Open Access
Corrosion behavior in volcanic soils: in search of candidate materials for thermoelectric devices
(MDPI, 2021-12-21) Berlanga Labari, Carlos; Catalán Ros, Leyre; Palacio, José F.; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Institute for Advanced Materials and Mathematics - INAMAT2
Thermoelectric generators have emerged as an excellent solution for the energy supply of volcanic monitoring stations due to their compactness and continuous power generation. Nevertheless, in order to become a completely viable solution, it is necessary to ensure that their materials are able to resist in the acidic environment characteristic of volcanoes. Hence, the main objective of this work is to study the resistance to corrosion of six different metallic materials that are candidates for use in the heat exchangers. For this purpose, the metal probes have been buried for one year in the soil of the Teide volcano (Spain) and their corrosion behavior has been evaluated by using different techniques (OM, SEM, and XRD). The results have shown excessive corrosion damage to the copper, brass, and galvanized steel tubes. After evaluating the corrosion behavior and thermoelectric performance, AISI 304 and AISI 316 stainless steels are proposed for use as heat exchangers in thermoelectric devices in volcanic environments.
Open Access
Study of effect of nickel content on tribocorrosion behaviour of nickel-aluminium-bronzes (NABs)
(MDPI, 2023) Berlanga Labari, Carlos; Claver Alba, Adrián; Biezma Moraleda, María Victoria; Ingeniería; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2
The simultaneous existence of mechanical erosion and electrochemical corrosion is a common scenario for engineering alloys used in marine environments, such as pump impellers and valves. Nickel–aluminium–bronzes (NABs) are widely used alloys in these environments due to their combination of high corrosion resistance and effective mechanical properties. However, NAB alloys are increasingly cast with reduced nickel content due to its high price and low availability. In this study, we examined the tribocorrosion behaviour of two nickel–aluminium bronzes (C95500 and C95400) with different nickel contents (4.8% and 1.0%, respectively) by means of a pin-on-disk device combined with in situ electrochemistry under 1 M NaCl solution. We conducted tests for pure wear in distilled water, pure corrosion using in situ electrochemistry under 1 M NaCl solution, and a combination of wear and corrosion, called tribocorrosion, to understand the overall synergism that exists between the two. We analysed our results using gravimetric as well as volumetric analysis; in addition, we defined the friction coefficient to compare the effect of open-circuit potential (OCP). We also applied the Tafel method and compared corrosion rates for the different scenarios. We employed confocal microscopy to delimitate the impact of the surface topography of pure wear and its synergistic effect with corrosion, and used an optical microscope to study the materials’ microstructures as cast conditions. We also utilised XRD in the Bragg–Brentano configuration to determine the chemical composition of corrosion products. From the experiments conducted, we concluded that an important synergistic effect existed between the wear and corrosion of both NABs, which was associated with corrosion-induced wear. We found NAB C95400 to be more susceptible to erosion under both conditions compared with NAB C95500 due to the chemical composition and lubricant effect of corrosion products formed during the tribocorrosion tests, which were supported by the enriched Ni corrosion products, particularly the presence of nickel-rich copper chloride, 3Cu3(CuNi)(OH)6CuCl2, in the C95500 alloy. We concluded that, because it increased the nickel content, the NAB alloy offered better wear and corrosion behaviour in sea water conditions due to its protective film nature.
Open Access
Multifunctional protective PVC-ZnO nanocomposite coatings deposited on aluminum alloys by electrospinning
(MDPI, 2019) Iribarren Zabalegui, Álvaro; Rivero Fuente, Pedro J.; Berlanga Labari, Carlos; Larumbe Abuin, Silvia; Miguel, Adrián; Rodríguez Trías, Rafael; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, PRO-UPNA 18 (6107)
This paper reports the use of the electrospinning technique for the synthesis of nanocomposite micro/nanofibers by combining a polymeric precursor with hydrophobic behavior like polyvinyl chloride (PVC) with nanoparticles of a corrosion inhibitor like ZnO. These electrospun fibers were deposited on substrates of the aluminum alloy 6061T6 until forming a coating around 100 m. The effect of varying the different electrospinning deposition parameters (mostly applied voltage and flow-rate) was exhaustively analyzed in order to optimize the coating properties. Several microscopy and analysis techniques have been employed, including optical microscopy (OM), field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Water contact angle (WCA) measurements have been carried out in order to corroborate the coating hydrophobicity. Finally, their corrosion behavior has been evaluated by electrochemical tests (Tafel curves and pitting potential measurements), showing a relevant improvement in the resultant corrosion resistance of the coated aluminum alloys.
Open Access
Study of the degradation of heat exchanger materials in the acidic environment of Teide National Park
(2019) Catalán Ros, Leyre; Pérez Artieda, Miren Gurutze; Berlanga Labari, Carlos; Garacochea Sáenz, Amaia; Rodríguez García, Antonio; Domínguez, Vidal; Montañez, Ana Carolina; Padilla, Germán D.; Pérez, Nemesio M.; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Ingeniería
Supplying power to volcanic monitoring stations constitutes a challenge due to both the access difficulties and the acidic environment associated with volcanoes. ELECTROVOLCAN project is developing thermoelectric generators that make use of the temperature of the available fumaroles to directly supply electricity to the stations in a robust, compact and reliable way. The main element of thermoelectric generators are the thermoelectric modules, based on Seebeck effect. Nonetheless, since the efficiency of these modules increases with the temperature difference between their sides, the introduction of heat exchangers becomes essential. The present study analyses the behavior of different materials used in the construction of the heat exchangers in the acidic environment of Teide National Park.
Open Access
Corrosion of cast aluminum alloys: a review
(MDPI, 2020-10-16) Berlanga Labari, Carlos; Biezma Moraleda, María Victoria; Rivero Fuente, Pedro J.; Ingeniería; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2
Research on corrosion resistance of cast aluminum alloys is reviewed in this article. The effect of the main microstructural features of cast aluminum alloys such as secondary dendrite arm spacing (SDAS), eutectic silicon morphology, grain size, macrosegregation, microsegregation, and intermetallic compounds is discussed. Moreover, the corrosion resistance of cast aluminum alloys obtained by modern manufacturing processes such as semi-solid and additive manufacturing are analyzed. Finally, the protective effects provided by different coatings on the aluminum cast alloys—such as anodized, plasma electrolytic oxidation (PEO), and laser—is reviewed. Some conclusions and future guidelines for future works are proposed.
Open Access
Effect of Ti on microstructure, mechanical properties and corrosion behavior of a nickel-aluminum bronze alloy
(ABM, ABC, ABPol, 2021-04-12) Rivero Fuente, Pedro J.; Berlanga Labari, Carlos; Palacio, José F.; Biezma Moraleda, María Victoria; Ingeniería; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2
Nickel-aluminum bronze (NAB) alloys are suitable, in cast condition, to be used in marine propellers due to its excellent behavior avoiding erosion and cavitation as well as corrosion. A complex microstructure, intrinsic to this copper base system, is the result of a well-controlled chemical composition. There are few works related to the effect of adding small quantities of specific chemical elements on NAB alloys properties. The aim of this paper is to study the effect of Ti on the microstructure, mechanical properties, and corrosion behavior of a particular NAB alloy, CuAl10Fe5Ni5 (C95500), and the comparison to the Ti-free NAB alloy. Although the as- cast microstructure is very similar for both materials, the addition of only 120 ppm Ti leads to a significant grain refinement that plays a key role on the mechanical properties. It has been observed an increase in both microhardness and nanohardness as well as in the resultant Young moduli values, meanwhile no significant impact on the corrosion susceptibility has been observed.
Open Access
Estudio de la oxidación a elevada temperatura de ocho aleaciones en atmósferas de combustión de biomasa
(CENIM, 2008) Berlanga Labari, Carlos; Fernández Carrasquilla, Javier; Ingeniería Mecánica, Energética y de Materiales; Mekanika, Energetika eta Materialen Ingeniaritza
La combustión de biomasa, especialmente de paja de cereal, genera un ambiente muy corrosivo, particularmente, cerca de los tubos sobrecalentadores. El cloro es el principal agente corrosivo en las plantas de biomasa. Este trabajo se centra en comprobar el comportamiento de ocho aleaciones comerciales en una ambiente de combustión de biomasa. Los materiales estudiados han sido las siguientes: AISI 347 CG (1.4550), AISI 347 FG (1.4550), AISI 316LN (1.4910), ESSHETE 1250 (1.4982), AC 66 (1.4877), X20CrMoV12:1 (1.4922) y AISI 347 recubiertos con Inconel 625 e Inconel 686. Los ensayos se han realizado en la caldera de la planta de biomasa de Sangüesa (Navarra, España) durante 8.000 y 15.000 h a una temperatura de 500-550 °C. Los resultados indican un buen comportamiento de los aceros inoxidables austeníticos y de las aleaciones de Inconel, mientras que el del acero martensítico no ha sido aceptable. Se ha propuesto el mecanismo conocido como “oxidación activa” para interpretar el comportamiento a la corrosión de estos materiales en estos medios.