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Functionalization of 3D printed ABS filters with MOF for toxic gas removal
dc.creator | Pellejero, Ismael | es_ES |
dc.creator | Almazán, Fernando | es_ES |
dc.creator | Lafuente, María | es_ES |
dc.creator | Urbiztondo, Miguel A. | es_ES |
dc.creator | Dobrek, Martin | es_ES |
dc.creator | Bechelany, Mikhael | es_ES |
dc.creator | Julbe, Anne | es_ES |
dc.creator | Gandía Pascual, Luis | es_ES |
dc.date.accessioned | 2020-11-27T08:45:56Z | |
dc.date.available | 2022-09-25T23:00:12Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 1226-086X | |
dc.identifier.uri | https://hdl.handle.net/2454/38796 | |
dc.description.abstract | Acrylonitrile butadiene styrene (ABS) is one of the most extensively used polymer in 3D printing manufacturing due to its competitive thermal and mechanical properties. Recently, a special attention has been devoted to novel ABS composites featuring extra functionalities e.g. in the area of VOC removal. Herein, we report on a facile protocol for the functionalization of 3D printed ABS filters with a MOF (Metal- Organic Framework) material (ZIF-8) targeting the conception of attractive gas filters. The proposed synthesis strategy consists in low temperature ALD (Atomic Layer Deposition) of ZnO on the ABS grid followed by the hydrothermal conversion of ZnO to ZIF-8, both steps being conducted at 60 °C. In such way, the method enables an effective growth of ZIF-8 without altering the stability of the polymeric ABS support. The as-fabricated ABS/ZIF-8 filters offer a promising adsorption behaviour for dimethyl methylphosphonate (~20.4 mg of DMMP per gram of ZIF-8), thus proving their potential for toxic gas capture applications. | en |
dc.description.sponsorship | Financial support from Gobierno de Navarra (grants PC052-23), from MINECO (grant CTQ2016-79419-R) and from the Spanish Ministerio de Ciencia, Innovación y Universidades and the European Regional Development Fund (ERDF/FEDER) (grant RTI2018-096294-B-C31) is gratefully acknowledged. I.P. thanks Obra Social la Caixa, Fundación Caja Navarra and UPNA for his research contracts in the framework of the programs 'Ayudas Postdoctorales' and 'CaptaciónTalento'. L. M. G. wishes to thank Banco de Santander and Universidad Pública de Navarra for their financial support under 'Programa de Intensificación de la Investigación 2018' initiative. | en |
dc.format.extent | 31 p. | |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.relation.ispartof | Journal of Industrial and Engineering Chemistry 89 (2020) 194-203 | en |
dc.rights | © 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0 | en |
dc.subject | ZIF-8 | en |
dc.subject | 3D printing | en |
dc.subject | ABS filter | en |
dc.subject | Atomic layer deposition | en |
dc.subject | VOCs abatement | en |
dc.subject | Gas treatment | en |
dc.title | Functionalization of 3D printed ABS filters with MOF for toxic gas removal | en |
dc.type | info:eu-repo/semantics/article | en |
dc.type | Artículo / Artikulua | es |
dc.contributor.department | Institute for Advanced Materials and Mathematics - INAMAT2 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
dc.rights.accessRights | Acceso abierto / Sarbide irekia | es |
dc.embargo.terms | 2022-09-25 | |
dc.identifier.doi | 10.1016/j.jiec.2020.05.013 | |
dc.relation.projectID | info:eu-repo/grantAgreement/ES/1PE/CTQ2016-79419-R | en |
dc.relation.publisherversion | https://doi.org/10.1016/j.jiec.2020.05.013 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | en |
dc.type.version | Versión aceptada / Onetsi den bertsioa | es |
dc.contributor.funder | Gobierno de Navarra / Nafarroako Gobernua, PC052-23 | es |
dc.contributor.funder | Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa | es |