How the pretreatment temperature of zeolitic catalysts can affect the reaction temperature of methanol to olefins and gasoline processes
| dc.contributor.author | Yunes, Simón | |
| dc.contributor.author | Rosas, Abel Gaspar | |
| dc.contributor.author | Gil Bravo, Antonio | |
| dc.contributor.department | Ciencias | es_ES |
| dc.contributor.department | Zientziak | eu |
| dc.contributor.department | Institute for Advanced Materials and Mathematics - INAMAT2 | en |
| dc.date.accessioned | 2025-03-25T16:40:30Z | |
| dc.date.available | 2025-03-25T16:40:30Z | |
| dc.date.issued | 2025-03-20 | |
| dc.date.updated | 2025-03-25T16:28:39Z | |
| dc.description.abstract | The dehydration of methanol to produce light olefins and gasoline, known as MTO (methanol-to-olefins) process requires acidic catalysts that maintain their acidity at reaction temperatures. Zeolites, such as SAPOs and ZSM-5, are commonly used for this purpose due to their acidic centers. The initial step in these experiments involves the activation or pretreatment of these solids to remove physically adsorbed water from their pores. Inadequate pretreatment can lead to the destruction of the existing Brönsted sites through the dihydroxylation of surface -OH groups. Therefore, it is crucial to pretreat the zeolites properly to preserve the Brönsted sites. One method is to subject the fresh catalyst to programmed dehydration, which involves desorption at a controlled temperature while monitoring the appearance of water that results from Brönsted site dihydroxylation. The temperature at which the dehydration peak appears determines the optimal reaction temperature. The results presented in this work will demonstrate the progressive deactivation of the catalysts when the reaction temperature exceeds 400 °C. | en |
| dc.description.sponsorship | A.G. is grateful for financial support from the Spanish Ministry of Science and Innovation (MCIN/AEI/10.13039/501100011033) through project PID2023-146935OB-C21. | |
| dc.format.mimetype | application/pdf | en |
| dc.identifier.citation | Yunes, S., Rosas, A. G., Gil, A. (2025) How the pretreatment temperature of zeolitic catalysts can affect the reaction temperature of methanol to olefins and gasoline processes. Materials, 18(6), 1-11. https://doi.org/10.3390/ma18061370. | |
| dc.identifier.doi | 10.3390/ma18061370 | |
| dc.identifier.issn | 1996-1944 | |
| dc.identifier.uri | https://academica-e.unavarra.es/handle/2454/53826 | |
| dc.language.iso | eng | |
| dc.publisher | MDPI | |
| dc.relation.ispartof | Materials 2025, 18(6), 1370 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-146935OB-C21/ES/ | |
| dc.relation.publisherversion | https://doi.org/10.3390/ma18061370 | |
| dc.rights | © 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license. | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | Methanol | en |
| dc.subject | Olefins | en |
| dc.subject | Dehydration | en |
| dc.subject | Temperature-programmed desorption (TPD) | en |
| dc.subject | Acidity | en |
| dc.title | How the pretreatment temperature of zeolitic catalysts can affect the reaction temperature of methanol to olefins and gasoline processes | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | cd12e590-cb42-47d5-a642-f60eeee624ec | |
| relation.isAuthorOfPublication.latestForDiscovery | cd12e590-cb42-47d5-a642-f60eeee624ec |