Publication:

Temperature indicators and overtemperature detection in lithium-ion batteries based on electrochemical impedance spectroscopy

Lithium-ion batteries are the leading technology for energy storage systems due to their attractive advantages. However, the safety of lithium-ion batteries is a major concern, as their operating conditions are limited in terms of temperature, voltage and state of charge. Therefore, it is important to monitor the conditions of lithium-ion batteries to guarantee safe operation. To this end, in the present work, we analyze electrochemical impedance spectroscopy (EIS) as a tool to estimate the temperature of batteries. Overtemperature abuse tests from 25 °C to 140 °C are performed at various states of charge, and EIS measurements are obtained during the tests. The influence of temperature on cell impedance at different frequencies is analyzed and new findings are revealed. The real part of the impedance is identified to be the best indicator for cell temperature estimation by EIS. In addition, the best frequency to achieve accurate temperature monitoring, avoiding disturbances produced by state of charge variations, is proposed based on experimental results. Finally, EIS is proven to be a reliable technique for overtemperature and thermal runaway detection.