Open Access
Applied method to model the thermal runaway of lithium-ion batteries
(IEEE, 2021) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The thermal runaway (TR) is one of the most dangerous phenomena related to lithium-ion batteries. For this reason, there are different proposals in the literature for its modelling. Most of these proposed models take into account the decomposition reactions between the internal components of the cell, and base the adjustment of the parameters on numerous abuse tests that lead to the appearance of TR. However, these tests are destructive, require specific equipment, present a high economic cost and are very time consuming. This paper proposes a modelling method which enables the development of TR models with the use of fewer resources. This method is based on chemical kinetics, which allow a simplification of the general modelling process published in the literature. At the same time it maintains good accuracy and makes it possible to define the TR behavior of any type of cell, regardless of its chemistry, shape or size. Furthermore, the proposed method allows the use of the experimental results most commonly presented in the specialized literature, which significantly reduces the need for destructive testing. The presented modelling method achieves a good compromise between accuracy and applicability in the validations shown in the paper.
Open Access
Onset of irreversible reactions in overcharging lithium-ion cells: an experimental and modeling approach
(IEEE, 2023) Irujo Izcue, Elisa; Berrueta Irigoyen, Alberto; Lalinde Sainz, Iñaki; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
Lithium-ion batteries are energy storage systems used in an increasing number of applications. Due to their flammable materials, their use entails risks of fire and explosion. The study of the abuse operation of these batteries before reaching the thermal runaway is a relevant research topic to prevent safety issues. There are various studies in the bibliography providing exhaustive thermal studies of the safe operating area, as well as concerning the thermal runaway. However, the onset irreversible reactions, that take place at a SOC around 110%, have not been properly analyzed. We present in this contribution an experimental study of this onset reaction measured in pouch Li-ion cells under various conditions of charge current and temperature. We also propose a lumped-parameter thermal model for the cell, which allows a detailed characterization of this exothermic reaction. The results achieved in this contributions can be a key tool to prevent overcharge accidents that may arise due to malfunctioning of the battery charger or battery management system.
Open Access
Temperature indicators and overtemperature detection in lithium-ion batteries based on electrochemical impedance spectroscopy
(IEEE, 2023) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Soto Cabria, Adrián; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
Lithium-ion batteries are the leading technology for energy storage systems due to their attractive advantages. However, the safety of lithium-ion batteries is a major concern, as their operating conditions are limited in terms of temperature, voltage and state of charge. Therefore, it is important to monitor the conditions of lithium-ion batteries to guarantee safe operation. To this end, in the present work, we analyze electrochemical impedance spectroscopy (EIS) as a tool to estimate the temperature of batteries. Overtemperature abuse tests from 25 °C to 140 °C are performed at various states of charge, and EIS measurements are obtained during the tests. The influence of temperature on cell impedance at different frequencies is analyzed and new findings are revealed. The real part of the impedance is identified to be the best indicator for cell temperature estimation by EIS. In addition, the best frequency to achieve accurate temperature monitoring, avoiding disturbances produced by state of charge variations, is proposed based on experimental results. Finally, EIS is proven to be a reliable technique for overtemperature and thermal runaway detection.
Open Access
Experimental evaluation of the safety performance of lithium-ion batteries based on abuse areas
(IEEE, 2024) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Valera, Juan José; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Gobierno de Navarra / Nafarroako Gobernua
Safety issues associated with lithium-ion batteries (LIBs) jeopardize their widespread adoption in both stationary applications and electric vehicles. One of the factors that can most affect the safety of a LIB is its chemistry. For this reason, this article aims to evaluate the safety of the two main current chemistries, LFP and NMC. In particular, the safety of both technologies is examined from the perspective of the areas of abuse that characterize their behavior beyond the safe operation area. A commercial 5 Ah pouch cell with LFP chemistry is subjected to various overtemperature and overcharge abuses at different conditions. The results obtained for LFP chemistry cell are discussed together with those for NMC cell from a previous work of the authors. Identification of the abuse areas allows for a comparative analysis of the safety of both chemistries, providing a valuable tool for classifying the abuse behavior of LIBs.

Berrueta Irigoyen, Alberto

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