A comparative study in the design of TIO2 assisted photocatalytic coatings monitored by controlling hydrophilic behavior and rhodamine b degradation

dc.contributor.authorSandúa Fernández, Xabier
dc.contributor.authorRivero Fuente, Pedro J.
dc.contributor.authorConde, Ana
dc.contributor.authorEsparza Gorráiz, Joseba
dc.contributor.authorRodríguez Trías, Rafael
dc.contributor.departmentIngenieríaes_ES
dc.contributor.departmentIngeniaritzaeu
dc.contributor.departmentInstitute for Advanced Materials and Mathematics - INAMAT2en
dc.date.accessioned2023-07-18T17:55:36Z
dc.date.available2023-07-18T17:55:36Z
dc.date.issued2023
dc.date.updated2023-07-18T17:49:44Z
dc.description.abstractThis work presents a comparative study related to the photocatalytic efficiency associated with wettability measurements and organic dye degradation, as well as other relevant properties (i.e., corrosion resistance, roughness, wettability, and adhesion to a substrate). The photocatalytic precursors are titanium dioxide nanoparticles (TiO2 NPs) which are dispersed onto a polymeric electrospun fiber matrix by using three different deposition techniques such as electrospraying, spraying, and dip-coating, respectively. In this work, the host electrospun matrix is composed of poly(acrylic acid) fibers crosslinked with cyclodextrin (β-CD), which shows a good chemical affinity and stability with the other deposition techniques which are responsible for incorporating the TiO2 NPs. In order to evaluate the efficacy of each coating, the resultant photocatalytic activity has been monitored by two different tests. Firstly, the reduction in the water contact angle is appreciated, and secondly, the degradation of an organic dye (Rhodamine B) is observed under UV irradiation. In addition, the final roughness, adherence, and pitting corrosion potential have also been controlled in order to determine which solution provides the best combination of properties. Finally, the experimental results clearly indicate that the presence of TiO2 NPs deposited by the three techniques is enough to induce a super hydrophilic behavior after UV irradiation. However, there are notable differences in photocatalytic efficiency on the Rhodamine B as a function of the selected deposition technique.en
dc.description.sponsorshipThis research was funded by the Government of Navarra—Department of Economic Development (PC080/081 GREEN-COPPER).en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationSandua, X., Rivero, P. J., Conde, A., Esparza, J., & Rodríguez, R. (2023). A comparative study in the design of tio2 assisted photocatalytic coatings monitored by controlling hydrophilic behavior and rhodamine b degradation. Materials, 16(7), 2589. https://doi.org/10.3390/ma16072589en
dc.identifier.doi10.3390/ma16072589
dc.identifier.issn1996-1944
dc.identifier.urihttps://academica-e.unavarra.es/handle/2454/45790
dc.language.isoengen
dc.publisherMDPIen
dc.relation.ispartofMaterials 2023, 16(7), 2589en
dc.relation.projectIDinfo:eu-repo/grantAgreement/Gobierno de Navarra//PC080%2F081 GREEN-COPPER/
dc.relation.publisherversionhttps://doi.org/10.3390/ma16072589
dc.rights2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.en
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectDip coatingen
dc.subjectElectrosprayingen
dc.subjectPhotocatalysisen
dc.subjectSprayingen
dc.subjectWettabilityen
dc.titleA comparative study in the design of TIO2 assisted photocatalytic coatings monitored by controlling hydrophilic behavior and rhodamine b degradationen
dc.typeinfo:eu-repo/semantics/article
dc.type.versioninfo:eu-repo/semantics/publishedVersion
dspace.entity.typePublication
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relation.isAuthorOfPublication.latestForDiscoveryccf8da2b-8e86-4e57-835a-358562d70571

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