Oxidative steam reforming of glycerol. A review
| dc.contributor.author | Moreira, Rui | |
| dc.contributor.author | Bimbela Serrano, Fernando | |
| dc.contributor.author | Gandía Pascual, Luis | |
| dc.contributor.author | Ferreira, Abel | |
| dc.contributor.author | Sánchez, José Luis | |
| dc.contributor.author | Portugal, Antonio | |
| dc.contributor.department | Institute for Advanced Materials and Mathematics - INAMAT2 | en |
| dc.contributor.funder | Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa | es |
| dc.date.accessioned | 2022-02-14T08:39:00Z | |
| dc.date.available | 2023-06-11T23:00:10Z | |
| dc.date.issued | 2021 | |
| dc.description.abstract | This review article presents the state-of-the-art on the catalytic oxidative steam reforming (OSR) of glycerol to produce syngas. Concerning the different technologies proposed for the catalytic OSR of glycerol, the following key points can be highlighted: (1) the robustness is much higher than other reforming technologies, (2) several catalysts can work with low deactivation, some of which can recover almost full activity by suitable regeneration, (3) syngas production by catalytic OSR of glycerin is higher than with concurrent technologies, (4) their scaling-up remains an unrealized task, (5) the thermodynamics of the process has been sufficiently covered in the literature, (6) there is a significant lack of kinetic and mechanistic studies that could help gaining deeper insight on the process, (7) novel concepts and reactor designs must be proposed for their development at larger scales, (8) new catalyst formulations must be developed for attaining higher resistance against oxidation and (9) process intensification could help developing them at larger scales. | en |
| dc.description.sponsorship | António Portugal and Rui Moreira are grateful to the Portuguese Foundation for Science and Technology (FCT) and the European Development Regional Fund (ERDF) for funding under the scope of the MultiBiorefinery project (POCI-01-0145-FEDER-016403). Luis M. Gandía thanks Banco de Santander and Universidad Pública de Navarra for their financial support under the 'Programa de Intensificación de la Investigación 2018' initiative. Fernando Bimbela and Luis M. Gandía wish to thank financial support from Spanish Ministerio de Ciencia, Innovación y Universidades , and the European Regional Development Fund ( ERDF / FEDER ) (grant RTI2018-096294-B-C31). José Luis Sánchez expresses his gratitude to Aragón Government (Ref. T22_20R), co-funded by FEDER 2014–2020 'Construyendo Europa desde Aragón' for providing frame support for this work. | en |
| dc.embargo.lift | 2023-06-11 | |
| dc.embargo.terms | 2023-06-11 | |
| dc.format.extent | 50 p. | |
| dc.format.mimetype | application/pdf | en |
| dc.identifier.doi | 10.1016/j.rser.2021.111299 | |
| dc.identifier.issn | 1364-0321 | |
| dc.identifier.uri | https://academica-e.unavarra.es/handle/2454/42192 | |
| dc.language.iso | eng | en |
| dc.publisher | Elsevier | en |
| dc.relation.ispartof | Renewable and Sustainable Energy Reviews, Vol. 148, September 2021, pp. 111299 | en |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-096294-B-C31/ES/ | |
| dc.relation.publisherversion | https://doi.org/10.1016/j.rser.2021.111299 | |
| dc.rights | © 2021 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 | en |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject | Autothermal reforming | en |
| dc.subject | Glycerin | en |
| dc.subject | Oxidative steam reforming | en |
| dc.subject | Structured catalytic reactors | en |
| dc.subject | Syngas | en |
| dc.title | Oxidative steam reforming of glycerol. A review | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.type.version | info:eu-repo/semantics/acceptedVersion | |
| dspace.entity.type | Publication | |
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| relation.isAuthorOfPublication.latestForDiscovery | 87547128-c184-40ba-9780-0a2016749925 |