Open Access
Vermicomposting of lavender waste: a biological laboratory investigation
(MDPI, 2022) González Moreno, Miguel Ángel; García Gracianteparaluceta, Beñat; Marcelino Sádaba, Sara; Prieto Cobo, Eduardo; Seco Meneses, Andrés; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Gobierno de Navarra / Nafarroako Gobernua
In the present work, lavender waste, a residue of the essential oil extract industry, was used to feed Eisenia andrei with mature horse manure at ratios of 0:100, 25:75, 50:50, 75:25 and 100:0 on dry weight basis. Vermicomposting was carried out for 70 days in laboratory conditions. Biological parameters such as population build-up, total biomass, mortality and cocoon production were observed and measured. Increasing concentrations of waste affected positively the growth and reproduction of worms in a significant way. The 100% lavender waste combination showed the best cocoon production and even tripled their biomass in the first week. A seed germination test was also made, where no evidence of toxicity was found. The germination index range was, in general terms, above 100. The results indicated that the earthworm E. andrei was able to transform lavender waste into compost and thus play a major role in industrial waste management and apply circular economy.
Open Access
Experimental study of the performance and emission characteristics of an adapted commercial four-cylinder spark ignition engine running on hydrogen-methane mixtures
(Elsevier, 2014) Diéguez Elizondo, Pedro; Urroz Unzueta, José Carlos; Marcelino Sádaba, Sara; Pérez Ezcurdia, Amaya; Benito Amurrio, Marta; Sáinz Casas, David; Gandía Pascual, Luis; Ingeniería; Ingeniaritza
The use of hydrogen/methane mixtures with low methane contents as fuels for internal combustion engines (ICEs) may help to speed up the development of the hydrogen energy market and contribute to the decarbonization of the transportation sector. In this work, a commercial 1.4 L four-cylinder Volkswagen spark-ignition engine previously adapted to operate on pure hydrogen has been fueled with hydrogen/methane mixtures with 5–20 vol.% methane (29.6–66.7 wt.%). An experimental program has been executed by varying the fuel composition, air-to-fuel ratio (λ), spark advance and engine speed. A discussion of the results regarding the engine performance (brake torque, brake mean effective pressure, thermal efficiency) and emissions (nitrogen oxides, CO and unburned hydrocarbons) is presented. The results reveal that λ is the most influential variable on the engine behavior due to its marked effect on the combustion temperature. As far as relatively high values of λ have to be used to prevent knock, the effect on the engine performance is negative. In contrast, the specific emissions of nitrogen oxides decrease due to a reduced formation of thermal NOx. A clear positive effect of reducing the spark advance on the specific NOx emissions has been observed as well. As concerns CO and unburned hydrocarbons (HCs), their specific emissions increase with the methane content of the fuel mixture, as expected. However, they also increase as λ increases in spite of the lower fuel concentration due to a proportionally higher reduction of the power. Finally, the effect of the increase of the engine speed is positive on the CO and HCs emissions but negative on that of NOx due to improved mixing and higher temperature associated to intensified turbulence in the cylinders.
Open Access
Sulfate soils stabilization with magnesium-based binders
(Elsevier, 2016) Seco Meneses, Andrés; Miqueléiz Jiménez, Luis; Prieto Cobo, Eduardo; Marcelino Sádaba, Sara; García, Beñat; Urmeneta, Pablo; Proyectos e Ingeniería Rural; Landa Ingeniaritza eta Proiektuak; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Sulfate soils' stabilization is a very interesting subject with technical, economic and environmental implications. The difficulty of their stabilization is due to the fact that the usual stabilizer additives are based on calcium. In these soils, sulfate combines with the calcium from the additive and the aluminum from the clay, resulting in a highly hydrated expansive mineral named ettringite. This provokes the swelling of the treated material and even its destruction. This study analyzes the result of the substitution of the calciumbased additives by one alternative additive based on magnesium, an industrial byproduct named PC-8, in the stabilization of five different sulfate soils. From a mechanical point of view soils treated with PC-8 reached similar resistance values to the lime treated ones, of about 2–3 MPa for 4% dosage and 2–5 MPa for 8% dosage, being usually better with the PC-8 results than with the lime ones. When PC-8 was combined with GGBS the resistance values increased up to 11–13 MPa and the lime-GGBS reached the 6–7 MPa. The natural swelling of the soils treated with PC-8 decreased substantially and maintained constant even for immersion at long-term. In the case of the soils treated with lime, long-termswelling increased up to very high values even in the case of soilswithout natural swelling. XRD analysis of these samples demonstrated the existence of ettringite in 4 of the 5 soilswhen theywere treated with lime and there was not expansive minerals in the PC-8 treated soils, agreeing with the swelling observed behavior of the soils when treated with both additives.
Open Access
Experimental study of the valorization of sulfate soils for use as construction material
(MDPI, 2022) Seco Meneses, Andrés; Del Castillo García, Jesús María; Perlot, Céline; Marcelino Sádaba, Sara; Prieto Cobo, Eduardo; Espuelas Zuazu, Sandra; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
This article shows an experimental investigation carried out for the stabilization of a sulfate soil. The stabilization was carried out in two phases: the first phase was the consumption of the sulfate present in the soil through its controlled transformation into ettringite. After this, a modified soil with lower maximum density, greater optimum moisture identified via standard proctor (SP) test, no plasticity and improved unconfined compressive strength (UCS) was obtained. In the second phase, the modified soil was stabilized by the use of different additives rich in oxides of calcium or magnesium, combined with by-products or waste materials containing reactive aluminum or silicon oxides. As a result, the mechanical strength of the modified soil was improved. In this phase, a binary binder composed of a magnesium oxide product and ground granulated blast-furnace slags (GGBS) obtained the highest UCS. The binary binder composed of lime and an alumina filler formed ettringite in the treated soil. This experiment allowed for the validation of a two-phase stabilization process and the non-conventional additives used, mainly magnesium oxide and GGBS, even for high-bearing-requirement pavement layers’ construction.
Open Access
Technical and environmental characterization of hydraulic and alkaline binders
(Elsevier, 2018) Espuelas Zuazu, Sandra; Echeverria Lazcano, Angel María; Marcelino Sádaba, Sara; Prieto Cobo, Eduardo; Seco Meneses, Andrés; Proyectos e Ingeniería Rural; Landa Ingeniaritza eta Proiektuak; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2017-000176
Portland cement is a widely used binder in construction and building applications because of its good properties. Despite its convenience as construction material, the social demands and policies trends are requesting a lower impact and more sustainable cement manufacturing industry. The most effective ways to reach this goal are the substitution of clinker by different wastes or by-products in the cement composition or the development of more sustainable binders like the alkali activated binders. This work analyzes from a technical and environmental point of view the substitution of a clinker based CEM I common cement for the construction mortars manufacturing. Four common cements with different ground granulated blastfurnace slags (GGBS) or fly ashes (FA) contents as well as fifteen alkali activated binders (AAB) combinations were considered. Fresh consistency, density, compressive strength (CS) tests and life cycle analysis were carried out to state the ability of these different hydraulic and alkaline activated binders for the CEM I substitution. The results obtained demonstrated the technical and environmental convenience of these binders for the construction mortars manufacturing.
Open Access
Sustainable unﬁred bricks manufacturing from construction and demolition wastes
(Elsevier, 2018) Seco Meneses, Andrés; Omer, Joshua; Marcelino Sádaba, Sara; Espuelas Zuazu, Sandra; Prieto Cobo, Eduardo; Proyectos e Ingeniería Rural; Landa Ingeniaritza eta Proiektuak
The management of construction and demolition wastes is a huge challenge for most Governments. Thegreatest component of such wastes is concrete and masonry fragments or remains. Among the most com-mon approaches to valorization of such w astes is to convert them to recycled aggregates, however thismay be hampered by low quality of some recycled aggregates compared to natural aggregates. This paperpresents the results of experimental investigation where concrete and ceramic remains were used to par-tially substitute clay soil in producing unﬁred bricks. The bricks were then tested for mechanical strength,water absorption freeze-thaw resistance. Additionally the environmental impact of the bricks wasassessed based on Life Cycle Analysis (LCA). It was established that concrete waste could be used to sub-stitute up to 50% of the clay whereas ceramic wastes could only substitute a maximum of 30% of the clay.Blended bricks made from clay and concrete waste mixes had a lower mechanical strength than thosemade from clay and ceramic waste. As regards water absorption, there was no marked differencebetween the two blends of brick however reduction in water resistance was slightly greater in bricks con-taining concrete waste that in those containing ceramic wastes. Also, tests showed that freeze-thawresistance was greater in bricks blended with concrete wastes than in those incorporating ceramicwastes. Life Cycle analyses demonstrated that it is the binder content in the mix that largely determinesthe environmental impact of the blended bricks. Lastly, it was demonstrated that the most desirable tech-nical and environmental credentials of brick material mixes resulted from using the binder combination:CL-90-S+GGBS 2/8.
Open Access
Sulphate soil stabilisation with magnesium binders for road subgrade construction
(Taylor and Francis, 2020) Seco Meneses, Andrés; Espuelas Zuazu, Sandra; Marcelino Sádaba, Sara; García, Beñat; Del Castillo García, Jesús María; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua
This paper analyzes the ability of magnesium oxide-based additives to stabilise a low bearing gypsum marly soil, in order to reach subgrade requirements. This soil was not adequate for stabilisation with lime or cement because of its high sulphate content. Binders considered in this investigation were composed of three reactive Mg products and by products, both with and without ground granulated blast furnace slags (GGBS). They were compared to two cements and an aerial lime as soil stabilisers in a laboratory investigation and a field trial. Laboratory tests showed that Mg products with GGBS reached strength results close and at times even better than those of cement. One of the Mg products was the only additive able to reduce the natural soil swelling. Leaching tests demonstrated the ability of the Mg products to reduce the soil leaching of substances like calcium, magnesium, sulphate and chloride. In field trials two of the Mg products combined with GGBS met the bearing capacity requirements for subgrades, in accordance with the Spanish standard.
Open Access
Recycled granulates manufacturing from spent refractory wastes and magnesium based binder
(Elsevier, 2023) Seco Meneses, Andrés; Del Castillo García, Jesús María; Perlot, Céline; Marcelino Sádaba, Sara; Espuelas Zuazu, Sandra; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC
This paper analyzes the ability of two Spent Refractory Wastes (SRW) for the manufacturing of recycled granulates for construction applications. A binary magnesium oxide and ground granulated blast furnace slag hydraulic binder was considered as an agglomerating agent for the granulates manufacturing. Influence of curing atmosphere was carried out: in air, 20 % CO2 and 100 % CO2 atmosphere up to 28 days. Granulometry, thermal analysis, particle density, bulk density, water absorption and mechanical strength tests were performed to characterize the granulates. SRW showed their ability for the granulates manufacturing. Results demonstrated the existence of a residual reactivity of the wastes considered. A direct relationship between the CO2 content of the curing atmosphere and the granulates hydration degree was observed. Carbonation process increased from 7 days to 28 days and direct relationships were observed between the CO2 content and the carbonation degree as well as between the binder dosage and the carbonation degree. CO2 curing reduced the water absorption and increased the compressive strength of the granulates.
Open Access
Recovered foam impact absorption systems
(MDPI, 2024-10-19) Marcelino Sádaba, Sara; Benito Hernández, Pablo; Martín Antunes, Miguel Ángel; Villanueva Roldán, Pedro; Veiga Suárez, Fernando; Ingeniería; Ingeniaritza
The use of foam materials in environments where they come into contact with individuals often results in deterioration, necessitating periodic replacements to maintain safety and hygiene standards. Foam, a lightweight, porous plastic formed by aggregated bubbles, possesses excellent impact-absorbing properties; however, its inherent porosity and susceptibility to wear present challenges. This project aims to develop a technological application for repurposing spent polyurethane (PU) foam from leisure facilities into effective impact absorption systems. By focusing on the reuse of deteriorated foam materials, this initiative seeks to minimize environmental impact while leveraging their beneficial technical characteristics. Addressing issues related to foam degradation, this project endeavors to create sustainable solutions by reintegrating spent foam into new systems. This innovative approach promotes sustainability while enhancing safety through the provision of high-quality, impact-resistant elements. Ultimately, this work aims to contribute to environmental conservation and the advancement of effective impact protection measures in leisure facilities.
Open Access
Magnesium oxide as alternative binder for unﬁred clay bricks manufacturing
(Elsevier, 2017) Espuelas Zuazu, Sandra; Omer, Joshua; Marcelino Sádaba, Sara; Echeverria Lazcano, Angel María; Seco Meneses, Andrés; Proyectos e Ingeniería Rural; Landa Ingeniaritza eta Proiektuak; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Replacement of ﬁred bricks by unﬁred ones could be an eﬀective way to reduce the building industryenvironmental footprint: Their manufacture not only requires less energy and natural resources but alsogenerates less waste. Bricks are based on the use of an additive cementitious material in the form of a binder,usually lime or cement. Such additives have a great environmental impact owing to the high energy consumptionand CO2during in their manufacturing process. In this article experiments are carried out in order to investigatethe applicability of a MgO rich industry by-product as a binder for the production of unﬁred clay bricks. Fromthe experiments, the MgO was observed to show ability to enhance the mechanical properties of a clay brick inmuch the same way as lime does. Water absorption tests on bricks revealed the superiority of MgO over lime inenhancing the durability properties of unﬁred bricks. The laboratory results demonstrate the high potential ofMgO based additives as alternative binders to the calcium based ones. Consequently, this oﬀers opportunity forreducing the environmental impact associated with the use of ﬁred clay bricks. In addition, it could allow aneﬀective way for the valorization of MgO containing industry by-products that currently discarded to landﬁlls