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Asymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalent
| dc.creator | Iriarte, Igor | es_ES |
| dc.creator | Vera, Silvia | es_ES |
| dc.creator | Badiola, Eider | es_ES |
| dc.creator | Mielgo, Antonia | es_ES |
| dc.creator | Oiarbide, Mikel | es_ES |
| dc.creator | García Castillo, Jesús María | es_ES |
| dc.creator | Odriozola Ibarguren, José Manuel | es_ES |
| dc.creator | Palomo, Claudio | es_ES |
| dc.date.accessioned | 2024-01-30T11:40:10Z | |
| dc.date.available | 2024-01-30T11:40:10Z | |
| dc.date.issued | 2016 | |
| dc.identifier.citation | Iriarte, I., Vera, S., Badiola, E., Mielgo, A., Oiarbide, M., García, J. M., Odriozola, J. M., & Palomo, C. (2016). Asymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalent. Chemistry – A European Journal, 22(38), 13690-13696. https://doi.org/10.1002/chem.201603082 | en |
| dc.identifier.issn | 0947-6539 | |
| dc.identifier.uri | https://hdl.handle.net/2454/47251 | |
| dc.description.abstract | An efficient, highly diastereo- and enantioselective assembly of acyclic carbonyl fragments possessing nonadjacent all-carbon tertiary/quaternary stereoarrays is reported based on a Brønsted base catalyzed Michael addition/a-protonation sequence involving a-cyanoacetates and 2,4-dimethyl-4-hydroxypenten-3-one as novel methacrylate equivalent. | en |
| dc.description.sponsorship | Support was provided by the University of the Basque Country UPV/EHU (UFI 11/22), Gobierno Vasco (GV,GrantNoIT-628-13),and Ministerio de Economía y Competitividad (MEC,Grant CTQ 2013-47925-C2), Spain. | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | Wiley | en |
| dc.relation.ispartof | Chemistry – A European Journal 2016, 22, 13690 – 13696 | en |
| dc.rights | © 2016 Wiley-VCH Verlag GmbH & Co. | en |
| dc.subject | Asymmetric organocatalysis | en |
| dc.subject | Michael reactions | en |
| dc.subject | Stereoselective protonation | en |
| dc.subject | Quaternary stereocenters | en |
| dc.subject | Brønsted bases | en |
| dc.title | Asymmetric assembly of all‐carbon tertiary/quaternary nonadjacent stereocenters through organocatalytic conjugate addition of α‐cyanoacetates to a methacrylate equivalent | en |
| dc.type | Artículo / Artikulua | es |
| dc.type | info:eu-repo/semantics/article | en |
| dc.date.updated | 2024-01-30T11:27:57Z | |
| dc.contributor.department | Química Aplicada | es_ES |
| dc.contributor.department | Kimika Aplikatua | eu |
| dc.rights.accessRights | Acceso abierto / Sarbide irekia | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
| dc.identifier.doi | 10.1002/chem.201603082 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2013-47925-C2-2-P/ES/ | en |
| dc.relation.publisherversion | https://doi.org/10.1002/chem.201603082 | |
| dc.type.version | Versión aceptada / Onetsi den bertsioa | es |
| dc.type.version | info:eu-repo/semantics/acceptedVersion | en |
