Martínez Hernández, María ElenaGoicoechea Fernández, JavierRivero Fuente, Pedro J.Sandúa Fernández, XabierArregui San Martín, Francisco Javier2022-07-212022-07-212022Martínez-Hernández, M. E.; Goicoechea, J.; Rivero, P. J.; Sandua, X.; Arregui, F. J. (2022). Self-referenced optical fiber sensor based on LSPR generated by gold and silver nanoparticles embedded in layer-by-layer nanostructured coatings. Chemosensors. 10,22227-904010.3390/chemosensors10020077https://academica-e.unavarra.es/handle/2454/43382In this work, an optical fiber sensor based on the localized surface plasmon resonance (LSPR) phenomenon has been designed for the detection of two different chemical species (mercury and hydrogen peroxide) by using Layer-by-Layer Embedding (LbL-E) as a nanofabrication technique. In the first step, silver nanoparticles (AgNPs) and gold nanoparticles (AuNPs) have been synthesized by using a chemical protocol as a function of the strict control of three main parameters, which were polyelectrolyte concentration, a loading agent, and a reducing agent. In the second step, their incorporation into nanometric thin films have been demonstrated as a function of the number of bilayers, which shows two well-located absorption peaks associated to their LSPR in the visible region at 420 nm (AgNPs) and 530 nm (AuNPs). Finally, both plasmonic peaks provide a stable real-time reference measurement, which can be extracted from the spectral response of the optical fiber sensor, which shows a specific sensing mechanism as a function of the analyte of study.13 p.application/pdfeng© 2022 by the authors. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) licenseFiber optic sensorGold nanoparticlesHydrogen peroxideLayer-by-Layer EmbeddingLocalized surface plasmon resonanceMercurySilver nanoparticlesinfo:eu-repo/semantics/article2022-07-18info:eu-repo/semantics/openAccess