Open Access
Modelización y desarrollo experimental de un sistema de generación termoeléctrica basado en efecto Seebeck. Aplicación a gases de escape en calderas de combustión
(2018) Araiz Vega, Miguel; Astrain Ulibarrena, David; Martínez Echeverri, Álvaro; Ingeniería; Ingeniaritza
La situación energética actual y todos los problemas medioambientales, políticos y económicos asociados a ella, hacen cada vez más necesaria una optimización de los sistemas de generación eléctrica y una incorporación de medidas de ahorro energético a los procesos, que contribuyen en gran parte a una reducción de la demanda de energía y a un mayor aprovechamiento de los recursos. En este sentido, son muchos los investigadores que han puesto el foco en la recuperación del llamado calor residual, una energía de desecho obtenida como subproducto no aprovechado de distintos procesos. Esta tesis doctoral estudia el aprovechamiento de energía residual a través de generadores termoeléctricos basados en el efecto Seebeck. Estos sistemas son capaces de producir energía eléctrica a partir de una fuente de calor y una de las formas de optimización es mediante el diseño adecuado de los intercambiadores de calor incluidos. Los intercambiadores tratan de acercar la temperatura de las caras de los módulos a la de los respectivos focos y tienen un efecto directo en la producción eléctrica. Se propone la utilización de un intercambiador de calor pasivo con sistema termosifón y cambio de fase como disipador de la parte fría de los sistemas termoeléctricos. Para llevar a cabo su optimización, se ha desarrollado un modelo computacional de simulación que predice el comportamiento de estos sistemas y permite evaluar la influencia de las características geométricas que lo definen. Este modelo es capaz de simular estos sistemas con desviaciones menores del ± 9%. Tras este desarrollo, se ha utilizado la herramienta computacional para el diseño de un termosifón bifásico que pueda ser acoplado en la parte fría de un prototipo de generador termoeléctrico instalado en el conducto de los gases de salida de una caldera de combustión. Los resultados experimentales han revelado que se puede llegar a generar 240W=m2 utilizando este sistema pasivo, lo que supone una mejora de casi un 83% frente a la utilización de un disipador de aletas convencional con un ventilador en las mismas condiciones de funcionamiento. Se ha realizado, también, un estudio de la implantación de generadores termoeléctricos en un proceso industrial real. Para ello, se ha desarrollado, previamente, un modelo computacional que tenga en cuenta, no solo el funcionamiento de los módulos termoeléctricos, sino que también considere el enfriamiento que sufre la corriente de gases al circular por el conducto del generador e integre los termosifones bifásicos como sistema de disipación del lado frío. Una vez realizada la optimización de estos sistemas, se ha demostrado la posibilidad de generar un total de 363MWh en un año de funcionamiento. También se ha elaborado un análisis que pretende probar la viabilidad económica de esta inversión alcanzándose un coste de instalación de 10€/W. Los resultados derivados de esta tesis demuestran que la termoelectricidad puede jugar un papel importante en el objetivo global de generación de electricidad de forma sostenible, que permita combatir con los efectos del cambio climático, debido a su capacidad de aprovechamiento energía residual.
Open Access
Geothermal thermoelectric generator for Timanfaya National Park
(2019) Catalán Ros, Leyre; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In the case of shallow Hot Dry Rock (HDR) fields, thermoelectric generators can entail a sustainable alternative to Enhanced Geothermal Systems (EGS). The present work studies two configurations of thermoelectric generators for Timanfaya National Park (Spain), one of the most important Hot Dry Rock fields in the world, with temperatures of 500°C at only 3 meters deep. The first configuration includes biphasic thermosyphons as heat exchangers for both sides, leading to a completely passive thermoelectric generator. The second configuration uses fin dissipators as cold-side heat exchangers.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(2021) Alegría Cía, Patricia; Rodríguez García, Antonio; Catalán Ros, Leyre; Astrain Ulibarrena, David; Araiz Vega, Miguel; Ingeniería; Institute of Smart Cities - ISC; Ingeniaritza
Nowadays, geothermal energy in shallow hot dry rocks is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Enhanced behaviour of a passive thermoelectric generator with phase change heat exchangers and radiative cooling
(Elsevier, 2023) Astrain Ulibarrena, David; Jaramillo-Fernández, Juliana; Araiz Vega, Miguel; Francone, Achille; Catalán Ros, Leyre; Jacobo-Martín, Alejandra; Alegría Cía, Patricia; Sotomayor-Torres, Clivia M.; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Heat exchangers are essential to optimize the efficiency of Thermoelectric Generators (TEGs), and heat pipes without fans have proven to be an advantageous design as it maintains the characteristic robustness of thermoelectricity, low maintenance and lack of moving parts. However, the efficiency of these heat exchangers decreases under natural convection conditions, reducing their heat transfer capacity and thus thermoelectric power production. This work reports on a novel heat exchanger that combines for the first time, phase change and radiative cooling in a thermoelectric generator to improve its efficiency and increase the production of electrical energy, specially under natural convection. For this, two thermoelectric generators with heat-pipes on their cold sides have been tested: one with the radiative coating and the other without it. Their thermal resistances have been determined and the electric power output was compared under different working conditions, namely, natural convection and forced convection indoors and outdoors. The experimental tests show a clear reduction of the heat exchanger thermal resistance thanks to the radiative coating and consequently, an increase of electric production 8.3 % with outdoor wind velocities of 1 m/s, and up to 54.8 % under free convection conditions. The application of the radiative surface treatment is shown to result in a more stable electrical energy production, suppressing the drastic decrease in the generated electric power that occurs in thermoelectric generators when they work under free convection.
Open Access
Simulation of thermoelectric heat pumps in nearly zero energy buildings: why do all models seem to be right?
(Elsevier, 2021) Martínez Echeverri, Álvaro; Díaz de Garayo, Sergio; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Catalán Ros, Leyre; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
The use of thermoelectric heat pumps for heat, ventilation, and air conditioning in nearly-zero-energy buildings is one of the most promising applications of thermoelectrics. However, simulation works in the literature are predominately based on the simple model, which was proven to exhibit significant deviations from experimental results. Nine modelling techniques have been compared in this work, according to statistical methods based on uncertainty analysis, in terms of predicted coefficient of performance and cooling power. These techniques come from the combination of three simulation models for thermoelectric modules (simple model, improved model, electric analogy) and five methods for implementing the thermoelectric properties. The main conclusion is that there is no statistical difference in the mean values of coefficient of performance and cooling power provided by these modelling techniques under all the scenarios, at 95% level of confidence. However, differences appear in the precision of these results in terms of uncertainty of the confidence intervals. Minimum values of uncertainty are obtained when the thermal resistance ratio approaches 0.1, being ±8% when using temperature-dependent expressions for the thermoelectric properties, ±18% when using Lineykin's method, and ± 25% when using Chen's method. The best combination is that composed of the simple model and temperature-dependent expressions for the thermoelectric properties. Additionally, if low values of resistance ratio are anticipated, empirical expressions from the literature can be used for the thermal resistance of the heat exchangers; for high values, though, experimental tests should be deployed, especially for the heat exchanger on the hot side.
Open Access
Investigation of direct contact membrane distillation coupling with a concentrated photovoltaic solar system
(Elsevier, 2019) Krnac, Andrew; Araiz Vega, Miguel; Rana, Sohel; Velardo, Jason; Date, Abhijit; Ingeniería; Ingeniaritza
The scarcity of fresh water amongst a growing population is an impending global issue, which must be addressed by utilizing renewable energy sources. A Concentrated Photovoltaic (CPV) and Direct Contact Membrane Distillation (DCMD) hybrid system is a viable solution to address water shortage in arid and rural areas. The objective is to determine the feasibility of the combination of a DCMD and CPV system, demonstrate fresh water production utilizing the DCMD method and increase total CPV system efficiency. An experimental setup has been designed and built, and the results indicate a mass flux of 7.096 L/m2.h is achievable with a Polytetrafluoroethylene Membrane area of 0.0491 m2, salinity concentration of 1±0.1 % and a membrane temperature difference of 18.82 °C.
Open Access
Improvements in the cooling capacity and the COP of a transcritical CO 2 refrigeration plant operating with a thermoelectric subcooling system
(Elsevier, 2019) Astrain Ulibarrena, David; Merino Vicente, Amaya; Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Sánchez, Daniel; Cabello, Ramón; Llopis, R.; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Restrictive environmental regulations are driving the use of CO 2 as working fluid in commercial vapour compression plants due to its ultra-low global warming potential (GWP 100 = 1) and its natural condition. However, at high ambient temperatures transcritical operating conditions are commonly achieved causing low energy efficiencies in refrigeration facilities. To solve this issue, several improvements have been implemented, especially in large centralized plants where ejectors, parallel compressors or subcooler systems, among others, are frequently used. Despite their good results, these measures are not suitable for small-capacity systems due mainly to the cost and the complexity of the system. Accordingly, this work presents a new subcooling system equipped with thermoelectric modules (TESC), which thanks to its simplicity, low cost and easy control, results very suitable for medium and small capacity plants. The developed methodology finds the gas-cooler pressure and the electric voltage supplied to the TESC system that maximizes the overall COP of the plant taking into account the ambient temperature, the number of thermoelectric modules used and the thermal resistance of the heat exchangers included in the TESC. The obtained results reveal that, with 20 thermoelectric modules, an improvement of 20% in terms of COP and of 25.6% regarding the cooling capacity can be obtained compared to the base cycle of CO 2 of a small cooling plant refrigerated by air. Compared to a cycle that uses an internal heat exchanger IHX, the improvements reach 12.2% and 19.5% respectively.
Open Access
Experimental and computational study on thermoelectric generators using thermosyphons with phase change as heat exchangers
(Elsevier, 2017) Araiz Vega, Miguel; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Mekanika, Energetika eta Materialen Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería Mecánica, Energética y de Materiales
An important issue in thermoelectric generators is the thermal design of the heat exchangers since it can improve their performance by increasing the heat absorbed or dissipated by the thermoelectric modules. Due to its several advantages, compared to conventional dissipation systems, a thermosyphon heat exchanger with phase change is proposed to be placed on the cold side of thermoelectric generators. Some of these advantages are: high heat-transfer rates; absence of moving parts and lack of auxiliary con- sumption (because fans or pumps are not required); and the fact that these systems are wickless. A com- putational model is developed to design and predict the behaviour of this heat exchangers. Furthermore, a prototype has been built and tested in order to demonstrate its performance and validate the compu- tational model. The model predicts the thermal resistance of the heat exchanger with a relative error in the interval [?8.09;7.83] in the 95% of the cases. Finally, the use of thermosyphons with phase change in thermoelectric generators has been studied in a waste-heat recovery application, stating that including them on the cold side of the generators improves the net thermoelectric production by 36% compared to that obtained with finned dissipators under forced convection.
Open Access
Experimental and computational investigation of passive heat exchangers to enhance the performance of a geothermal thermoelectric generator
(Elsevier, 2024) Pascual Lezaun, Nerea; Alegría Cía, Patricia; Araiz Vega, Miguel; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
Thermoelectric devices hold significant promise for generating electricity from geothermal heat, enabling the powering of measuring equipment in remote locations without the need for moving parts. Nevertheless, most developed geothermal thermoelectric generators employ fans and pumps to enhance heat transfer, thereby compromising the robustness and reliability inherent to thermoelectricity. Furthermore, there is a lack of research on passive heat exchangers for geothermal thermoelectric generators, particularly in studying their operation under a wide range of meteorological conditions. Therefore, this paper conducts a comprehensive analysis of passive heat exchangers for the cold side of the generators. Phase-change-based heat exchangers differing in their length and fluid are studied experimentally, along with a fin dissipator. Additionally, the influence of wind velocity on heat transfer and mechanical requirements is further explored through a Computational Fluid Dynamics model. The most significant outcome is quantifying the impact of the design parameters and operational variables on the electrical production of the thermoelectric generator. Accordingly, this research aims to broaden the application of these generators to extreme environments, such as Deception Island in Antarctica. Under average operational conditions, generators incorporating 400 mm water heat pipes generate 0.95 W per thermoelectric module, while those incorporating heat pipes with methanol achieve an average of 0.70 W. Moreover, water and methanol-based systems produce 120% and 60% more power than generators using a fin dissipator. Nonetheless, for temperatures beyond -6.5 °C, water might freeze and the methanol-based heat exchangers become more suitable.
Open Access
Experimental evaluation of a transcritical CO2 refrigeration facility working with an internal heat exchanger and a thermoelectric subcooler: performance assessment and comparative
(Elsevier, 2022) Casi Satrústegui, Álvaro; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Sánchez, Daniel; Cabello, Ramón; Astrain Ulibarrena, David; Ingeniería; Ingeniaritza; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The use of carbon dioxide in transcritical state has become one of the most used solutions to comply with the F-Gas directive and reduce greenhouse gases emissions from refrigeration systems at high ambient temperatures. For low-medium power units, the commonly used solutions to improve the efficiency such as the ejector, multiple compressor arrangements, mechanical subcooler, etc., add complexity and increase the cost of the refrigeration facility, which is not ideal for small units. In this low-medium power range, two technologies stand out to increase the performance of a carbon dioxide transcritical cycle: the internal heat exchanger and the thermoelectric subcooler. This study brings a complete research in which both solutions have been tested in the same experimental transcritical carbon dioxide refrigeration facility under the same working conditions. It focuses on the real performance of both systems and discusses the strengths and weaknesses of using an internal heat exchanger or a thermoelectric subcooler. The results show that the thermoelectric subcooler outperforms the internal heat exchanger in both the coefficient of performance and the cooling capacity while also being a more controllable and flexible solution.