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Preparation of Ca2Al1–mFem(OH)6Cl 2H2O-doped hydrocalumites and application of their derived mixed oxides in the photodegradation of ibuprofen

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dc.contributor.authorJiménez, Alejandro
dc.contributor.authorValverde, Marta
dc.contributor.authorMisol, Alexander
dc.contributor.authorTrujillano, Raquel
dc.contributor.authorGil Bravo, Antonio
dc.contributor.authorVicente, Miguel Ángel
dc.contributor.departmentInstitute for Advanced Materials and Mathematics - INAMAT2en
dc.date.accessioned2022-08-19T07:39:40Z
dc.date.available2022-08-19T07:39:40Z
dc.date.issued2022
dc.date.updated2022-08-19T07:34:34Z
dc.description.abstractAluminum from saline slags generated during the recycling of this metal, extracted under reflux conditions with aqueous NaOH, was used in the synthesis of hydrocalumite-type solids with the formula Ca2Al1–mFem(OH)6Cl 2H2O. The characterization of the obtained solids was carried out by powder X-ray diffraction, infrared spectroscopy, thermal analysis, element chemical analysis, N2 adsorption-desorption at -196ºC and electron microscopy. The results showed the formation of Layered Double Hydroxide-type compounds whose characteristics varied as the amount of incorporated Fe3+ increased. These solids were calcined at 400ºC and evaluated for the catalytic photodegradation of ibuprofen, showing promising results in the elimination of this drug by advanced oxidation processes. The CaAl photocatalyst (without Fe) showed the best performance under UV light for the photodegradation of ibuprofen.en
dc.description.sponsorshipThis research was funded by Universidad de Salamanca (Plan I-B2).en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationJimenez, A.; Valverde, M.; Misol, A.; Trujillano, R.; Gil-Bravo, A.; Vicente, M. A.. (2022). Preparation of Ca2Al1-mFem(OH)6Cl·2H2O-doped hydrocalumites and application of their derived mixed oxides in the photodegradation of ibuprofen. ChemEngineering. 6,64 1-18 .en
dc.identifier.doi10.3390/chemengineering6040064
dc.identifier.issn2305-7084
dc.identifier.urihttps://academica-e.unavarra.es/handle/2454/43824
dc.language.isoengen
dc.publisherMDPIen
dc.relation.ispartofChemEngineering 2022, 6, 64en
dc.relation.publisherversionhttps://doi.org/10.3390/chemengineering6040064
dc.rights© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.en
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectHydrocalumiteen
dc.subjectAluminum saline slag recoveryen
dc.subjectPhotocatalysisen
dc.subjectIbuprofen degradationen
dc.titlePreparation of Ca2Al1–mFem(OH)6Cl 2H2O-doped hydrocalumites and application of their derived mixed oxides in the photodegradation of ibuprofenen
dc.typeinfo:eu-repo/semantics/article
dc.type.versionVersión publicada / Argitaratu den bertsioaes
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
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relation.isAuthorOfPublicationcd12e590-cb42-47d5-a642-f60eeee624ec
relation.isAuthorOfPublication.latestForDiscoverycd12e590-cb42-47d5-a642-f60eeee624ec

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