Open Access
Onset of irreversible reactions in overcharging lithium-ion cells: an experimental and modeling approach
(IEEE, 2023) Irujo Izcue, Elisa; Berrueta Irigoyen, Alberto; Lalinde Sainz, Iñaki; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
Lithium-ion batteries are energy storage systems used in an increasing number of applications. Due to their flammable materials, their use entails risks of fire and explosion. The study of the abuse operation of these batteries before reaching the thermal runaway is a relevant research topic to prevent safety issues. There are various studies in the bibliography providing exhaustive thermal studies of the safe operating area, as well as concerning the thermal runaway. However, the onset irreversible reactions, that take place at a SOC around 110%, have not been properly analyzed. We present in this contribution an experimental study of this onset reaction measured in pouch Li-ion cells under various conditions of charge current and temperature. We also propose a lumped-parameter thermal model for the cell, which allows a detailed characterization of this exothermic reaction. The results achieved in this contributions can be a key tool to prevent overcharge accidents that may arise due to malfunctioning of the battery charger or battery management system.
Open Access
Applied method to model the thermal runaway of lithium-ion batteries
(IEEE, 2021) Lalinde Sainz, Iñaki; Berrueta Irigoyen, Alberto; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The thermal runaway (TR) is one of the most dangerous phenomena related to lithium-ion batteries. For this reason, there are different proposals in the literature for its modelling. Most of these proposed models take into account the decomposition reactions between the internal components of the cell, and base the adjustment of the parameters on numerous abuse tests that lead to the appearance of TR. However, these tests are destructive, require specific equipment, present a high economic cost and are very time consuming. This paper proposes a modelling method which enables the development of TR models with the use of fewer resources. This method is based on chemical kinetics, which allow a simplification of the general modelling process published in the literature. At the same time it maintains good accuracy and makes it possible to define the TR behavior of any type of cell, regardless of its chemistry, shape or size. Furthermore, the proposed method allows the use of the experimental results most commonly presented in the specialized literature, which significantly reduces the need for destructive testing. The presented modelling method achieves a good compromise between accuracy and applicability in the validations shown in the paper.
Open Access
New design alternatives for a hybrid photovoltaic and doubly-fed induction wind plant to augment grid penetration of renewable energy
(IEEE, 2021) Goñi, Naiara; Sacristán Sillero, Javier; Berrueta Irigoyen, Alberto; Rodríguez Rabadan, José Luis; Ursúa Rubio, Alfredo; Sanchis Gúrpide, Pablo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Reducing carbon emissions is essential to stop climate change. The grid-share of renewable generation plants is increasing, being wind and photovoltaic plants the most common ones, whereas conventional plants are the only ones that provide the necessary services to maintain the grid stability and keep the generation-demand balance. However, with the aim of achieving carbon-neutral generation, conventional plants are being dismantled. This leads to the imminent need of providing these services with renewable plants. Due to this challenge, this proposal analyses a hybrid plant composed by wind and photovoltaic generation with two types of storage, lithium-ion batteries and a thermal storage system based on volcanic stones. In order to compare both strategies, a technoeconomic methodology is explained that allows to optimally size the plant, using the current prices of each technology. The most cost-competitive proposal turns to be the hybrid plant with thermal storage, composed by 623.9 MW installed power and 21.9 GWh of storage, which could replace a 100 MW, 24/7 conventional power plant, with an LCOHS (levelized cost of hybrid system) of 118.38 €/MWh, providing identical grid services and an equivalent inertia in a way committed with the environment. This is in turn a zero-carbon emissions solution perfectly matched to a second life plan for a conventional power plant.
Open Access
Identification of critical parameters for the design of energy management algorithms for Li-ion batteries operating in PV power plants
(IEEE, 2020) Berrueta Irigoyen, Alberto; Soto Cabria, Adrián; Marcos Álvarez, Javier; Parra Laita, Íñigo de la; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, ReBMS PJUPNA1904; Gobierno de Navarra / Nafarroako Gobernua, 0011-1411-2018-000029 GERA
Lithium-ion batteries are gaining importance for a variety of applications due to their price decrease and characteristics improvement. For a proper use of such storage systems, an energy management algorithm (EMA) is required. A number of EMAs, with various characteristics, have been published recently, given the diverse nature of battery problems. The EMA of deterministic battery problems is usually based on an optimization algorithm. The selection of such an algorithm depends on a few problem characteristics, which need to be identified and closely analyzed. The aim of this article is to identify the critical optimization problem parameters that determine the most suitable EMA for a Li-ion battery. With this purpose, the starting point is a detailed model of a Li-ion battery. Three EMAs based on the algorithms used to face deterministic problems, namely dynamic, linear, and quadratic programming, are designed to optimize the energy dispatch of such a battery. Using real irradiation and power price data, the results of these EMAs are compared for various case studies. Given that none of the EMAs achieves the best results for all analyzed cases, the problem parameters that determine the most suitable algorithm are identified to be four, i.e., desired computation intensity, characteristics of the battery aging model, battery energy and power capabilities, and the number of optimization variables, which are determined by the number of energy storage systems, the length of the optimization problem, and the desired time step.
Open Access
Role of student associations in the acquisition of competences in university engineering programs
(IEEE, 2023) Samanes Pascual, Javier; Parra Laita, Íñigo de la; Berrueta Irigoyen, Alberto; Rosado Galparsoro, Leyre; Soto Cabria, Adrián; Elizondo Martínez, David; Catalán Ros, Leyre; Sanchis Gúrpide, Pablo; Institute of Smart Cities - ISC
Students in the STEM field (Science, Technology, Engineering and Mathematics), do not only require deep technical knowledge, but a complete set of global skills related to management, teamwork, lifelong learning, personal development, communications skills or proactiveness, abilities often referred as soft-skills. Student-led organizations, and specifically, university student associations, are one of the best alternatives to promote the acquisition of soft-skills in STEM high education fields. These skills are competences already included in official university programs that can hardly be addressed or acquired from traditional university education. This article studies how student enrollment in student led organizations (SLOs), with an active participation on their organization and activities, allows engineering students to achieve a better development of these soft skills. As case study, a medium size university, with 9000-students and eleven SLOs, six of them focused on STEM related fields, is used in this paper. A survey is conducted among the university community to identify their degree of participation in SLOs, and to test whether participation in these initiatives increases students' self-perception of their soft skill acquisition during their university studies. This survey shows how students of engineering programs, with a high degree of involvement in SLOs, demonstrated greater confidence in their soft skills at the end of their university years.
Open Access
Influence of the aging model of lithium-ion batteries on the management of PV self-consumption systems
(IEEE, 2018) Berrueta Irigoyen, Alberto; Pascual Miqueleiz, Julio María; San Martín Biurrun, Idoia; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua, PI038 INTEGRA-RENOVABLES
Lithium-ion batteries are gaining importance for a variety of applications due to their improving characteristics and decreasing price. An accurate knowledge of their aging is required for a successful use of these ESSs. The vast number of models that has been proposed to predict these phenomena raise doubts about the suitability of a model for a particular battery application. The performance of three models published for a Sanyo 18650 cylindrical cell in a self-consumption system are compared in this work. Measured photovoltaic production and home consumption with a sampling frequency of 15 minutes are used for this comparison. The different aging predictions calculated by these three models are analyzed, compared and discussed. These comparison is particularized for two management strategies. The first of them maximizes the self-consumption PV energy, while the second reduces the maximum power peak demanded from the grid.
Open Access
Comparison of State-of-Charge estimation methods for stationary Lithium-ion batteries
(IEEE, 2016) Berrueta Irigoyen, Alberto; San Martín Biurrun, Idoia; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Institute of Smart Cities - ISC
An accurate monitoring of the State of Charge (SoC) is mandatory for an efficient management of a Lithium-ion battery. Batteries of stationary systems barely have long resting periods when the cumulative errors can be reset. These special requirements make a robust and accurate SoC estimation algorithm necessary. A real stationary system including an experimental microgrid with renewable energy generation, home consumption and a 5.3 kWh Li-ion storage system is analyzed in this paper. Three representative SoC monitoring algorithms are applied and compared in terms of accuracy and robustness to battery aging and current measurement offset. A closed-loop method consisting of an adaptive filter and a state observer achieves best results while having a reasonable computational complexity.
Open Access
Impact of micro-cycles on the lifetime of lithium-ion batteries - EIS analysis
(IEEE, 2024-07-30) Nováková, Katerina; Berrueta Irigoyen, Alberto; Soto Cabria, Adrián; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Gobierno de Navarra / Nafarroako Gobernua
Experimental studies of lithium-ion batteries are very often based only on deep charge and discharge cycles. However, these test profiles do not fully reflect the actual operation of the battery in an electric vehicle or in stationary applications, where the battery is not only loaded during the main charging and discharging profiles, but it is also stressed by the current throughput caused by renewable power fluctuations or by auxiliary services. These cycles, which are superimposed to the main charge and discharge processes and have a depth of discharge not exceeding 2%, are called micro-cycles. Although there are several simulation studies that attempt to capture this issue, there is still no comprehensive experimental study that has the phenomena that occur during micro-cycling. This paper presents an experimental analysis of micro-cycles, providing a detailed view of the different processes taking place in the battery during aging, by means of a detailed analysis of the results from electrochemical impedance spectroscopy (EIS). By studying the single electrochemical processes in detail, this paper explains the benefits of micro-cycling in terms of extending the lifetime of the battery.
Open Access
Combined dynamic programming and region-elimination technique algorithm for optimal sizing and management of lithium-ion batteries for photovoltaic plants
(Elsevier, 2018) Berrueta Irigoyen, Alberto; Heck, Michael; Jantsch, Martin; Ursúa Rubio, Alfredo; Sanchis Gúrpide, Pablo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua PI038 INTEGRA-RENOVABLES
The unpredictable nature of renewable energies is drawing attention to lithium-ion batteries. In order to make full utilization of these batteries, some research works are focused on the management of existing systems, while others propose sizing techniques based on business models. However, in order to optimise the global system, a comprehensive methodology that considers both battery sizing and management at the same time is needed. This paper proposes a new optimisation algorithm based on a combination of dynamic programming and a region elimination technique that makes it possible to address both problems at the same time. This is of great interest, since the optimal size of the storage system depends on the management strategy and, in turn, the design of this strategy needs to take account of the battery size. The method is applied to a real installation consisting of a 100 kWp rooftop photovoltaic plant and a Li-ion battery system connected to a grid with variable electricity price. Results show that, unlike conventional optimisation methods, the proposed algorithm reaches an optimised energy dispatch plan that leads to a higher net present value. Finally, the tool is used to provide a sensitivity analysis that identifies key informative variables for decision makers
Open Access
Inertial response and inertia emulation in DFIG and PMSG wind turbines: emulating inertia from a supercapacitor-based energy storage system
(IEEE, 2021) Sacristán Sillero, Javier; Goñi, Naiara; Berrueta Irigoyen, Alberto; López Taberna, Jesús; Rodríguez Rabadan, José Luis; Ursúa Rubio, Alfredo; Sanchis Gúrpide, Pablo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The increasing wind power penetration in electrical power systems results in a reduction of operative conventional power plants. These plants include synchronous generators directly connected to the grid. Facing a change in grid frequency, these generators inherently respond by varying their stored kinetic energy and their output power, which contributes to grid stability. Such a response is known as inertial response. Wind turbines (WTs) are mostly based on Doubly-Fed Induction Generator (DFIG) or Permanent Magnet Synchronous Generator (PMSG) machines. Their power electronics interface decouples the electromechanical behaviour of the generator from the power grid, making their inertial response null or insignificant. Therefore, in order not to weaken the frequency response of the power system, WTs must be able to react to frequency variations by changing their output power, i.e., emulating an inertial response. Common techniques for inertia emulation in WTs rely on pitch control and stored kinetic energy variation. This contribution proposes a strategy (applicable for both DFIG and PMSG) which uses the energy stored in a supercapacitor connected to the back-to-back converter DC link to emulate the inertial response. Its performance is compared by simulation with aforementioned common techniques, showing ability to remove certain limitations.