Show simple item record

dc.creatorTimofeeva, Maria N.es_ES
dc.creatorKalashnikova, Galina O.es_ES
dc.creatorShefer, Kristina I.es_ES
dc.creatorMel'gunova, Elena A.es_ES
dc.creatorPanchenko, Valentina N.es_ES
dc.creatorNikolaev, Anatoliy I.es_ES
dc.creatorGil Bravo, Antonioes_ES
dc.date.accessioned2020-05-26T13:13:04Z
dc.date.available2022-03-01T00:00:16Z
dc.date.issued2020
dc.identifier.issn0169-1317
dc.identifier.urihttps://hdl.handle.net/2454/36984
dc.description.abstractIn this work we investigated the microporous layered titanosilicate AM-4 (Aveiro-Manchester material number 4) of a synthetic analogous the mineral Lintisite having edge-shared brookite-type TiO6 chains. The objective of our work was to verify the effects of the acid activation on the AM-4 properties, treated with 0.0625–0.25 M HNO3. The results of the physicochemical characterization by SEM, XRD, IR and DR UV–vis spectroscopy, nitrogen adsorption/desorption at 77 K have provided evidences that texture, chemical composition, structural and physicochemical properties of AM-4 could be adjusted by treatment with 0.0625–0.25 M HNO3. According to the method of mass titration, surface acidity (pHPZC) of AM-4 roses with increasing HNO3 concentration, which was in accord with the increase of the reaction rate and yield of 1,5-benzodiazepine in the reaction of cyclocondansation between 1,2-phenylenediamine and acetone.en
dc.description.sponsorshipThis work was conducted within the framework of the budget projects АААА-А17-117041710082-8 for Boreskov Institute of Catalysis and AAAA-A17-117020110075-1 for Nanomaterials Research Centre of the Federal Research Centre 'Kola Science Centre of the Russian Academy of Sciences' (NMRC KSC RAS), respectively. AG thanks Santander Bank for funding through the Research Intensification Program.en
dc.format.extent31 p.
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherElsevieren
dc.relation.ispartofApplied Clay Science, 2020, 186, 105445en
dc.rights© 2020 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectLayered titanosilicate AM-4en
dc.subjectAcid treatmenten
dc.subject1,5-benzodiazepineen
dc.subject1,2-phenylenediamineen
dc.subjectCyclocondensation reactionen
dc.titleEffect of the acid activation on a layered titanosilicate AM-4: the fine-tuning of structural and physicochemical propertiesen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeArtículo / Artikuluaes
dc.contributor.departmentZientziakeu
dc.contributor.departmentInstitute for Advanced Materials and Mathematics - INAMAT2en
dc.contributor.departmentCienciases_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.rights.accessRightsAcceso abierto / Sarbide irekiaes
dc.embargo.terms2022-03-01
dc.identifier.doi10.1016/j.clay.2020.105445
dc.relation.publisherversionhttps://doi.org/10.1016/j.clay.2020.105445
dc.type.versioninfo:eu-repo/semantics/embargoedAccessen
dc.type.versionVersión aceptada / Onetsi den bertsioaes


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

© 2020 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0
Except where otherwise noted, this item's license is described as © 2020 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0

El Repositorio ha recibido la ayuda de la Fundación Española para la Ciencia y la Tecnología para la realización de actividades en el ámbito del fomento de la investigación científica de excelencia, en la Línea 2. Repositorios institucionales (convocatoria 2020-2021).
Logo MinisterioLogo Fecyt