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Synthesis and molecular structures of palladium(II) metalated 2-phenylpyridine complexes [PdCl(pyC6H4)L] containing amino- or acetylamino-pyridine co-ligands
dc.creator | Al-Jibori, Subhi A. | es_ES |
dc.creator | Gergees, Hayfa M. | es_ES |
dc.creator | Al-Rubaye, Mousa S. | es_ES |
dc.creator | Basak-Modi, Sucharita | es_ES |
dc.creator | Luquin, Asunción | es_ES |
dc.date.accessioned | 2020-09-22T07:53:15Z | |
dc.date.available | 2020-09-22T07:53:15Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | https://hdl.handle.net/2454/38209 | |
dc.description.abstract | A number of cyclometalated palladium(II) complexes [PdCl(pyC6H4)(L)] containing amino-pyridine or acetylamino-pyridine co-ligands (L) have been prepared from the reaction of [Pd(pyC6H4)(μ-Cl)]2 with two equivalents of these ligands. Crystal structures of four examples have been carried out, each showing a distorted square planer geometry around palladium with the amino- or acetylamino-pyridine ligand being coordinated via nitrogen atom and lying almost perpendicular to the square-plane. Similarly, [PdCl(pyC6H4)(κ1-dppmO)] and [PdCl(pyC6H4)(κ1-dppeO)] result from reactions of [Pd(C6H4py)(μ-Cl)]2 with Ph2PCH2P(O)PPh2 (dppmO) and Ph2PCH2CH2P(O)PPh2 (dppeO) respectively. Here the phosphine ligand is attached via only phosphorus, however, removal of the chloride upon addition of AgNO3 lead to the formation of [Pd(pyC6H4)(κ2-dppmO)][NO3] and [Pd(pyC6H4)(κ2-dppeO)][NO3] in which the ligands are believed to bind in a chelate fashion. | en |
dc.description.sponsorship | The authors would like to thank the University of Tikrit for partial support of this work and the Erasmus-Mundus programme for the provision of a post-doctoral fellowship to S.B.-M. | en |
dc.format.extent | 23 p. | |
dc.format.mimetype | application/pdf | en |
dc.format.mimetype | application/zip | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.relation.ispartof | Inorganica Chimica Acta, 2016, 450, 50-56 | en |
dc.rights | © 2016 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0. | en |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject | Palladium | en |
dc.subject | Cyclometalated | en |
dc.subject | Crystal structure | en |
dc.subject | 2-Phenylpyridine | en |
dc.subject | Synthesis | en |
dc.title | Synthesis and molecular structures of palladium(II) metalated 2-phenylpyridine complexes [PdCl(pyC6H4)L] containing amino- or acetylamino-pyridine co-ligands | en |
dc.type | info:eu-repo/semantics/article | en |
dc.type | Artículo / Artikulua | es |
dc.contributor.department | Química Aplicada | es_ES |
dc.contributor.department | Kimika Aplikatua | eu |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
dc.rights.accessRights | Acceso abierto / Sarbide irekia | es |
dc.identifier.doi | 10.1016/j.ica.2016.04.046 | |
dc.relation.publisherversion | https://doi.org/10.1016/j.ica.2016.04.046 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | en |
dc.type.version | Versión aceptada / Onetsi den bertsioa | es |