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Asymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalent

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dc.contributor.authorIriarte, Igores_ES
dc.contributor.authorVera, Silviaes_ES
dc.contributor.authorBadiola, Eideres_ES
dc.contributor.authorMielgo, Antoniaes_ES
dc.contributor.authorOiarbide, Mikeles_ES
dc.contributor.authorGarcía Castillo, Jesús María
dc.contributor.authorOdriozola Ibarguren, José Manuel
dc.contributor.authorPalomo, Claudioes_ES
dc.contributor.departmentQuímica Aplicadaes_ES
dc.contributor.departmentKimika Aplikatuaeu
dc.date.accessioned2024-01-30T11:40:10Z
dc.date.available2024-01-30T11:40:10Z
dc.date.issued2016
dc.date.updated2024-01-30T11:27:57Z
dc.description.abstractAn efficient, highly diastereo- and enantioselective assembly of acyclic carbonyl fragments possessing nonadjacent all-carbon tertiary/quaternary stereoarrays is reported based on a Brønsted base catalyzed Michael addition/a-protonation sequence involving a-cyanoacetates and 2,4-dimethyl-4-hydroxypenten-3-one as novel methacrylate equivalent.en
dc.description.sponsorshipSupport was provided by the University of the Basque Country UPV/EHU (UFI 11/22), Gobierno Vasco (GV,GrantNoIT-628-13),and Ministerio de Economía y Competitividad (MEC,Grant CTQ 2013-47925-C2), Spain.en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationIriarte, I., Vera, S., Badiola, E., Mielgo, A., Oiarbide, M., García, J. M., Odriozola, J. M., & Palomo, C. (2016). Asymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalent. Chemistry – A European Journal, 22(38), 13690-13696. https://doi.org/10.1002/chem.201603082en
dc.identifier.doi10.1002/chem.201603082
dc.identifier.issn0947-6539
dc.identifier.urihttps://academica-e.unavarra.es/handle/2454/47251
dc.language.isoengen
dc.publisherWileyen
dc.relation.ispartofChemistry – A European Journal 2016, 22, 13690 – 13696en
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//CTQ2013-47925-C2-2-P/ES/en
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201603082
dc.rights© 2016 Wiley-VCH Verlag GmbH & Co.en
dc.rights.accessRightsAcceso abierto / Sarbide irekiaes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.subjectAsymmetric organocatalysisen
dc.subjectMichael reactionsen
dc.subjectStereoselective protonationen
dc.subjectQuaternary stereocentersen
dc.subjectBrønsted basesen
dc.titleAsymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalenten
dc.typeArtículo / Artikuluaes
dc.typeinfo:eu-repo/semantics/articleen
dc.type.versionVersión aceptada / Onetsi den bertsioaes
dc.type.versioninfo:eu-repo/semantics/acceptedVersionen
dspace.entity.typePublication
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relation.isAuthorOfPublication7eb540a5-6611-491d-a1a6-7fadcff366f0
relation.isAuthorOfPublication.latestForDiscoverycc7e9b93-b971-4b05-9d6c-a8e93ab0a131

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