Artículos de revista DF - FS Aldizkari artikuluak

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Open Access
Polycaprolactone/MSMA composites for magnetic refrigeration applications
(Wiley, 2024-09-06) Sánchez-Alarcos Gómez, Vicente; Khanna, Deepali; La Roca, Paulo Matías; Recarte Callado, Vicente; Lambri, Fernando Daniel; Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Royo Silvestre, Isaac; Urbina Yeregui, Antonio; Pérez de Landazábal Berganzo, José Ignacio; Ciencias; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2
A high filling load (62% weight) printable magnetic composite has been elaborated from the dispersion of magnetocaloric Ni45Mn36.7In13.3Co5 metamagnetic shape memory alloy microparticles into a PCL polymer matrix. The composite material has been prepared by solution method, resulting in a very homogeneous particles dispersion into the matrix. The structural transitions in the polymer are not affected by the addition of the metallic microparticles, which in turn results in a significant increase of the mechanical consistency. The good ductility of the elaborated composite allows its extrusion in flexible printable filaments, from which 3D pieces with complex geometries have been grown. The heat transfer of the composite material has been assessed from finite element simulation. In spite of the achievable magnetocaloric values are moderated with respect to the bulk, numerical simulations confirm that, in terms of heat transference, a PCL/Ni-Mn-In-Co wire is more efficient than a bulk Ni-Mn-In-Co cubic piece containing the same amount of magnetic active material. The quite good magnetocaloric response of the composite and the possibility to print high surface/volume ratio geometries make this material a promising candidate for the development of heat exchangers for clean and efficient magnetic refrigeration applications.
Open Access
Theoretical modeling and experimental verification of the scattering from a ferromagnetic microwire
(IEEE, 2011) Liberal Olleta, Íñigo; Ederra Urzainqui, Íñigo; Gómez Polo, Cristina; Labrador Otamendi, Alberto; Pérez de Landazábal Berganzo, José Ignacio; Gonzalo García, Ramón; Física; Fisika; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa
This contribution presents a theoretical modelling of the scattering of ferromagnetic microwires in free-space and inside a rectangular waveguide, providing both an analytical solution and a physical interpretation of the problem. Special attention is devoted to the impact of the microwire radius and its magnetic properties. Theoretical results have been experimentally verified measuring the reflection, absorption and transmission coefficients of a ferromagnetic microwire inside a rectangular waveguide.
Open Access
Changes in the crystalline degree in neutron irradiated EPDM viewed through infrared spectroscopy and inelastic neutron scattering
(Rede Latino-Americana de Materiais, 2018) Lambri, Osvaldo Agustín; Giordano, E. D.; Bonifacich, Federico Guillermo; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Física; Fisika; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The changes in the degree of crystallinity in commercial Ethylene Propylene Diene rubber-type M (EPDM) irradiated with neutrons at different doses has been studied by means of inelastic neutron scattering and infrared absorption spectroscopy experiments. EPDM samples were taken from the housing of non-ceramic electrical insulators which are used in outdoor transmission lines of 66 kV. Inelastic neutron scattering spectra were recorded at 5 K with an accessible energy-transfer range between 180 - 3500 cm-1. Infrared studies were performed at room temperature with an energy transfer between 4000 - 400 cm-1. Controlled neutron irradiation allows to obtain different volume fraction and size of crystalline zones in EPDM. The obtained results are discussed and correlated with studies of differential scanning calorimetry, dynamic mechanical analysis and positron annihilation lifetime spectroscopy from where the changes in crystallinity in EPDM were indirectly studied. Inelastic neutron scattering studies were not appropriate for determining the changes in the crystallinity degree in neutron irradiated commercial EPDM. In contrast, from infrared absorption spectroscopy the changes in crystallinity could be determined successfully.
Open Access
Study of the martensitic transition in Ni-Mn-Sn-Ti ferromagnetic shape memory alloys
(Rede Latino-Americana de Materiais, 2018) Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Sánchez-Alarcos Gómez, Vicente; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In the present work, mechanical spectroscopy measurements as a function of temperature and strain have been performed in (at.%) Ni50Mn37Sn13-xTix (x=0, 0.5 and 2) ferromagnetic shape memory alloys in order both to study martensitic transition phenomenon and also to determine its temperature of appearance. For mechanical spectroscopy measurements, a five elements piezoelectric device recently developed has been used. In addition, other characterization techniques as, differential thermal analysis and superconducting quantum interference magnetic spectroscopy, were also used. Besides, relaxation processes near the martensitic transition temperature have been also observed.
Open Access
Evolution of magnetic response as a function of annealing temperature in Fe-based alloys
(Rede Latino-Americana de Materiais, 2018) Gargicevich, Damián; Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The magnetic response, coercive force and magnetic induction, in Fe-10at.% Si, Fe-6at.% Al-9at.% Si and Fe-4at.% Al-8at.% Ge alloys as a function of the annealing temperature was determined and correlated to the microstructural state. The microstructural characterization was made through differential thermal analysis, mechanical spectroscopy and neutron thermodiffraction studies. It has been determined that the increase in the order degree and the decrease in the mobility of structural defects lead to a deterioration of the magnetic quality of the alloys above detailed.
Open Access
Influence of defects on the irreversible phase transition in the Fe-Pd doped with Co and Mn
(Rede Latino-Americana de Materiais, 2018) Bonifacich, Federico Guillermo; Lambri, Osvaldo Agustín; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Sánchez-Alarcos Gómez, Vicente; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The appearance of BCT martensite in Fe-Pd-based ferromagnetic shape memory alloys, which develops at lower temperatures than the thermoelastic martensitic transition, deteriorates the shape memory properties. In a previous work performed in Fe70Pd30, it was shown that a reduction in defects density reduces the non thermoelastic FCT-BCT transformation temperature. In the present work, the influence of quenched-in-defects upon the intensity and temperature of the thermoelastic martensitic (FCC-FCT) and the non thermoelastic (FCT-BCT) transitions in Fe-Pd doped with Co and Mn is studied. Differential scanning calorimetric and mechanical spectroscopy studies demonstrate that a reduction in the dislocation density the stability range of the FCC-FCT reversible transformation in Fe67Pd30Co3 and Fe66.8Pd30.7Mn2.5 ferromagnetic shape memory alloys.
Open Access
119Sn Mössbauer spectroscopy for assessing the local stress and defect state towards the tuning of Ni-Mn-Sn alloys
(AIP Publishing, 2017) Unzueta, Iraultza; López García, Javier; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Pérez de Landazábal Berganzo, José Ignacio; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física
The influence of defects and local stresses on the magnetic properties and martensitic transformation in Ni50Mn35Sn15 is studied at macroscopic and atomic scale levels. We show that both the structural and magnetic properties of the alloy are very sensitive to slight microstructural distortions. Even though no atomic disorder is induced by milling, the antiphase boundaries linked to dislocations promote the antiferromagnetic coupling of Mn, resulting in a significant decrease in the saturation magnetization. On the other hand, the temperature range of the transformation is considerably affected by the mechanically induced local stresses, which in turn does not affect the equilibrium temperature between the austenitic and martensitic phases. Finally, we demonstrate that the recovery of the martensitic transformation is directly related to the intensity of the non-magnetic component revealed by 119Sn Mössbauer spectroscopy. This result opens the possibility of quantifying the whole contribution of defects and the local stresses on the martensitic transformation in Ni-Mn-Sn alloys.
Open Access
Thermal degradation of type I collagen from bones
(Tech Science Press, 2016) Lambri, Melania Lucila; Giordano, E. D.; Bozzano, P. B.; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The denaturation processes of collagen in the temperature range between 450 K and 670 K are revealed through studies performed on cow rib bones by means of mechanical spectroscopy, differential scanning calorimetry, thermogravimetry, scanning electron microscopy and infrared spectroscopy. The conformational change of the collagen molecules from a triple helix structure to a random coil was found at around 510 K. It was determined that the transformation is developed through the viscous movement of fibrils with an activation energy of (127 ± 8) kJ/mol. The second stage of massive bulk deterioration of the collagen was found at around 600 K, which leads to the loss of the mechanical integrity of the bulk collagen. In addition, an easy-to-handle viscoelastic procedure for obtaining the activation energy of the denaturation process from mechanical spectroscopy studies was also shown.
Open Access
People exposed to traffic noise in european agglomerations from noise maps: a critical review
(De Gruyter, 2014) Arana Burgui, Miguel; San Martín Murugarren, Ricardo; Salinas Hilburg, Juan Carlos; Física; Fisika
Two of the main objectives of the European Directive on environmental noise are, firstly, to unify acoustic indices for assessing environmental noise and, secondly, to standardize assessment methodologies. The ultimate goal is to objectively and comparably manage the impact and evolution of environmental noise caused both by urban agglomerations and by traffic infrastructures (roads, rails and airports). The use of common indices and methodologies (together with five-year plan assessment required by the authorities in charge) should show how noise pollution levels are evolving plus the effectiveness of corrective measures implemented in the action plans. In this paper, available results from numerous European agglomerations (with particular emphasis on Spanish agglomerations) are compared and analysed. The impact and its evolution are based on the percentage of people exposed to noise. More specifically, it demonstrates the impact caused by road traffic, which proves to be the main noise source in all agglomerations. In many cases, the results are extremely remarkable. In some case, the results are illogical. For such cases, it can be concluded that either assessment methodologies have been significantly amended or the input variables to the calculation programs have been remarkably changed. The uncertainty associated with the results is such that, in our opinion, no conclusions can be drawn concerning the effectiveness of remedial measures designed within the action plans after the Directive’s first implementation Phase.
Open Access
Magnetocaloric effect enhancement driven by intrinsic defects in a Ni45Co5Mn35Sn15 alloy
(Elsevier, 2019) Sánchez-Alarcos Gómez, Vicente; López García, Javier; Unzueta, Iraultza; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Beato López, Juan Jesús; García, José Ángel; Plazaola, Fernando; Rodríguez Velamazán, José Alberto; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física
The influence of mechanically-induced defects on the magnetostructural properties is analyzed in a Ni-Co-Mn-Sn alloy subjected to soft milling and subsequent annealing treatments. It is found that, opposite to what occurs in Ni-Mn-Sn ternary alloys, the annealing treatment affects the magnetic properties in a different way in martensite and in austenite. In particular, the saturation magnetization significantly increases in martensite after annealing whereas just a very slight variation is observed in austenite. This leads to the interesting fact that the presence of microstructural defects, far for worsening, makes the magnetocaloric effect to be higher in the as-milled state than after annealing. This behavior is explained as the result of the combination of the effect of defects on the Mn-Mn distance, the effect of Co on the magnetic exchange coupling between Mn atoms, and the effect of defects on the vibrational entropy change at the martensitic transformation.
Open Access
Strong angular dependence of resonant states in 2D dielectric cylinder rings
(AIP Publishing, 2018) Andueza Unanua, Ángel María; Pérez Conde, Jesús; Sevilla Moróder, Joaquín; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Fisika; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Física
We investigate collective resonators made of dielectric cylinders assembled as two-dimensional regular octagons and decagons. These structures exhibit collective resonance states that change their intensity with the incident radiation angle. While most parts of the spectra present small or even null variation, one of these resonances presents high-sensitivity to the incidence angle. This strong variation is well characterized in terms of the electric field intensity distribution of a resonant state where all the cylinders show the lowest order Mie resonance and the neighbors alternate their polarities. The collective state is optimally excited when radiation impinges on a vertex of the polygonal arrangement of cylinders, while the response decreases to its minimum when the incident field hits an edge (two cylinders at the same time). The resonant state and its high dependence on the excitation incidence angle have been found in both octagonal and decagonal configurations for different dielectric permittivity values. In addition, the scalability of Maxwell equations warranties the same behavior if the whole system is downscaled to terahertz or optic frequencies. The study was performed by finite integration time domain calculations of scattering and transmission for different incidence angles. Experimental measures in the microwave range were taken from photonic molecule prototypes made of centimeter-scale glass cylinders (ϵ = 4.5). We find an overall excellent agreement between measurements and simulations. We propose that photonic molecules made of polygonal rings of dielectric cylinders are an ideal structure to build angle sensors using the strongly varying state that they present.
Open Access
A comprehensive analysis of the absorption spectrum of conducting ferromagnetic wires
(IEEE, 2012) Liberal Olleta, Íñigo; Ederra Urzainqui, Íñigo; Gómez Polo, Cristina; Labrador Otamendi, Alberto; Pérez de Landazábal Berganzo, José Ignacio; Gonzalo García, Ramón; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Física; Fisika
A detailed analysis of the absorption spectrum of conductive ferromagnetic wires is presented. The absorption spectrum is computed from the solution to the scattering problem, and circuit models are formulated to clarify the interplay between losses, skin-effect and wire geometry. Both infinitely-long wires and the axial resonances introduced by finite-length wires are considered. The theoretical results are validated experimentally through measurements within a metallic rectangular waveguide.
Open Access
Uncertainties caused by source directivity in room-acoustic investigations
(Acoustical Society of America (ASA), 2008) San Martín Murugarren, Ricardo; Arana Burgui, Miguel; Física; Fisika
Although deviations in the measurement of acoustic parameters should be lower than the subjectively perceivable change in the corresponding parameter measured, this study reflects that directionality of sound sources could cause wide audience areas to break away from this criterion at high frequencies, even when using dodecahedron loudspeakers which meet the requirements of the ISO 3382 standard. The directivity of four different acoustic sources was measured and the influence of its accurate orientation spatially quantified in five enclosures for speech and music. By means of simulation software, the number of receivers affected by uncertainties greater than difference limens was established.
Open Access
Magnetic transition in nanocrystalline soft magnetic alloys analyzed via ac inductive techniques
(American Physical Society, 2004) Gómez Polo, Cristina; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Vázquez, M.; Hernando, A.; Física; Fisika; Gobierno de Navarra / Nafarroako Gobernua
The magnetic transition in a FeSiBCuNb nanocrystalline alloy, associated with the decoupling of ferromagnetic crystallites around the Curie point of the residual amorphous matrix, is analyzed in this work through the temperature dependence of the ac axial magnetic permeability and impedance of the samples. The temperature dependence of both complex magnitudes presents a maximum in the irreversible contribution at a certain transition temperature. While for low values of the exciting ac magnetic field the transition temperature lies below the Curie temperature of the amorphous phase, a shift above this Curie point is observed increasing the amplitude of the applied ac magnetic field. The detected field dependence is interpreted taking into account the ac nature of the inductive characterization techniques and the actual temperature dependence of the coercivity of the samples.
Open Access
Experimental Stark widths and shifts of Cr II spectral lines
(Oxford University Press, 2013) Aguilera Andoaga, José Antonio; Aragón Garbizu, Carlos; Manrique Rosel, Javier; Física; Fisika
Stark widths and shifts of Cr II lines with wavelengths in the range 2000–3500 Å have been determined by laser-induced breakdown spectroscopy. The spectra have been measured at different instants of the plasma evolution from 0.6 to 3.4 μs, at which the temperature and electron density are in the ranges 12 000–16 300 K and (0.89–8.2) × 10¹⁷ cm ˉ³, respectively. The laser-induced plasmas have been generated from three fused glass samples with different chromium concentrations, selected to control the self-absorption of the lines. The Stark widths and shifts are compared with the experimental and theoretical data available in the literature.
Open Access
A field induced ferromagnetic-like transition below 2.8 K in Li2CuO2: an experimental and theoretical study
(AIP Publishing, 1998) Ortega Hertogs, Ricardo; Jensen, P. J.; Rao, K. V.; Sapiña, F.; Beltrán, D.; Iqbal, Z.; Cooley, J. C.; Smith, J. L.; Física; Fisika
The low temperature magnetic properties of the Li2CuO2 compound have been investigated by means of superconducting quantum interference device magnetometry. We find in addition to an antiferromagnetic phase below 9.5 K a ferromagnetic-like steep rise of the magnetization around 2.8 K. The observed low temperature behavior is discussed by considering second and fourth order magnetocrystalline effective anisotropy coefficients, in addition to the exchange couplings reported in the literature.
Open Access
Study of optical fiber sensors for cryogenic temperature measurements
(MDPI, 2017) Miguel Soto, Verónica de; Leandro González, Daniel; López Aldaba, Aitor; Beato López, Juan Jesús; Pérez de Landazábal Berganzo, José Ignacio; Auguste, Jean-Louis; Jamier, Raphael; Roy, Philippe; López-Amo Sáinz, Manuel; Ingeniaritza Elektrikoa eta Elektronikoa; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica; Física; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In this work, the performance of five different fiber optic sensors at cryogenic temperatures has been analyzed. A photonic crystal fiber Fabry-Pérot interferometer, two Sagnac interferometers, a commercial fiber Bragg grating (FBG), and a -phase shifted fiber Bragg grating interrogated in In this work, the performance of five different fiber optic sensors at cryogenic temperatures has been analyzed. A photonic crystal fiber Fabry-Pérot interferometer, two Sagnac interferometers, a commercial fiber Bragg grating (FBG), and a π-phase shifted fiber Bragg grating interrogated in a random distributed feedback fiber laser have been studied. Their sensitivities and resolutions as sensors for cryogenic temperatures have been compared regarding their advantages and disadvantages. Additionally, the results have been compared with the given by a commercial optical backscatter reflectometer that allowed for distributed temperature measurements of a single mode fiber.
Open Access
Giant direct and inverse magnetocaloric effect linked to the same forward martensitic transformation
(Springer Nature, 2017) Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Sánchez-Alarcos Gómez, Vicente; Beato López, Juan Jesús; Rodríguez Velamazán, José Alberto; Sánchez Marcos, J.; Gómez Polo, Cristina; Cesari, Eduard; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física
Metamagnetic shape memory alloys have aroused considerable attraction as potential magnetic refrigerants due to the large inverse magnetocaloric effect associated to the magnetic-field-induction of a reverse martensitic transformation (martensite to austenite). In some of these alloys, the austenite phase can be retained on cooling under high magnetic fields, being the retained phase metastable after field removing. Here, we report a giant direct magnetocaloric effect linked to the anomalous forward martensitic transformation (austenite to martensite) that the retained austenite undergoes on heating. Under moderate fields of 10 kOe, an estimated adiabatic temperature change of 9 K has been obtained, which is (in absolute value) almost twice that obtained in the conventional transformation under higher applied fields. The observation of a different sign on the temperature change associated to the same austenite to martensite transformation depending on whether it occurs on heating (retained) or on cooling is attributed to the predominance of the magnetic or the vibrational entropy terms, respectively.
Open Access
Loss of ductility due to the decarburation and Mn depletion of a coarse-grained TWIP steel
(Consejo Superior de Investigaciones Científicas (CSIC), 2017) Cuevas Jiménez, Fernando de las; Gil Sevillano, Javier; Física; Fisika
Se ha observado una clara transición de la ductilidad a tracción con el tamaño de grano D del orden 15 μm - 20 μm (1,50 μm ≤ D < 50 μm) en un acero TWIP, 22% de Mn, 0,6% de C (% en masa). Este comportamiento es una combinación de un efecto intrínseco del tamaño de grano D en la resistencia y el endurecimiento por deformación del material, con un efecto extrínseco, proceso de descarburación superficial y pérdida de Mn ocurrido durante los tratamientos de recocido a T ≥ 1000 ºC. En el presente trabajo se ha estudiado en profundidad este efecto extrínseco sucedido en el acero TWIP. Se han realizado análisis por GDOES (Espectroscopia Óptica de Descarga Luminiscente) para estudiar cuantitativamente los perfiles de concentración de C y Mn. La profundidad de descarburación superficial se ha modelizado usando la teoría de Birks-Jackson. Se ha observado vía ferritoscopio que, en el volumen descarburizado, coexisten dos microconstituyentes: α’-martensita y γ-austenita. La ductilidad del acero TWIP de tamaño de grano grosero, sometido a altas temperaturas y largos tiempos de recocido, disminuye como consecuencia de la formación de α’-martensita y γ-austenita menos estable con menor energía de defectos de apilamiento, EDA, debido a la pérdida de Mn en el volumen descarburizado.
Open Access
Entropy change caused by martensitic transformations of ferromagnetic shape memory alloys
(MDPI, 2017) L'vov, Victor A.; Cesari, Eduard; Kosogor, Anna; Torrens Serra, Joan; Recarte Callado, Vicente; Pérez de Landazábal Berganzo, José Ignacio; Física; Fisika
In this paper, our most recent findings on the influence of magnetic order on the main transformational caloric and elastic properties of shape memory alloys (SMAs) are reviewed. It is argued that ferromagnetic order has a strong influence on the temperature interval of martensitic transformation (MT), the characteristics of stress-induced MT, and the shear elastic modulus of SMA. The problem of separation of the magnetic contributions to the entropy change ΔS and heat Q exchanged in the course of martensitic transformation (MT) of SMA is considered in general terms, and theoretical formulas enabling the solution of the problem are presented. As an example, the ΔS and Q values, which were experimentally determined for Ni-Mn-Ga and Ni-Fe-Ga alloys with different Curie temperatures TC and MT temperatures TM, are theoretically analyzed. It is shown that for Ni-Mn-Ga martensites with TM < TC, the ratio of elastic and magnetic contributions to the entropy change may be greater or smaller than unity, depending on the temperature difference TC – TM.