Browsing by Subject "Jahn-Teller distortion"
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The effect of the orientation of the Jahn-Teller distortion on the magnetic interactions of trinuclear mixed-valence Mn(II)/Mn(III) complexes
Two new trinuclear manganese complexes, [Mn3(L1)(μ-OCH3)2(N3)2]·CH3OH (1) and [Mn3(L2)(μ-OCH3)2(N3)2]·CH3OH (2), have been obtained from the reaction of Mn(OAc)2 4H2O, NaN3 and the preformed N6O4-donor H4L1 or H4L2 ...