Open Access
Enhancing sensitivity of photonic crystal fiber interferometric humidity sensor by the thickness of SnO2 thin films
(Elsevier, 2017) López Torres, Diego; Elosúa Aguado, César; Villatoro, Joel; Zubia, Joseba; Rothhardt, Manfred; Schuster, Kay; Arregui San Martín, Francisco Javier; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa
Open Access
Nanostructured PbS-doped inorganic film synthesized by sol-gel route
(MDPI, 2022) Nicoara, Adrian Ionut; Eftimie, Mihai; Mihail, Elisa; Vasiliu, Ileana Cristina; Bartha, Cristina; Enculescu, Monica; Filipescu, Mihaela; Elosúa Aguado, César; López Torres, Diego; Sava, Bogdan Alexandru; Oane, Mihai; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación
IV-VI semiconductor quantum dots embedded into an inorganic matrix represent nanostructured composite materials with potential application in temperature sensor systems. This study explores the optical, structural, and morphological properties of a novel PbS quantum dots (QDs)- doped inorganic thin film belonging to the Al2O3 -SiO2 -P2O5 system. The film was synthesized by the sol-gel method, spin coating technique, starting from a precursor solution deposited on a glass substrate in a multilayer process, followed by drying of each deposited layer. Crystalline PbS QDs embedded in the inorganic vitreous host matrix formed a nanocomposite material. Specific investigations such as X-ray diffraction (XRD), optical absorbance in the ultraviolet (UV)-visible (Vis)-near infrared (NIR) domain, NIR luminescence, Raman spectroscopy, scanning electron microscopy– energy dispersive X-ray (SEM-EDX), and atomic force microscopy (AFM) were used to obtain a comprehensive characterization of the deposited film. The dimensions of the PbS nanocrystallite phase were corroborated by XRD, SEM-EDX, and AFM results. The luminescence band from 1400 nm follows the luminescence peak of the precursor solution and that of the dopant solution. The emission of the PbS-doped film in the NIR domain is a premise for potential application in temperature sensing systems.
Open Access
A nanocomposite sol-gel film based on PbS quantum dots embedded into an amorphous host inorganic matrix
(MDPI, 2023) Mihail, Elisa; Sava, Bogdan Alexandru; Eftimie, Mihai; Nicoara, Adrian Ionut; Vasiliu, Ileana Cristina; Rusu, Madalin Ion; Bartha, Cristina; Enculescu, Monica; Kuncser, Andrei Cristian; Oane, Mihai; Elosúa Aguado, César; López Torres, Diego; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
In this study, a sol-gel film based on lead sulfide (PbS) quantum dots incorporated into a host network was synthesized as a special nanostructured composite material with potential applications in temperature sensor systems. This work dealt with the optical, structural, and morphological properties of a representative PbS quantum dot (QD)-containing thin film belonging to the Al2O3–SiO2–P2O5 system. The film was prepared using the sol-gel method combined with the spin coating technique, starting from a precursor solution containing a suspension of PbS QDs in toluene with a narrow size distribution and coated on a glass substrate in a multilayer process, followed by annealing of each deposited layer. The size (approximately 10 nm) of the lead sulfide nanocrystallites was validated by XRD and by the quantum confinement effect based on the band gap value and by TEM results. The photoluminescence peak of 1505 nm was very close to that of the precursor PbS QD solution, which demonstrated that the synthesis route of the film preserved the optical emission characteristic of the PbS QDs. The photoluminescence of the lead sulfide QD-containing film in the near infrared domain demonstrates that this material is a promising candidate for future sensing applications in temperature monitoring.
Open Access
Enhancement of the sensitivity of a volatile organic compounds MOF sensor by means of its structure
(MDPI, 2019) López Torres, Diego; López Aldaba, Aitor; Elosúa Aguado, César; Auguste, Jean-Louis; Jamier, Raphael; Roy, Philippe; López-Amo Sáinz, Manuel; Arregui San Martín, Francisco Javier; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In this paper, we experimentally compare several core structures of Microstructured Optical Fibers (MOFs) for low-finesse Fabry-Pérot (FP) sensors. These sensors are designed for Volatile Organic Compounds (VOCs) measurements. We deposit Indium Tin Oxide (ITO) thin films by sputtering on the MOFs and different optical phase responses of the FP were measured for saturated atmospheres of ethanol. The sensitivity of the developed sensors is demonstrated to depend on the geometry and the dimensions of the MOF-cores. The sensors show recovery times under 100 s and the baselines are fully recovered after exposure to VOC.
Open Access
Micro and nanostructured materials for the development of optical fibre sensors
(MDPI, 2017) Elosúa Aguado, César; Arregui San Martín, Francisco Javier; Del Villar, Ignacio; Ruiz Zamarreño, Carlos; Corres Sanz, Jesús María; Bariáin Aisa, Cándido; Goicoechea Fernández, Javier; Hernáez Sáenz de Zaitigui, Miguel; Rivero Fuente, Pedro J.; Socorro Leránoz, Abián Bentor; Urrutia Azcona, Aitor; Sánchez Zábal, Pedro; Zubiate Orzanco, Pablo; López Torres, Diego; Acha Morrás, Nerea de; Ascorbe Muruzabal, Joaquín; Ozcariz Celaya, Aritz; Matías Maestro, Ignacio; Ingeniaritza Elektrikoa eta Elektronikoa; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica
The measurement of chemical and biomedical parameters can take advantage of the features exclusively offered by optical fibre: passive nature, electromagnetic immunity and chemical stability are some of the most relevant ones. The small dimensions of the fibre generally require that the sensing material be loaded into a supporting matrix whose morphology is adjusted at a nanometric scale. Thanks to the advances in nanotechnology new deposition methods have been developed: they allow reagents from different chemical nature to be embedded into films with a thickness always below a few microns that also show a relevant aspect ratio to ensure a high transduction interface. This review reveals some of the main techniques that are currently been employed to develop this kind of sensors, describing in detail both the resulting supporting matrices as well as the sensing materials used. The main objective is to offer a general view of the state of the art to expose the main challenges and chances that this technology is facing currently.
Open Access
Real time measuring system of multiple chemical parameters using microstructured optical fibers based sensors
(IEEE, 2018) López Aldaba, Aitor; López Torres, Diego; Elosúa Aguado, César; Arregui San Martín, Francisco Javier; Auguste, Jean-Louis; Jamier, Raphael; Roy, Philippe; López-Amo Sáinz, Manuel; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación
In this paper, a multiplexing system for simultaneous interrogation of optical fiber sensors which measure different parameters is presented and validated. The whole system has been tested with 6 different sensing heads with different purposes: one temperature sensing head, two relative humidity sensors and three VOCs leak sensors; all of them based on microstructured optical fibers. The interrogation system uses the FFT technique to isolate each sensor's interference, enabling their simultaneous interrogation. The system interrogates all the sensors at frequencies up to 1 KHz, showing a good performance of each measurement without crosstalk between sensors. The developed system is independent of the sensors' purpose or of the multiplexing topology.
Open Access
Relative humidity multi-point optical sensors system based on Fast Fourier multiplexing technique
(SPIE, 2017) López Aldaba, Aitor; López Torres, Diego; Elosúa Aguado, César; Auguste, Jean-Louis; Jamier, Raphael; Roy, Philippe; Arregui San Martín, Francisco Javier; López-Amo Sáinz, Manuel; Ingeniaritza Elektrikoa eta Elektronikoa; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica
In this paper, a new multipoint optical fiber system for relative humidity measurements based on Sn02-FP (Fabry-Pérot) sensing heads and an optical interrogator as single active device is presented and characterized. The interrogation of the sensing heads is carried out by monitoring the Fast Fourier Transform phase variations of the FP (Fabry-Pérot) interference frequencies. This method allows to multiplex several sensors with different wavelength spacing interference pattern. The sensors operate within a wide humidity range (20%-90% relative humidity) with low crosstalk between them. Five sensing heads have been measured using two different channels of the optical interrogator. The availability of four channels in the interrogator allows to multiplex a higher number of sensors, reducing proportionally the cost of each sensing point.
Open Access
From superhydrophilic to superhydrophobic surfaces by means of polymeric Layer-by-Layer films
(Elsevier, 2015) López Torres, Diego; Elosúa Aguado, César; Hernáez Sáenz de Zaitigui, Miguel; Goicoechea Fernández, Javier; Arregui San Martín, Francisco Javier; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa
Open Access
Microstructured optical fiber sensor for soil moisture measurements
(Optical Society of America, 2018) López Aldaba, Aitor; López Torres, Diego; Campo-Bescós, Miguel; López Rodríguez, José Javier; Yerro Lizarazu, David; Elosúa Aguado, César; Arregui San Martín, Francisco Javier; Auguste, Jean-Louis; Jamier, Raphael; Roy, Philippe; López-Amo Sáinz, Manuel; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniería
A discrete sensor based on a Sn0₂-FP (Fabry-Pérot) cavity is presented and characterized in real soil conditions. Results are compared, for the first time to our knowledge, with a commercial capacitive sensor and gravimetric measurements.
Open Access
Title enhancement of the sensitivity of a volatile organic compounds MOF-sensor by means of its structure
(MDPI, 2017) López Torres, Diego; López Aldaba, Aitor; Elosúa Aguado, César; Auguste, Jean-Louis; Jamier, Raphael; Roy, Philippe; López-Amo Sáinz, Manuel; Arregui San Martín, Francisco Javier; Ingeniaritza Elektrikoa eta Elektronikoa; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería Eléctrica y Electrónica; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In this paper, we experimentally compare several core structures of Microstructured Optical Fibers (MOFs) for low-finesse Fabry-Pérot (FP) sensors. These sensors are designed for Volatile Organic Compounds (VOCs) measurements. We deposit Indium Tin Oxide (ITO) thin films by sputtering on the MOFs and different optical phase responses of the FP were measured for saturated atmospheres of ethanol. The sensitivity of the developed sensors is demonstrated to depend on the geometry and the dimensions of the MOF-cores. The sensors show recovery times under 100 s and the baselines are fully recovered after exposure to VOC.