Publication:
CO2 methanation over nickel catalysts: support effects investigated through specific activity and operando IR spectroscopy measurement

Simple item page
dc.contributor.authorGonzález Rangulan, Vigni Virginia
dc.contributor.authorReyero Zaragoza, Inés
dc.contributor.authorBimbela Serrano, Fernando
dc.contributor.authorRomero Sarria, Francisca
dc.contributor.authorDaturi, Marco
dc.contributor.authorGandía Pascual, Luis
dc.contributor.departmentCienciases_ES
dc.contributor.departmentZientziakeu
dc.contributor.departmentInstitute for Advanced Materials and Mathematics - INAMAT2en
dc.contributor.funderUniversidad Pública de Navarra / Nafarroako Unibertsitate Publikoaes
dc.date.accessioned2023-08-03T14:22:04Z
dc.date.available2023-08-03T14:22:04Z
dc.date.issued2023
dc.date.updated2023-08-03T14:15:12Z
dc.description.abstractRenewed interest in CO2 methanation is due to its role within the framework of the Power-to-Methane processes. While the use of nickel-based catalysts for CO2 methanation is well stablished, the support is being subjected to thorough research due to its complex effects. The objective of this work was the study of the influence of the support with a series of catalysts supported on alumina, ceria, ceria–zirconia, and titania. Catalysts’ performance has been kinetically and spectroscopically evaluated over a wide range of temperatures (150–500 °C). The main results have shown remarkable differences among the catalysts as concerns Ni dispersion, metallic precursor reducibility, basic properties, and catalytic activity. Operando infrared spectroscopy measurements have evidenced the presence of almost the same type of adsorbed species during the course of the reaction, but with different relative intensities. The results indicate that using as support of Ni a reducible metal oxide that is capable of developing the basicity associated with medium-strength basic sites and a suitable balance between metallic sites and centers linked to the support leads to high CO2 methanation activity. In addition, the results obtained by operando FTIR spectroscopy suggest that CO2 methanation follows the formate pathway over the catalysts under consideration.en
dc.description.sponsorshipFinancial support from Spanish Ministerio de Ciencia e Innovación and Agencia Estatal de Investigación MCIN/AEI/10.13039/501100011033/ and FEDER “Una manera de hacer Europa” (grant PID2021-127265OB-C21), as well as from Plan de Recuperación, Transformación y Resiliencia and NextGenerationEU (grants PLEC2022-009221 and TED2021-130846B-100) is gratefully acknowledged. Financial support from Universidad Pública de Navarra is also thanked for the PhD grant awarded to V.V. González-Rangulan. V.V. González-Rangulan also acknowledges the CNRS for the financial support, the guidance, and assistance provided during the 3-month research sojourn in ENSICAEN. L.M. Gandía also thanks Banco de Santander and Universidad Pública de Navarra for their financial support under “Programa de Intensificación de la Investigación 2018” initiative.en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationGonzález-Rangulan, V. V., Reyero, I., Bimbela, F., Romero-Sarria, F., Daturi, M., Gandía, L. M. (2023) CO2 methanation over nickel catalysts: support effects investigated through specific activity and operando IR spectroscopy measurement. Catalysts, 13(2), 1-25. https://doi.org/10.3390/catal13020448.en
dc.identifier.doi10.3390/catal13020448
dc.identifier.issn2073-4344
dc.identifier.urihttps://academica-e.unavarra.es/handle/2454/45875
dc.language.isoengen
dc.publisherMDPIen
dc.relation.ispartofCatalysts 2023, 13(2), 448en
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI//PID2021-127265OB-C21en
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI//PLEC2022-009221en
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI//TED2021-130846B-100en
dc.relation.publisherversionhttps://doi.org/10.3390/catal13020448
dc.rights© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.en
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectCarbon dioxideen
dc.subjectHydrogenationen
dc.subjectMethaneen
dc.subjectNickel catalystsen
dc.subjectOperando FTIRen
dc.subjectSupporten
dc.subjectTOFen
dc.titleCO2 methanation over nickel catalysts: support effects investigated through specific activity and operando IR spectroscopy measurementen
dc.typeinfo:eu-repo/semantics/article
dc.type.versionVersión publicada / Argitaratu den bertsioaes
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dspace.entity.typePublication
relation.isAuthorOfPublication9db8ae81-da7d-4fba-b7df-907e3438bd1f
relation.isAuthorOfPublicationa563cdcf-aa65-4dbf-902c-308aa67c766f
relation.isAuthorOfPublication87547128-c184-40ba-9780-0a2016749925
relation.isAuthorOfPublicationd2bd5a4b-ea1f-488b-afea-05b77f69d3f0
relation.isAuthorOfPublication.latestForDiscoverya563cdcf-aa65-4dbf-902c-308aa67c766f

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Gonzalez_CO2Methanation.pdf
Size:
2.63 MB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.78 KB
Format:
Item-specific license agreed to upon submission
Description:
Download

Collections

Artículos de revista DCIE - ZIES Aldizkari artikuluak
Artículos de revista - Aldizkari artikuluak
Artículos de revista INAMAT2 - INAMAT2 aldizkari artikuluak