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Consecutive single-crystal-to-single-crystal isomerization of novel octamolybdate anions within a microporous hybrid framework with robust water sorption properties
dc.creator | Ruiz Bilbao, Estíbaliz | es_ES |
dc.creator | Iturrospe, Amaia | es_ES |
dc.creator | Reinoso, Santiago | es_ES |
dc.creator | Artetxe, Beñat | es_ES |
dc.creator | Beobide, Garikoitz | es_ES |
dc.creator | San Felices, Leire | es_ES |
dc.creator | Lezama, Luis | es_ES |
dc.creator | Gutiérrez Zorrilla, Juan M. | es_ES |
dc.creator | Darwish, Shaza | es_ES |
dc.creator | Sensharma, Debobroto | es_ES |
dc.creator | Zaworotko, Michael J. | es_ES |
dc.date.accessioned | 2023-10-26T11:24:39Z | |
dc.date.available | 2023-10-26T11:24:39Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | Ruiz‐Bilbao, E., Iturrospe, A., Reinoso, S., Artetxe, B., Beobide, G., San Felices, L., Lezama, L., Gutiérrez‐Zorrilla, J. M., Darwish, S., Sensharma, D., & Zaworotko, M. J. (2023). Consecutive single‐crystal‐to‐single‐crystal isomerization of novel octamolybdate anions within a microporous hybrid framework with robust water sorption properties. Angewandte Chemie International Edition, 62(42), e202307436. https://doi.org/10.1002/anie.202307436 | en |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | https://hdl.handle.net/2454/46649 | |
dc.description.abstract | The 3D hybrid framework [{Cu(cyclam)}3(kMo8O27)]· 14H2O (1) (cyclam=1,4,8,11-tetraazacyclotetradecane) undergoes sequential single-crystal-to-singlecrystal transformations upon heating to afford two different anhydrous phases (2 a and 3a). These transitions modify the framework dimensionality and enable the isomerization of k-octamolybdate (k-Mo8) anions into λ (2 a) and μ (3 a) forms through metal migration. Hydration of 3 a involves condensation of one water molecule to the cluster to afford the γ-Mo8 isomer in 4, which dehydrates back into 3a through the 6a intermediate. In contrast, 2a reversibly hydrates to form 5, exhibiting the same Mo8 cluster as that of 1. It is remarkable that three of the Mo8 clusters (k, λ and μ) are new and that up to three different microporous phases can be isolated from 1 (2 a, 3a, and 6a). Water vapor sorption analyses show high recyclability and the highest uptake values for POM-based systems. The isotherms display an abrupt step at low humidity level desirable for humidity control devices or water harvesting in drylands. | en |
dc.description.sponsorship | Funded by Eusko Jaurlaritza/Gobierno Vasco (EJ/GV, grants IT1722-22 and KK-2022/00045). E.R.B. thanks EJ/GV for her doctoral fellowship (PRE_2018_1_0143). | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Wiley | en |
dc.relation.ispartof | Angewandte Chemie International 2023, 62, e202307436 (1 of 9) | en |
dc.rights | © 2023 The Authors. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made | en |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject | Microporous Materials | en |
dc.subject | Polyoxometalates | en |
dc.subject | Single-Crystal-to-Single-Crystal | en |
dc.subject | Solid-State Isomerization | en |
dc.subject | Water Sorption | en |
dc.title | Consecutive single-crystal-to-single-crystal isomerization of novel octamolybdate anions within a microporous hybrid framework with robust water sorption properties | en |
dc.type | Artículo / Artikulua | es |
dc.type | info:eu-repo/semantics/article | en |
dc.date.updated | 2023-10-26T11:16:43Z | |
dc.contributor.department | Ciencias | es_ES |
dc.contributor.department | Zientziak | eu |
dc.contributor.department | Institute for Advanced Materials and Mathematics - INAMAT2 | en |
dc.rights.accessRights | Acceso abierto / Sarbide irekia | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
dc.identifier.doi | 10.1002/anie.202307436 | |
dc.relation.publisherversion | https://doi.org/10.1002/anie.202307436 | |
dc.type.version | Versión publicada / Argitaratu den bertsioa | es |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
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La licencia del ítem se describe como © 2023 The Authors. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made