Publication:
Multifunctional protective PVC-ZnO nanocomposite coatings deposited on aluminum alloys by electrospinning

dc.contributor.authorIribarren Zabalegui, Álvaro
dc.contributor.authorRivero Fuente, Pedro J.
dc.contributor.authorBerlanga Labari, Carlos
dc.contributor.authorLarumbe Abuin, Silvia
dc.contributor.authorMiguel, Adrián
dc.contributor.authorRodríguez Trías, Rafael
dc.contributor.departmentIngeniaritzaeu
dc.contributor.departmentInstitute for Advanced Materials and Mathematics - INAMAT2en
dc.contributor.departmentIngenieríaes_ES
dc.contributor.funderUniversidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, PRO-UPNA 18 (6107)es
dc.date.accessioned2019-11-25T13:16:00Z
dc.date.available2019-11-25T13:16:00Z
dc.date.issued2019
dc.description.abstractThis paper reports the use of the electrospinning technique for the synthesis of nanocomposite micro/nanofibers by combining a polymeric precursor with hydrophobic behavior like polyvinyl chloride (PVC) with nanoparticles of a corrosion inhibitor like ZnO. These electrospun fibers were deposited on substrates of the aluminum alloy 6061T6 until forming a coating around 100 m. The effect of varying the different electrospinning deposition parameters (mostly applied voltage and flow-rate) was exhaustively analyzed in order to optimize the coating properties. Several microscopy and analysis techniques have been employed, including optical microscopy (OM), field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Water contact angle (WCA) measurements have been carried out in order to corroborate the coating hydrophobicity. Finally, their corrosion behavior has been evaluated by electrochemical tests (Tafel curves and pitting potential measurements), showing a relevant improvement in the resultant corrosion resistance of the coated aluminum alloys.en
dc.description.sponsorshipThis research was funded by the Spanish Economy and Competitiveness Ministry, FEDER (Project TRA2013-48603-C4-1-R-HELADA) and by the Public University of Navarra collaboration research grant PRO-UPNA 18 (6107).en
dc.format.extent13 p.
dc.format.mimetypeapplication/pdfen
dc.identifier.doi10.3390/coatings9040216
dc.identifier.issn2079-6412
dc.identifier.urihttps://academica-e.unavarra.es/handle/2454/35451
dc.language.isoengen
dc.publisherMDPIen
dc.relation.ispartofCoatings, 2019, 9(4), 216en
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//TRA2013-48603-C4-1-R/ES/en
dc.relation.publisherversionhttps://doi.org/10.3390/coatings9040216
dc.rights© 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.en
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectElectrospinningen
dc.subjectCorrosionen
dc.subjectSuperhydrophobicen
dc.subjectPVC-ZnOen
dc.subjectNanocomposite coatingen
dc.titleMultifunctional protective PVC-ZnO nanocomposite coatings deposited on aluminum alloys by electrospinningen
dc.typeinfo:eu-repo/semantics/article
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.type.versionVersión publicada / Argitaratu den bertsioaes
dspace.entity.typePublication
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