and their mixtures(Elsevier, 2023) Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Arzamendi Manterola, María Cruz; Arana Burgui, Miguel; Gandía Pascual, Luis; Ingeniería; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Zientziak; Universidad Pública de Navarra / Nafarroako Unibertsitate PublikoaIn the present work, methane, carbon monoxide, hydrogen and the binary mixtures 20 % CH4–80 % H2, 80 % CH4–20 % H2, 25 % CO–75 % H2 (by volume) were considered as fuels of a naturally aspirated port-fuel injection four-cylinder Volkswagen 1.4 L spark-ignition (SI) engine. The interest in these fuels lies in the fact that they can be obtained from renewable resources such as the fermentation or gasification of residual biomasses as well as the electrolysis of water with electricity of renewable origin in the case of hydrogen. In addition, they can be used upon relatively easy modifications of the engines, including the retrofitting of existing internal combustion engines. It has been found that the engine gives similar performance regardless the gaseous fuel nature if the air–fuel equivalence ratio (λ) is the same. Maximum brake torque and mean effective pressure values within 45–89 N⋅m and 4.0–8.0 bar, respectively, have been obtained at values of λ between 1 and 2 at full load, engine speed of 2000 rpm and optimum spark-advance. In contrast, the nature of the gaseous fuel had great influence upon the range of λ values at which a fuel (either pure or blend) could be used. Methane and methane-rich mixtures with hydrogen or carbon monoxide allowed operating the engine at close to stoichiometric conditions (i.e. 1 < λ < 1.5) yielding the highest brake torque and mean effective pressure values. On the contrary, hydrogen and hydrogen-rich mixtures with methane or carbon monoxide could be employed only in the very fuel-lean region (i.e. 1.5 < λ < 2). The behavior of carbon monoxide was intermediate between that of methane and hydrogen. The present study extends and complements previous works in which the aforementioned fuels were compared only under stoichiometric conditions in air (λ = 1). In addition, a simple zero-dimensional thermodynamic combustion model has been developed that allows describing qualitatively the trends set by the several fuels. Although the model is useful to understand the influence of the fuels properties on the engine performance, its predictive capability is limited by the simplifications made.Publication Open Access Acoustic and psychoacoustic levels from an internal combustion engine fueled by hydrogen vs. gasoline(Elsevier, 2022) Arana Burgui, Miguel; San Martín Murugarren, Ricardo; Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Gandía Pascual, Luis; Zientziak; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate PublikoaWhereas noise generated by road traffic is an important factor in urban pollution, little attention has been paid to this issue in the field of hydrogen-fueled vehicles. The objective of this study is to analyze the influence of the type of fuel (gasoline or hydrogen) on the sound levels produced by a vehicle with an internal combustion engine. A Volkswagen Polo 1.4 vehicle adapted for its bi-fuel hydrogen-gasoline operation has been used. Tests were carried out with the vehicle when stationary to eliminate rolling and aerodynamic noise. Acoustics and psychoacoustics levels were measured both inside and outside the vehicle. A slight increase in the noise level has only been found outside when using hydrogen as fuel, compared to gasoline. The increase is statistically significant, can be quantified between 1.1 and 1.7 dBA and is mainly due to an intensification of the 500 Hz band. Loudness is also higher outside the vehicle (between 2 and 4 sones) when the fuel is hydrogen. Differences in sharpness and roughness values are lower than the just-noticeable difference (JND) values of the parameters. Higher noise levels produced by hydrogen can be attributed to its higher reactivity compared to gasoline.Publication Open Access Aumento de potencia en un motor comercial de encendido provocado alimentado con hidrógeno: mezclas hidrógeno-metano y combustiones anómalas(2020) Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Gandía Pascual, Luis; Ingeniería; IngeniaritzaEste trabajo se ha centrado en el aumento de potencia de un motor comercial de encendido provocado alimentado con hidrógeno. La extremadamente baja densidad del hidrógeno conlleva una menor potencia, frente a otros combustibles como la gasolina, por unidad de cilindrada del motor. Con el objetivo de paliar esta deficiencia, el presente trabajo se centra en dos líneas de investigación. En primer lugar, se estudian las mezclas de hidrógeno con metano, compuesto éste de alto contenido energético por unidad de volumen. En segundo lugar, se analizan las combustiones anómalas, problemática inherente a los combustibles, pero muy determinante para el hidrógeno debido a su elevada reactividad química.Publication Open Access Aluminum coated fiber optic sensor for enhancing flow rate measurement(SPIE, 2023) Rodríguez Rodríguez, Armando; Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Bravo Acha, Mikel; López-Amo Sáinz, Manuel; López Rodríguez, José Javier; Ingeniería; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio IngeniaritzarenA water flow and velocity aluminum-coated Fiber Bragg Grating sensor system for open channels was designed, simulated and tested. The sensing head was designed, ruggedized and customized to measure velocities at different depths, in order to calculate the discharge in open channels. This paper shows, for the first time to our knowledge, the simulation of such kind of fiber sensors in open channels.Publication Open Access Comparative performance of coke oven gas, hydrogen and methane in a spark ignition engine(Elsevier, 2020) Ortiz Imedio, Rafael; Ortiz, A.; Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Gorri, D.; Gandía Pascual, Luis; Ortiz, I.; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; IngenieríaIn this study, coke oven gas (COG), a by-product of coke manufacture with a high volumetric percentage of H2 and CH4, has been identified as auxiliary support and promising energy source in stationary internal combustion engines. Engine performance (power and thermal efficiency) and emissions (NOx, CO, CO2 and unburned hydrocarbons) of COG, pure H2 and pure CH4 have been studied on a Volkswagen Polo 1.4 L port-fuel injection spark ignition engine. Experiments have been done at optimal spark advance and wide open throttle, at different speeds (2000–5000 rpm) and various air-fuel ratios (λ) between 1 and 2. The obtained data revealed that COG combines the advantages of pure H2 and pure CH4, widening the λ range of operation from 1 to 2, with very good performance and emissions results comparable to pure gases. Furthermore, it should be highlighted that this approach facilitates the recovery of an industrial waste gas.Publication Open Access Development of a water flow and velocity optical fiber sensor for field testing(Optica Publishing Group, 2022) Rodríguez Rodríguez, Armando; Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Bravo Acha, Mikel; López-Amo Sáinz, Manuel; López Rodríguez, José Javier; Ingeniería; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio IngeniaritzarenA water flow and velocity fiber optic sensor system was developed and tested. The sensing head was especially developed and ruggedized to measure velocities at different depths, in order to calculate the discharge in channels.Publication Open Access Optical fiber sensor for water velocity measurement in rivers and channels(Nature Research, 2024) Rodríguez Rodríguez, Armando; Diéguez Elizondo, Pedro; Urroz Unzueta, José Carlos; Bravo Acha, Mikel; López Rodríguez, José Javier; López-Amo Sáinz, Manuel; Ingeniería; Ingeniaritza; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISCIn this work, optical fiber Bragg grating sensors were used to measure water velocity and examine how it was distributed in open channels. Several types of coatings were incorporated into the design of the sensors to examine their effects on the strain that the fibers experienced as a result of the water flow. Due to their low elastic coefficient, which reduced the hysteresis, the results indicated that the aluminum- and acrylate-coated fibers had the best performance. ANSYS-CFX V2020 R2 software was used to model the strain encountered by the fibers under various flow rates to assess the performance of the FBG sensors. The calculations and actual data exhibited good convergence, demonstrating the accuracy of the FBG sensors in determining water velocity. The study illustrated the usability of the proposal in both scenarios by contrasting its application in rivers and channels.Publication Open Access Hydrogen gas-grilling in meat: impact on odor profile and contents of polycyclic aromatic hydrocarbons and volatile organic compounds(MDPI, 2024) Beriain Apesteguía, María José; Gómez Bastida, Inmaculada; García Murillo, Susana; Urroz Unzueta, José Carlos; Diéguez Elizondo, Pedro; Ibáñez Moya, Francisco C.; Ingeniería; Ingeniaritza; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Ciencias; ZientziakThe effect of fuel (hydrogen vs. butane) on the formation of volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs) was evaluated for grilled horse meat (very low-fat and low-fat) cooking vertically. Gas chromatography-mass spectrometry was used to analyze PAHs and VOCs. An electronic nose was used to evaluate the odor profile. Total high-molecular-weight PAHs ranged from 19.59 to 28.65 µg/kg with butane and from 1.83 to 1.61 µg/kg with hydrogen. Conversely, total low-molecular-weight PAHs went from 184.41 to 286.03 µg/kg with butane and from 36.88 to 41.63 µg/kg with hydrogen. Aldehydes and alkanes were the predominant family in a total of 59 VOCs. Hydrogen gas-grilling reduced significantly (p < 0.05) the generation of VOCs related to lipid oxidation. The odor profile was not modified significantly despite the change of PAHs and VOCs. The findings indicate that hydrogen is a viable alternative to butane for grilling horse meat. Hydrogen gas-grilling may be regarded as a safe cooking procedure of meat from a PAH contamination point and perhaps sustainable environmentally compared to a conventional technique. The present study provides the basis for the use of hydrogen gas in grilled meat.Publication Open Access Design of optical fiber Bragg grating-based sensors for flow measurement in pipes(Taylor & Francis, 2023) Diéguez Elizondo, Pedro; Rodríguez Rodríguez, Armando; Urroz Unzueta, José Carlos; López Rodríguez, José Javier; López-Amo Sáinz, Manuel; Ingeniería; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio IngeniaritzarenIn this work, optical Fiber Bragg grating (FBG) sensors were used to measure water flow in pipes. Several types of coatings were incorporated into the design of the sensors to examine their effects on the elastic strain that the fiber underwent as a result of the water flow. ANSYS-CFX V2020 R2 software was used to model the elastic strain encountered by the fiber under various flow rates in order to assess the performance of the FBG sensors. The calculations and experimental data exhibited good convergence, demonstrating the accuracy of the FBG sensors in determining water flow. These calculations and procedures can be extrapolated to any other fluid.Publication Open Access Comparative study of supported Ni and Co catalysts prepared using the All-in-One method in the hydrogenation of CO2: effects of using (Poly)Vinyl Alcohol (PVA) as an additive(MDPI, 2024) Navarrete Rodríguez, Luisa Fernanda; Atienza Martínez, María; Reyero Zaragoza, Inés; Urroz Unzueta, José Carlos; Amorrortu, Oihana; Sanz Iturralde, Oihane; Montes, Mario; Garcés, Siby I.; Bimbela Serrano, Fernando; Gandía Pascual, Luis; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; IngeniaritzaTwo series of Ni and Co catalysts supported onto La-Al2O3 were prepared and the CO2 hydrogenation reactions investigated. The catalytic performance was evaluated in terms of the evolution with the reaction temperature of the CO2 conversion and product (CH4 and CO) yields, as well as specific activities (TOF) and apparent activation energies. CH4 was the favored product over both metals while the TOF for CH4 formation was about three times higher for Ni than Co at 240–265 °C. Metallic particle size effects were found, with the TOF for CH4 formation decreasing over both Ni and Co as the mean metallic size decreased. In contrast, the TOF for CO formation tended to increase at a decreasing particle size for the catalysts with the smallest Ni particle sizes. The apparent activation energies for Ni and Co were very similar and significantly decreased to values of 73–79 kJ/mol when the metallic dispersion increased. The catalysts were prepared using the all-in-one method, resulting in (poly)vinyl alcohol (PVA) being a key additive that allowed us to enhance the dispersion of Ni and Co to give very effective catalysts. This comparative study joins the few existing ones in the literature in which catalysts based on these metals operated under strictly the same reaction conditions.