Open Access
Lithium-ion battery model and experimental validation
(2015) Berrueta Irigoyen, Alberto; Irigaray, Víctor; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa eta Elektronikoa; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica
A simple battery model is useful for: Sizing of the storage system for a particular application; Designing other elements connected to the battery; Managing the storage system operation. This poster consists on: Tests to characterize a lithium-ion battery at Ta=23 ⁰C. Methodology to fit the parameters of the battery model; Parameter trends related to the state of charge; Experimental validation and model accuracy.
Open Access
Energy storage systems based on lithium-ion batteries and supercapacitors: characterization, modelling and integration with renewable energies
(2017) Berrueta Irigoyen, Alberto; Ursúa Rubio, Alfredo; Sanchis Gúrpide, Pablo; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Gobierno de Navarra / Nafarroako Gobernua
Los inconvenientes medioambientales, sociales y económicos que presentan los combustibles fósiles y nucleares están propiciando un uso cada vez mayor de fuentes de energía renovables. El fuerte desarrollo tecnológico de los sistemas de generación basados en estas fuentes de energía, especialmente de los sistemas eólicos y fotovoltaicos, ha abaratado enormemente sus costes de producción, resultando ya tecnologías competitivas en relación con las plantas convencionales. Actualmente, el principal obstáculo que limita su integración masiva en la red eléctrica es su gestionabilidad, dada la naturaleza intermitente del recurso renovable. Los sistemas de almacenamiento energético distribuidos, y en particular las baterías de litio y los supercondensadores, surgen como una de las mejores alternativas para mejorar la gestión de esta energía y facilitar la operación de una red el ectrica cada vez más basada en sistemas renovables. Esta tesis analiza en profundidad ambas tecnologías de almacenamiento, especialmente cuando funcionan en entornos de generación renovable. Las principales líneas de trabajo de la tesis son: Análisis del estado actual de las tecnologías; Estudio de la influencia de los fenómenos termodinámicos, electroquímicos y térmicos en el funcionamiento de estos sistemas de almacenamiento; Modelado electroquímico y térmico de ambas tecnologías de almacenamiento; Estimación del estado de carga y del envejecimiento en baterías de litio; Validación experimental de los modelos propuestos ante diferentes condiciones de funcionamiento; Desarrollo de metodologías para el diseño y funcionamiento óptimo de sistemas de almacenamiento basados en baterías de litio en entornos renovables y particularización para centrales fotovoltaicas.
Open Access
Hydrogen-lithium energy storage for a stand-alone microgrid
(2016) Berrueta Irigoyen, Alberto; San Martín Biurrun, Idoia; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa eta Elektronikoa; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica
Sizing of the storage system for a stand-alone application: Satisfaction of technical requirements; Based on real data from an experimental microgrid; Long lifetime; Lowest price
Open Access
Impact of micro-cycles on the lifetime of lithium-ion batteries - EIS analysis
(IEEE, 2024-07-30) Nováková, Katerina; Berrueta Irigoyen, Alberto; Soto Cabria, Adrián; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Gobierno de Navarra / Nafarroako Gobernua
Experimental studies of lithium-ion batteries are very often based only on deep charge and discharge cycles. However, these test profiles do not fully reflect the actual operation of the battery in an electric vehicle or in stationary applications, where the battery is not only loaded during the main charging and discharging profiles, but it is also stressed by the current throughput caused by renewable power fluctuations or by auxiliary services. These cycles, which are superimposed to the main charge and discharge processes and have a depth of discharge not exceeding 2%, are called micro-cycles. Although there are several simulation studies that attempt to capture this issue, there is still no comprehensive experimental study that has the phenomena that occur during micro-cycling. This paper presents an experimental analysis of micro-cycles, providing a detailed view of the different processes taking place in the battery during aging, by means of a detailed analysis of the results from electrochemical impedance spectroscopy (EIS). By studying the single electrochemical processes in detail, this paper explains the benefits of micro-cycling in terms of extending the lifetime of the battery.
Open Access
Methodology for comparative assessment of battery technologies: experimental design, modeling, performance indicators and validation with four technologies
(Elsevier, 2025-01-15) Irujo Izcue, Elisa; Berrueta Irigoyen, Alberto; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, PJUPNA2023-11380; Gobierno de Navarra / Nafarroako Gobernua
An increasing number of applications with diverse requirements incorporate various battery technologies. Selecting the most suitable battery technology becomes a tedious task as several aspects need to be taken into account. Two of the key aspects are the battery characteristics under temperature variations and their degradation. While numerous contributions using tailored assessment methods to evaluate both aspects for a particular application exist in the literature, a general methodology for analysis is necessary to enable a quantitative comparison between different technologies. We propose in this paper a novel methodology, based on performance indicators, to quantify the potential and limitations of a battery technology for diverse applications sharing a similar operational profile. A quantification of phenomena such as the influence of high and low temperatures on the battery, or the effect of cycling and state of charge on battery aging is obtained. In pursuit of these indicators, an experimental procedure and the fitting of aging model parameters that allow their calculation are proposed. As an additional outcome of this work, a general aging model that allows comprehensive analysis of aging behavior is developed and the trade-off between experimental time and accuracy is analyzed to find an optimal experimental time between 2 and 4 months, depending on the studied battery technology. Finally, the proposed methodology is applied to four battery technologies in order to show its potential in a real case-study.
Open Access
Experimental evaluation of the safety performance of lithium-ion batteries based on abuse areas
(IEEE, 2024) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Valera, Juan José; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Gobierno de Navarra / Nafarroako Gobernua
Safety issues associated with lithium-ion batteries (LIBs) jeopardize their widespread adoption in both stationary applications and electric vehicles. One of the factors that can most affect the safety of a LIB is its chemistry. For this reason, this article aims to evaluate the safety of the two main current chemistries, LFP and NMC. In particular, the safety of both technologies is examined from the perspective of the areas of abuse that characterize their behavior beyond the safe operation area. A commercial 5 Ah pouch cell with LFP chemistry is subjected to various overtemperature and overcharge abuses at different conditions. The results obtained for LFP chemistry cell are discussed together with those for NMC cell from a previous work of the authors. Identification of the abuse areas allows for a comparative analysis of the safety of both chemistries, providing a valuable tool for classifying the abuse behavior of LIBs.
Open Access
Temperature indicators and overtemperature detection in lithium-ion batteries based on electrochemical impedance spectroscopy
(IEEE, 2023) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Soto Cabria, Adrián; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
Lithium-ion batteries are the leading technology for energy storage systems due to their attractive advantages. However, the safety of lithium-ion batteries is a major concern, as their operating conditions are limited in terms of temperature, voltage and state of charge. Therefore, it is important to monitor the conditions of lithium-ion batteries to guarantee safe operation. To this end, in the present work, we analyze electrochemical impedance spectroscopy (EIS) as a tool to estimate the temperature of batteries. Overtemperature abuse tests from 25 °C to 140 °C are performed at various states of charge, and EIS measurements are obtained during the tests. The influence of temperature on cell impedance at different frequencies is analyzed and new findings are revealed. The real part of the impedance is identified to be the best indicator for cell temperature estimation by EIS. In addition, the best frequency to achieve accurate temperature monitoring, avoiding disturbances produced by state of charge variations, is proposed based on experimental results. Finally, EIS is proven to be a reliable technique for overtemperature and thermal runaway detection.
Open Access
Applied method to model the thermal runaway of lithium-ion batteries
(IEEE, 2021) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The thermal runaway (TR) is one of the most dangerous phenomena related to lithium-ion batteries. For this reason, there are different proposals in the literature for its modelling. Most of these proposed models take into account the decomposition reactions between the internal components of the cell, and base the adjustment of the parameters on numerous abuse tests that lead to the appearance of TR. However, these tests are destructive, require specific equipment, present a high economic cost and are very time consuming. This paper proposes a modelling method which enables the development of TR models with the use of fewer resources. This method is based on chemical kinetics, which allow a simplification of the general modelling process published in the literature. At the same time it maintains good accuracy and makes it possible to define the TR behavior of any type of cell, regardless of its chemistry, shape or size. Furthermore, the proposed method allows the use of the experimental results most commonly presented in the specialized literature, which significantly reduces the need for destructive testing. The presented modelling method achieves a good compromise between accuracy and applicability in the validations shown in the paper.
Open Access
On the characterization of lithium-ion batteries under overtemperature and overcharge conditions: identification of abuse areas and experimental validation
(Elsevier, 2024) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Although lithium-ion batteries have gained considerable popularity in renewable energy and electric vehicle applications, their safety still remains a concern under certain voltage, temperature, or state of charge conditions. This can lead to degradation and potential thermal runaway. In order to improve the safety assessment of LIBs based on their operating conditions, it is therefore essential to analyze not only their safe operating area but also their abuse region. This study focuses on the characterization of the abuse region of lithium-ion batteries by proposing a new methodology in which four areas of abuse are identified and experimentally validated using a commercial 3.6 Ah pouch cell. The cell is subjected to overtemperature and overcharge conditions, exploring various states of charge (0 to 200%) and ambient temperatures (25 to 100 °C). The influence of temperature and state of charge on the battery's behavior is thoroughly analyzed to fully characterize the abuse region. Results reveal the limiting temperatures and states of charge that define the boundaries of the abuse areas. By extending the characterization of LIBs behavior beyond the safe operation area with the determination of four areas of abuse, this article contributes to a better understanding of the phenomena and abuse mechanisms produced by overtemperature and overcharge events with an eye to improving battery safety.