Study and optimization of self-assembled polymeric multilayer structures with neutral red for pH sensing applications
Fecha
2008Autor
Versión
Acceso abierto / Sarbide irekia
Tipo
Artículo / Artikulua
Versión
Versión publicada / Argitaratu den bertsioa
Impacto
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10.1155/2008/142854
Resumen
The characterization of nanostructured thin films is critical in the design and fabrication of optical sensors. Particularly, this work is a detailed study of the properties of layer-by-layer electrostatic self-assembled multilayer (LbL) structures fabricated using poly(allylamine hydrochloride) (PAH) and Neutral Red (NR) as cations, and poly(acrylic acid) (PAA) as polyanion. These LbL films, due ...
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The characterization of nanostructured thin films is critical in the design and fabrication of optical sensors. Particularly, this work is a detailed study of the properties of layer-by-layer electrostatic self-assembled multilayer (LbL) structures fabricated using poly(allylamine hydrochloride) (PAH) and Neutral Red (NR) as cations, and poly(acrylic acid) (PAA) as polyanion. These LbL films, due to the colorimetric properties of the NR, are suitable for sensor applications such as pH sensing in the physiological range. In the (PAH+NR/PAA) LbL structure, it has been observed a very important influence of the pH of the solutions in the properties of the resultant films. Different techniques such as spectroscopy and atomic force microscopy (AFM) are combined to characterize the films, and the results are analyzed showing coherence with previous works. The LbL structure is finally optimized and dramatically improved nanostructured films were fabricated, showing good sensing properties, short response times, and good stability. [--]
Materias
Nanostructured thin films,
LbL structures,
Neutral red,
pH sensing
Editor
Hindawi / Wiley
Publicado en
Journal of Sensors, Volume 2008, Article ID 142854
Departamento
Universidad Pública de Navarra. Departamento de Ingeniería Eléctrica y Electrónica /
Nafarroako Unibertsitate Publikoa. Ingeniaritza Elektrikoa eta Elektronikoa Saila
Versión del editor
Entidades Financiadoras
This work was supported in part by the Spanish CICYT-FEDER Research Grant TEC2006-12170/MIC.