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dc.creatorSantamaría Arana, Leticiaes_ES
dc.creatorLópez Aizpún, Maríaes_ES
dc.creatorGarcía Padial, Marcoses_ES
dc.creatorVicente, Miguel Ángeles_ES
dc.creatorKorili, Sophia A.es_ES
dc.creatorGil Bravo, Antonioes_ES
dc.date.accessioned2020-05-29T07:13:39Z
dc.date.issued2020
dc.identifier.issn0169-1317
dc.identifier.urihttps://hdl.handle.net/2454/36991
dc.description.abstractThis work reports the synthesis of Zinc-Titanium-Aluminum (ZnTiAl) layered double hydroxides (LDH) with various proportions of Al[sbnd]Ti and a Zn/(Al[sbnd]Ti) molar ratio of 3:1 by the co-precipitation method. Two series, made with commercial aluminum (Al) and aluminum extracted from saline slags (Al*), have been considered. Structural characterization and comparison of the two series has been made using powder X-ray diffraction (PXRD), Nitrogen physisorption at 77 K, Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Thermogravimetry measurements. The adsorption capacity of diclofenac and salicylic acid, as examples of emergent pollutants, by the different LDH on batch and fixed-bed column experiments has been analyzed. The effect of various parameters, such as the pH, the initial concentration of pollutant, the mass of adsorbent and the contact time, on the sorption behavior were studied and compared. The contact time to attain equilibrium for maximum adsorption was found to be between 100 and 400 min. The kinetic and equilibrium results were correlated to several adsorption and isotherm equation models. The synthesized materials were more effective in removing diclofenac than salicylic acid, being Zn6Al*2 the hydrotalcite that showed the highest adsorption capacity. The results showed a new application of a material obtained from the valorization of an industrial waste such as aluminum saline slags.en
dc.description.sponsorshipThis work was funded by the Spanish Ministry of Economy, Industry and Competitiveness (AEI/MINECO), and the European Regional Development Fund (ERDF) through project MAT2016-78863-C2-R and the Government of Navarra through projects PI017-PI039 CORRAL. LS thanks Universidad Pública de Navarra for a pre-doctoral grant. AG also thanks Santander Bank for funding through the Research Intensification Program.en
dc.format.extent43 p.
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherElsevieren
dc.relation.ispartofApplied Clay Science, 2020, 187, 105486en
dc.rights© 2020 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectAluminum industrial wastesen
dc.subjectAdsorption removal of diclofenacen
dc.subjectHydrotalcite from saline slagsen
dc.subjectLayered double hydroxidesen
dc.subjectAdsorption removal of salicylic aciden
dc.titleZn-Ti-Al layered double hydroxides synthesized from aluminum saline slag wastes as efficient drug adsorbentsen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeArtículo / Artikuluaes
dc.contributor.departmentUniversidad Pública de Navarra. Departamento de Cienciases_ES
dc.contributor.departmentNafarroako Unibertsitate Publikoa. Zientziak Sailaeu
dc.contributor.departmentUniversidad Pública de Navarra / Nafarroako Unibertsitate Publikoa. InaMat - Institute for Advanced Materialses_ES
dc.rights.accessRightsinfo:eu-repo/semantics/embargoedAccessen
dc.rights.accessRightsAcceso embargado / Sarbidea bahitua dagoes
dc.embargo.lift2022-03-15
dc.embargo.terms2022-03-15
dc.identifier.doi10.1016/j.clay.2020.105486
dc.relation.projectIDinfo:eu-repo/grantAgreement/ES/1PE/MAT2016-78863en
dc.relation.publisherversionhttps://doi.org/10.1016/j.clay.2020.105486
dc.type.versioninfo:eu-repo/semantics/acceptedVersionen
dc.type.versionVersión aceptada / Onetsi den bertsioaes
dc.contributor.funderGobierno de Navarra / Nafarroako Gobernua, PI017-PI039 CORRALes
dc.contributor.funderUniversidad Pública de Navarra / Nafarroako Unibertsitate Publikoaes


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© 2020 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0
Except where otherwise noted, this item's license is described as © 2020 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0