Open Access
Simulation of thermoelectric heat pumps in nearly zero energy buildings: why do all models seem to be right?
(Elsevier, 2021) Martínez Echeverri, Álvaro; Díaz de Garayo, Sergio; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Catalán Ros, Leyre; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
The use of thermoelectric heat pumps for heat, ventilation, and air conditioning in nearly-zero-energy buildings is one of the most promising applications of thermoelectrics. However, simulation works in the literature are predominately based on the simple model, which was proven to exhibit significant deviations from experimental results. Nine modelling techniques have been compared in this work, according to statistical methods based on uncertainty analysis, in terms of predicted coefficient of performance and cooling power. These techniques come from the combination of three simulation models for thermoelectric modules (simple model, improved model, electric analogy) and five methods for implementing the thermoelectric properties. The main conclusion is that there is no statistical difference in the mean values of coefficient of performance and cooling power provided by these modelling techniques under all the scenarios, at 95% level of confidence. However, differences appear in the precision of these results in terms of uncertainty of the confidence intervals. Minimum values of uncertainty are obtained when the thermal resistance ratio approaches 0.1, being ±8% when using temperature-dependent expressions for the thermoelectric properties, ±18% when using Lineykin's method, and ± 25% when using Chen's method. The best combination is that composed of the simple model and temperature-dependent expressions for the thermoelectric properties. Additionally, if low values of resistance ratio are anticipated, empirical expressions from the literature can be used for the thermal resistance of the heat exchangers; for high values, though, experimental tests should be deployed, especially for the heat exchanger on the hot side.
Open Access
Experimental evidence of the viability of thermoelectric generators to power volcanic monitoring stations
(MDPI, 2020) Catalán Ros, Leyre; Garacochea Sáenz, Amaia; Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Although there is an important lack of commercial thermoelectric applications mainly due to their low efficiency, there exist some cases in which thermoelectric generators are the best option thanks to their well-known advantages, such as reliability, lack of maintenance and scalability. In this sense, the present paper develops a novel thermoelectric application in order to supply power to volcanic monitoring stations, making them completely autonomous. These stations become indispensable in any volcano since they are able to predict eruptions. Nevertheless, they present energy supply difficulties due to the absence of power grid, the remote access, and the climatology. As a solution, this work has designed a new integral system composed of thermoelectric generators with high efficiency heat exchangers, and its associated electronics, developed thanks to Internet of Things (IoT) technologies. Thus, the heat emitted from volcanic fumaroles is transformed directly into electricity with thermoelectric generators with passive heat exchangers based on phase change, leading to a continuous generation without moving parts that powers different sensors, the information of which is emitted via LoRa. The viability of the solution has been demonstrated both at the laboratory and at a real volcano, Teide (Canary Islands, Spain), where a compact prototype has been installed in an 82 C fumarole. The results obtained during more than eight months of operation prove the robustness and durability of the developed generator, which has been in operation without maintenance and under several kinds of meteorological conditions, leading to an average generation of 0.49W and a continuous emission over more than 14 km.
Open Access
The importance of the assembly in thermoelectric generators
(IntechOpen, 2018) Araiz Vega, Miguel; Catalán Ros, Leyre; Herrero Mola, Óscar; Pérez Artieda, Miren Gurutze; Rodríguez García, Antonio; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Generally, in the optimization of thermoelectric generators, only the heat exchangers or the thermoelectric modules themselves are taken into account. However, the assembly of the generator as a whole is of vital importance since a bad contact or a thermal bridge can waste the performance of an optimal generator. In this sense, the present chapter analyzes experimentally the use of different interface materials to reduce the thermal contact resistance between the modules and the heat exchangers, the influence of the pressure distribution in the assembly as well as the effect of different insulating materials in order to reduce the thermal bridge between the exchangers. Thus, it has been demonstrated that a good assembly requires the implementation of thermal interface materials to ensure the microscopic contact between the heat exchangers and the modules, besides a uniform clamping pressure. Nevertheless, since this is normally achieved with screws, they represent a source of thermal bridges in conjunction with the small distance between the exchangers. In order to reduce heat losses due to thermal bridges, which can represent up to one-third of the incoming heat, an increment of the distance between the exchangers and the use of an insulator is recommended.
Open Access
Computational study of geothermal thermoelectric generators with phase change heat exchangers
(Elsevier, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
The use of thermoelectric generators with phase change heat exchangers has demonstrated to be an interesting and environmentally friendly alternative to enhanced geothermal systems (EGS) in shallow hot dry rock fields (HDR), since rock fracture is avoided. The present paper studies the possibilities of the former proposal in a real location: Timanfaya National Park (Canary Islands, Spain), one of the greatest shallow HDR fields in the world, with 5000 m2 of characterized geothermal anomalies presenting temperatures up to 500 °C at only 2 m deep. For this purpose, a computational model based on the thermal-electrical analogy has been developed and validated thanks to a real prototype, leading to a relative error of less than 8%. Based on this model, two prototypes have been designed and studied for two different areas within the park, varying the size of the heat exchangers and the number of thermoelectric modules installed. As a result, the potential of the solution is demonstrated, leading to an annual electricity generation of 681.53 MWh thanks to the scalability of thermoelectric generators. This generation is obtained without moving parts nor auxiliary consumption, thus increasing the robustness of the device and removing maintenance requirements.
Open Access
Experimental validation and development of an advanced computational model of a transcritical carbon dioxide vapour compression cycle with a thermoelectric subcooling system
(Elsevier, 2022) Casi Satrústegui, Álvaro; Aranguren Garacochea, Patricia; Sánchez, Daniel; Araiz Vega, Miguel; Cabello, Ramón; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
The inclusion of a thermoelectric subcooler as an alternative to increment the performance of a vapour compression cycle has been proved promising when properly designed and operated for low-medium power units. In this work, a computational model that simulates the behaviour of a carbon dioxide transcritical vapour compression cycle in conjunction with a thermoelectric subcooler system is presented. The computational tool is coded in Matlab and uses Refprop V9.1 to calculate the properties of the refrigerant at each point of the refrigeration cycle. Working conditions, effect of the heat exchangers of the subcooling system, temperature dependent thermoelectric properties, thermal contact resistances and the four thermoelectric effects are taken into account to increment its accuracy. The model has been validated using experimental data to prove the reliability and accuracy of the results obtained and shows deviations between the ±7% for the most relevant outputs. Using the validated computational tool a 13.6 % COP improvement is predicted when optimizing the total number of thermoelectric modules of the subcooling system. The computational experimentally validated tool is properly fit to aid in the design and operation of thermoelectric subcooling systems, being able to predict the optimal configuration and operation settings for the whole refrigeration plant.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(2021) Alegría Cía, Patricia; Rodríguez García, Antonio; Catalán Ros, Leyre; Astrain Ulibarrena, David; Araiz Vega, Miguel; Ingeniería; Institute of Smart Cities - ISC; Ingeniaritza
Nowadays, geothermal energy in shallow hot dry rocks is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Experimental evaluation of a transcritical CO2 refrigeration facility working with an internal heat exchanger and a thermoelectric subcooler: performance assessment and comparative
(Elsevier, 2022) Casi Satrústegui, Álvaro; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Sánchez, Daniel; Cabello, Ramón; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The use of carbon dioxide in transcritical state has become one of the most used solutions to comply with the F-Gas directive and reduce greenhouse gases emissions from refrigeration systems at high ambient temperatures. For low-medium power units, the commonly used solutions to improve the efficiency such as the ejector, multiple compressor arrangements, mechanical subcooler, etc., add complexity and increase the cost of the refrigeration facility, which is not ideal for small units. In this low-medium power range, two technologies stand out to increase the performance of a carbon dioxide transcritical cycle: the internal heat exchanger and the thermoelectric subcooler. This study brings a complete research in which both solutions have been tested in the same experimental transcritical carbon dioxide refrigeration facility under the same working conditions. It focuses on the real performance of both systems and discusses the strengths and weaknesses of using an internal heat exchanger or a thermoelectric subcooler. The results show that the thermoelectric subcooler outperforms the internal heat exchanger in both the coefficient of performance and the cooling capacity while also being a more controllable and flexible solution.
Open Access
Experimental and computational study on thermoelectric generators using thermosyphons with phase change as heat exchangers
(Elsevier, 2017) Araiz Vega, Miguel; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Mekanika, Energetika eta Materialen Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería Mecánica, Energética y de Materiales
An important issue in thermoelectric generators is the thermal design of the heat exchangers since it can improve their performance by increasing the heat absorbed or dissipated by the thermoelectric modules. Due to its several advantages, compared to conventional dissipation systems, a thermosyphon heat exchanger with phase change is proposed to be placed on the cold side of thermoelectric generators. Some of these advantages are: high heat-transfer rates; absence of moving parts and lack of auxiliary con- sumption (because fans or pumps are not required); and the fact that these systems are wickless. A com- putational model is developed to design and predict the behaviour of this heat exchangers. Furthermore, a prototype has been built and tested in order to demonstrate its performance and validate the compu- tational model. The model predicts the thermal resistance of the heat exchanger with a relative error in the interval [?8.09;7.83] in the 95% of the cases. Finally, the use of thermosyphons with phase change in thermoelectric generators has been studied in a waste-heat recovery application, stating that including them on the cold side of the generators improves the net thermoelectric production by 36% compared to that obtained with finned dissipators under forced convection.
Open Access
Auxiliary consumption: a necessary energy that affects thermoelectric generation
(Elsevier, 2018) Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Astrain Ulibarrena, David; Ingeniería Mecánica, Energética y de Materiales; Mekanika, Energetika eta Materialen Ingeniaritza
Waste heat recovery can apply to a wide range of applications, from transportation, or industries to domestic appliances. Thermoelectric generation technology applied to those cases could produce electrical energy and thus improve their efficiency. A validated computational methodology, which simulates the behavior of any thermoelectric generator and calculates the energy consumption of the auxiliary equipment involved, has been used to determine the potential of waste heat harvesting. The usable energy, the net energy, generated has to be maximized, not only the thermoelectric generation has to be maximized, but also the consumption of the auxiliary equipment has to be minimized, or if possible eliminated. Heat exchangers with a liquid as the heat carrier procure high thermoelectric generations, as their thermal resistances are very low, nevertheless when the consumption of their auxiliary consumption is borne in mind, their use is not that promising. The optimal thermoelectric energy obtained from the flue gases of a real industry using these dissipation systems is 119 MWh/year, while the maximum net energy is 73 MWh/year due to the consumption of the auxiliary equipment. The latest scenario does not only represent a 40% reduction from the optimal thermoelectric generation but also a different optimal working point. The complete elimination of the auxiliary equipment using novel biphasic thermosyphons with free convection at the same application produces a net energy of 128 MWh/year. This novel dissipation technology presents an increase on the thermoelectric generation due to its low thermal resistances, but above all due to the elimination of the auxiliary consumption.
Open Access
Thermoelectric heat recovery in a real industry: from laboratory optimization to reality
(Elsevier, 2021) Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Catalán Ros, Leyre; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2018-000101
Thermoelectricity, in the form of thermoelectric generators, holds a great potential in waste heat recovery, this potential has been studied and proved in several laboratory and theoretical works. By the means of a thermoelectric generator, part of the energy that normally is wasted in a manufacturing process, can be transformed into electricity, however, implementing this technology in real industries still remains a challenge and on-site tests need to be performed in order to prove the real capabilities of this technology. In this work, a computational model to simulate the behaviour of a thermoelectric generator that harvest waste heat from hot fumes is developed. Using the computational model an optimal configuration for a thermoelectric generator is obtained, also an experimental study of the performance of different heat pipes working as cold side heat exchangers is carried out in order to optimize the performance of the whole thermoelectric generator, thermal resistances of under 0,25 K/W are obtained. The optimized configuration of the thermoelectric generator has been built, installed and tested under real conditions at a rockwool manufacturing plant and experimental data has been obtained during the 30 days field test period. Results show that 4.6 W of average electrical power are produced during the testing period with an efficiency of 2.38%. Moreover, the computational model is validated using this experimental data. Furthermore, the full harvesting potential of an optimized designed that takes advantage of the whole pipe is calculated using the validated computational model, resulting in 30.8 MWh of energy harvested during a sample year which could meet the demand of 8.34 Spanish average households.