ISFOOD - Institute on Innovation & Sustainable Development in Food Chain

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Open Access
25 years of continuous sewage sludge application vs. mineral fertilizers on a calcareous soil affected pH but not soil carbonates
(Frontiers Media, 2022) De Soto García, Isabel Sonsoles; Zamanian, Kazem; Urmeneta Martín-Calero, Henar; Enrique Martín, Alberto; Virto Quecedo, Íñigo; Zientziak; Estatistika, Informatika eta Matematika; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Ciencias; Estadística, Informática y Matemáticas; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Inorganic and organic fertilizers have been widely used to maintain crop yields. However, several studies have demonstrated that the dissolution of carbonates in agricultural soils by the acidification induced by N-fertilizers can result in their total or partial loss in the tilled layer of some agricultural soils. The effect of inorganic and organic fertilization on carbonates in calcareous semiarid Mediterranean soils has been less studied and is still unclear. Based on a 25-year field experiment, we investigated the effects of different fertilization strategies on the soil pH, inorganic C content, and in the proportion of pedogenic carbonates in the topsoil (0-30 cm) of a carbonate-rich soil in Navarre (N Spain). Five treatments were compared: no amendments as a control (SC), mineral fertilization (MF), and the application of sewage sludge at different doses (80 Mg ha-1 every year (80-1), 40 Mg ha-1 every year (40-1) and 40 Mg ha-1 every four years (40-4). Results showed a decrease in soil pH values by increasing the amount of sewage sludge and a small alteration in the calcite structure particularly in 40-4. However, no significant differences between treatments were found in the total content of carbonates nor in the proportion of pedogenic carbonates. The high concentration of total carbonates in the soil (16.09 ± 0.48%), and of the proportion of pedogenic carbonates (40.21 ± 1.29%, assuming a δ13C of primary carbonates = 0 ‰) seemed elevated enough to compensate for the observed acidification in the studied soil. In the case of MF, no changes were observed in the pH values, nor in the carbonate content (total and pedogenic). This suggests that the use of sewage sludge could induce changes in the future at a faster rate and of greater dimension than the use of mineral fertilizers such as the ones used in this field (46% urea, superphosphate and ClK).
Open Access
Carbon and water footprints of the revalorisation of glucosinolates from broccoli by-products: case study from Spain
(Elsevier, 2025-05-01) González Peñalver, José Miguel; Martínez Aldaya, Maite; Muez, Ane Maite; Martín-Guindal, Andrea; Beriain Apesteguía, María José; Agronomía, Biotecnología y Alimentación; Agronomia, Bioteknologia eta Elikadura; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Ciencias; Zientziak; Gobierno de Navarra / Nafarroako Gobernua
Assessing the costs, benefits, and externalities of circular economy measures from a life cycle perspective is increasingly important for developing sustainable agro-food strategies. This study evaluates the carbon and water implications of revalorising glucosinolates from broccoli by-products through two distinct life-cycle scenarios in a case study conducted in Navarra, Spain. In the first scenario, glucosinolates are obtained from conventional broccoli production, where they are naturally present in the edible inflorescences. The second scenario introduces an innovative step: extracting glucosinolates from otherwise discarded broccoli by-products, such as stalks and inflorescence detachments. Carbon and water footprints were analysed for both scenarios based on the production of 1000 grams of glucosinolates. The results reveal that while the second scenario enhances resource efficiency by utilizing agricultural waste, the environmental costs of the extraction process outweigh the benefits, leading to a 37.6 % increase in greenhouse gas emissions and a 4.6 % rise in water usage compared to the first scenario. To address this, an improvement scenario is proposed, featuring a more efficient use of solvents during extraction, which significantly reduces both emissions and water use. This study underscores that circular economy strategies in agro-food systems do not always translate into environmental benefits accross all resources. A detailed analysis of various carbon and water indicators has provided valuable insights to enhance the environmental performance of such strategies, reinforcing the importance of life-cycle assessments in shaping more effective agro-food policies.
Open Access
Cerámicas mudéjares en el entorno de la meseta castellana: hallazgos en Bonilla de la Sierra (Ávila)
(Universidad Autónoma de Madrid, Departamento de Prehistoria y Arqueología, 2022) Soto García, María de los Reyes de; Caballero Arribas, Jesús; Cabrera González, Blas; García Giménez, Rosario; De Soto García, Isabel Sonsoles; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
Las excavaciones realizadas en la muralla de Bonilla de la Sierra (Ávila, España) han sacado a la luz un conjunto de cerámicas procedentes de los siglos xiv/xv, de factura mudéjar (lozas decoradas en verde-manganeso, azul cobalto y dorado) y otras de producción local. Su estudio por métodos mineralógicos (Difracción de Rayos X —DRX— y microscopia óptica) y químicos (Masas con Plasma de Acoplamiento Inductivo —ICP/MS—) comparándolas con la cerámica local, las vincula con algunos fragmentos de alfares ubicados en la zona, aún no identificados, y permite establecer una correspondencia con otros conjuntos aparecidos en localidades cercanas, situadas en la Meseta castellana. El conjunto de lozas decoradas no es uniforme. Sus relaciones Pb/Sn fluctúan en amplios márgenes y permiten diferenciar cerámicas autóctonas, junto a otras traídas de regiones con tradición mudéjar como la levantina.
Open Access
Complementary strengths of water footprint and life cycle assessments in analyzing global freshwater appropriation and its local impacts: recommendations from an interdisciplinary discussion series
(Elsevier, 2025-05-01) Berger, Markus; Gerbens-Leenes, Winnie; Karandish, Fatemeh; Martínez Aldaya, Maite; Boulay, Anne-Marie; Hogeboom, Rick J.; Link, Andreas; Manzardo, Alessandro; Mialyk, Oleksandr; Motoshita, Masaharu; Nuñez, Montserrat; Pfister, Stephan; Rosenbaum, Ralph K.; Scherer, Laura; Su, Han; Wöhler, Lara; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
Considering globally increasing water challenges, the analysis of water use along supply chains is of great relevance and can be tackled by mainly two methodological approaches: Water Footprint Assessment (WFA) and Life Cycle Assessment (LCA). While sharing the same goal of promoting sustainable water use, both methods developed in different contexts and scientific communities. This has led to heated debates on methodological presuppositions that at times has become unconstructive. To build mutual understanding and enable a fruitful cooperation, researchers from both communities have exchanged over the course of two years. This paper summarizes the outcomes of this discussion series by providing i) a description of the development of both approaches and their ways of assessing freshwater consumption and pollution, ii) an application in a case study, and iii) an analysis of strengths and weaknesses in relation to questions decision-makers may have. Our analysis revealed that WFA's strength lies in its ability to measure freshwater appropriation, water-use efficiency, water scarcity and total pollution levels. This makes WFA particularly useful for crop selection as well as agricultural and river basin water management. With its focus on assessing impacts, LCA is strong in quantifying potential consequences of water use for humans and ecosystems. This makes it particularly useful for assessing complex supply chains and for analysing water-related impacts in combination with other environmental aspects. Rather than being in competition with each other, we emphasize the individual and complementary strengths of both approaches and their joint efforts in addressing the world's pressing water challenges.
Open Access
Construction and demolition waste in cement matrices as sinkholes of atmospheric pollution: effect of the 2022 airborne dust in the Iberian Peninsula
(Elsevier, 2023) Rubio Fernández, Virginia; Vigil de la Villa Mencía, Raquel; Frías Rojas, Moisés; García Giménez, Rosario; Moreno Juez, Jaime; De Soto García, Isabel Sonsoles; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
Open Access
Crop grey water footprints in China: the impact of pesticides on water pollution
(Elsevier, 2024) Yi, Junjie; Gerbens-Leenes, Winnie; Martínez Aldaya, Maite; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
Agricultural water pollution is a significant challenge in China, a rapidly growing economy with a large agricultural sector. The grey water footprint (WF) is a tool for evaluating freshwater pollution. It expresses pollution in volumetric units identifying the pollutant that theoretically needs most water to be diluted to accepted water quality standards. Previous agricultural grey WF studies focused on nitrogen (N) and phosphorus (P), some studies included pesticides. This study assesses grey WFs based on N, P and 1513 pesticide combinations for twelve main crops and two crop categories in 31 Chinese provinces. Grey WFs, including the pesticide component, are far larger than estimated before, dominating total agricultural WFs (green, blue, and grey). The total grey WF of Chinese agriculture (4,900 109 m3 year−1) is determined by pesticides, while grey WFs related to N and P are 450 and 1,500 109 m3 year−1, differences of a factor of eleven and three respectively. The provinces Heilongjiang, Inner Mongolia, Hebei, Henan, and Shandong are hotspots contributing 37 % to the total grey WF. A limited number of pesticides used for maize, vegetables, fruits and potato (Mancozeb a fungicide, Acetochlor a herbicide and Cypermethrin an insecticide) dominate total grey WFs, contributing 80 % to the total grey WF. Eliminating the most polluting pesticides per category and redistributing the remaining ones with a similar function but lower grey WFs reduces national water pollution from agriculture by 64 %. Only five crops, i.e. maize, potato, soybean, rice and wheat, and the two crop categories, vegetables and fruits, contribute 94 % to this reduction. Probably grey WFs could reduce even further with a second elimination and redistribution effort. This study is the first national grey WF assessment related to pesticides in agriculture. It offers valuable insights to farmers and policymakers to enhance water quality in China and beyond.
Open Access
Cubierta vegetal bajo las cepas: una alternativa al control de las malas hierbas en los viñedos
(INTIA (Tecnologías e Infraestructuras Agroalimentarias), 2023) Abad Zamora, Francisco Javier; Cibriain Sabalza, Félix; Sagüés Sarasa, Ana; Santesteban García, Gonzaga; Lezáun San Martín, Juan Antonio; Fabo Boneta, Jesús María; Virto Quecedo, Íñigo; Imbert Rodríguez, Bosco; Marín Arroyo, Remedios; Garbisu Crespo, Carlos; Ciencias; Zientziak; Agronomía, Biotecnología y Alimentación; Agronomia, Bioteknologia eta Elikadura; Institute for Multidisciplinary Research in Applied Biology - IMAB; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
En este artículo se presentan los resultados obtenidos con una cubierta vegetal de trébol sembrada bajo las cepas para competir con las malas hierbas, de manera que no sea necesario recurrir al empleo de herbicidas o laboreos intercepas.
Open Access
Decoupling of traditional burnings and grazing regimes alters plant diversity and dominant species competition in high-mountain grasslands
(Elsevier, 2021) Múgica Azpilicueta, Leire; Canals Tresserras, Rosa María; San Emeterio Garciandía, Leticia; Peralta de Andrés, Francisco Javier; Agronomia, Bioteknologia eta Elikadura; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Agronomía, Biotecnología y Alimentación; Ciencias; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Over millennia, the combination of controlled burnings and extensive grazing has maintained mosaic landscapes and preserved mountain grasslands in southern Europe. In the last century, deep socio-economic changes have led to an abandonment of traditional uses, to a general decline of the domestic herbivory and to a misuse of burning practices. This study aims to quantify how the decoupling of burning and grazing regimes affects in the long-term the structure, diversity and dynamics of high-mountain, shrub-encroached grasslands. In spring 2012, four treatments (burned-grazed, burned-ungrazed, unburned-grazed and unburned-ungrazed) were set up at three sites in the Special Area of Conservation Roncesvalles-Selva de Irati, in southwest Pyrenees. During seven years, we monitored floristic composition and the height of the native tall-grass Brachypodium rupestre in four plots at each site. In the burned plots, we surveyed the resprout of the dominant shrub Ulex gallii and the dynamics of recovering of the herbaceous vegetation. Plant communities evolved differently in grazed and ungrazed plots. Extensive grazing, despite being lower than in previous decades, maintained plant diversity and limited shrub encroachment. The total absence of grazing fostered the encroachment of U. gallii at two sites and the expansion of B. rupestre at the other site. When B. rupestre cover was >60%, the encroachment of U. gallii was reduced. This research highlights the competition that occurs between shrubs and tall-grasses in the absence of grazing, and the modulating effect exerted by the burnings and the site-specific features. Understanding local plant dynamics is the first step to design the most appropriate practices that help to preserve diversity at the landscape and the community level in high-mountain grasslands of south Europe.
Open Access
Effect of irrigation on carbonate dynamics in a calcareous soil using isotopic determinations
(Universia, 2019) De Soto García, Isabel Sonsoles; Virto Quecedo, Íñigo; Barré, Pierre; Enrique Martín, Alberto; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Ciencias
Este artículo evalúa el efecto del regadío en la dinámica de los carbonatos en suelos agrícolas. Se ha estudiado la proporción y distribución de carbonatos pedogénicos en las fracciones granulométricas de un suelo en regadío y en secano, usando la firma isotópica de C de los carbonatos. El regadío puede alterar la distribución de los carbonatos del suelo y producir una acumulación preferencial de carbonatos pedogénicos (87% al 92% con riego frente a 61% al 74% sin riego) en las fracciones más finas.
Open Access
Effect of stoniness on the hydraulic properties of a soil from an evaporation experiment using the wind and inverse estimation methods
(MDPI, 2019) Arias Fariñas, Nerea; Virto Quecedo, Íñigo; Enrique Martín, Alberto; Bescansa Miquel, Paloma; Walton, Riley; Wendroth, Ole; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Ciencias
Stony soils are distributed all over the world. The study of their characteristics has gained importance lately due to their increasing use as agricultural soils. The effect that rock fragments exert on the soil hydraulic properties is difficult to measure in situ, and is usually derived from the fine earth properties. However, the corrections used so far do not seem accurate for all types of stony soils. Our objective was to assess the adequacy of estimating the hydraulic properties of a stony soil from the fine earth ones by correcting the latter by the volume occupied by rock fragments. To do that, we first assessed the validity of different approaches for estimating the hydraulic properties of a stone-free and a stony (40% rock fragments) cylinder prepared with samples from the same silt loam soil. The functions relating to the soil hydraulic properties (-h, K-h-) were estimated by the Wind method and by inverse estimation, using data from an evaporation experiment where the soil water content and pressure head were measured at different soil depths over time. Results from the evaporation experiment were compared to those obtained by applying the equation that corrects fine earth properties by the rock fragments volume. Wind and the Inverse Estimation methods were successfully applied to estimate soil water content and hydraulic conductivity from the stony soil experiment, except for some uncertainties caused by the limited range of suction in which the experiment was conducted. The application of an equation for adjusting the soil water content at different pressure heads (allowing for defining the soil water retention curve, SWRC), and the unsaturated hydraulic conductivity (K) directly from the stone content was not satisfactory. K values obtained from the measured data were higher than those inferred by the correcting equation in the wet range, but decreased much faster with a decreasing pressure head. The use of this equation did therefore not take into account the effect that the creation of lacunar pores by the presence of rock fragments likely exerts on water flow processes. The use of such correction needs therefore to be revised and new approaches are needed for estimating the hydraulic conductivity in stony soils. In relation to SWRC, a new equation to calculate the water content of a stony soil accounting for the influence of possible lacunar pores is proposed.
Open Access
Effect of the long-term application of sewage sludge to a calcareous soil on its total and bioavailable content in trace elements, and their transfer to the crop
(MDPI, 2021-03-30) Zaragüeta, Armelle; Enrique Martín, Alberto; Virto Quecedo, Íñigo; Antón Sobejano, Rodrigo; Urmeneta Martín-Calero, Henar; Orcaray Echeverría, Luis; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Estadística, Informática y Matemáticas; Estatistika, Informatika eta Matematika
Sewage sludge (SS) can be used as an organic amendment in agricultural soils, provided they comply with the relevant legislation. This use can incorporate traces of metals into the soil, which can cause environmental or human health problems. In the study period between 1992 and 2018 (26 years), it was observed that the use of SS as an organic fertilizer significantly increased the total concentration of Zn, Cu, Cr, Ni and Hg of this study between 55.6% (Hg) and 7.0% (Ni). The concentration of Zn, Cu, Pb, Ni and Cd extracted with DTPA, also increased between 122.2% (Zn) and 11.3% (Cd). In contrast, the Mn concentrations extracted with Diethylene Triamine Pentaacetic Acid (DTPA)were 6.5% higher in the treatments without SS. These changes in the soil had an impact on the crop, which showed a significant increase in the concentration of Zn, Cu and Cr in the grain, between 15.0% (Cr) and 4.4% (Cu), and a decrease in the concentration of Mn, Cr and Ni in the barley straw when SS was added to the soil between 32.2% (Mn) and 29.6% (Ni). However, the limits established by current legislation on soil protection and food were not exceeded. This limited transfer to the crop, is likely due to the high content of carbonates and organic matter in the soil, which limit the bioavailability of most of the trace metals (TM) in the soil. As a conclusion, we observe that the use of SS as an organic amendment increased the concentration of some TM in the soil, in its bioavailable forms, and in the crop.
Open Access
Effects of innovative long-term soil and crop management on topsoil properties of a mediterranean soil based on detailed water retention curves
(European Geosciences Union, 2022) Aldaz Lusarreta, Alaitz; Giménez Díaz, Rafael; Campo-Bescós, Miguel; Arregui Odériz, Luis Miguel; Virto Quecedo, Íñigo; Agronomía, Biotecnología y Alimentación; Agronomia, Bioteknologia eta Elikadura; Ciencias; Zientziak; Ingeniería; Ingeniaritza; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Gobierno de Navarra / Nafarroako Gobernua
The effectiveness of conservation agriculture (CA) and other soil management strategies implying a reduction of tillage has been shown to be site-dependent (crop, clime and soil), and thus any new soil and crop management should be rigorously evaluated before its implementation. Moreover, farmers are normally reluctant to abandon conventional practices if this means putting their production at risk. This study evaluates an innovative soil and crop management (including no-tillage, cover crops and organic amendments) as an alternative to conventional management for rainfed cereal cropping in a calcareous soil in a semi-arid Mediterranean climatic zone of Navarra (Spain), based on the analysis of soil water retention curves (SWRCs) and soil structure. The study was carried out in a small agricultural area in the municipality of Garínoain (Navarre, Spain) devoted to rainfed cereal cropping. No other agricultural area in the whole region of Navarre exists where soil and crop management as proposed herein is practiced. Climate is temperate Mediterranean, and the dominant soil is Fluventic Haploxerept. Within the study area there is a subarea devoted to the proposed soil and crop management (OPM treatment), while there is another subarea where the soil and crop management is conventional in the zone (CM treatment). OPM includes no-tillage (18 years continuous) after conventional tillage, crop rotation, use of cover crops and occasional application of organic amendments. CM involves continuous conventional tillage (chisel plow), mineral fertilization, no cover crops and a lower diversity of crops in the rotation. Undisturbed soil samples from the topsoil and disturbed samples from the tilled layer were collected for both systems. The undisturbed samples were used to obtain the detailed SWRCs in the low suction range using a HYPROP©device. From the SWRCs, different approaches found in the literature to evaluate soil physical quality were calculated. The pore-size distribution was also estimated from the SWRCs. Disturbed samples were used in the laboratory to assess soil structure by means of an aggregate-size fractionation and to perform complementary analysis from which other indicators related to soil functioning and agricultural sustainability were obtained. The approaches evaluated did not show clear differences between treatments. However, the differences in soil quality between the two forms of management were better observed in the pore size distributions and by the analysis of the size distribution and stability of soil aggregates. There was an overabundance of macropores under CM, while the amount of mesopores (available water) and micropores were similar in both treatments. Likewise, more stable macroaggregates were observed in OPM than in CM, as well as more organic C storage, greater microbial activity, and biomass. The proposed management system is providing good results regarding soil physical quality and contributing also to the enhancement of biodiversity, as well as to the improvement in water-use efficiency. Finally, our findings suggest that the adoption of the proposed practice would not result in a loss in yields compared to conventional management.
Open Access
Effects of long-term sewage sludge addition to a calcareous soil on soil organic C fractions and soil functions
(Elsevier, 2024) Simoes da Mota, Ana Claudia; Barré, Pierre; Baudin, François; Poch, Rosa María; Bruni, Elisa; Antón Sobejano, Rodrigo; Enrique Martín, Alberto; Virto Quecedo, Íñigo; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
Soil organic matter (SOM) is a recognized carbon reservoir and paramount in soil functioning and agrosystems productivity. Different management strategies have been established to enhance SOM in arable soils, and one is the application of exogenous organic matter (EOM). Despite significant efforts in recent years, the consequences of EOM addition on increasing soil organic C (SOC) storage and stability in different pedoclimatic contexts remain incompletely understood. In this study, we evaluated the effect of long-term (28 y) sewage sludge (SS) addition to a calcareous soil supporting rainfed extensive crops in a Mediterranean sub-humid area in terms of SOC stabilization and distribution among functional fractions. To that end, we studied total SOM storage and soil fractions in a long-term experiment comparing 4 different doses of SS with mineral fertilization and no-fertilization controls. We compared the concentration, storage and distribution of C using two different fractionation methods (particulate vs. mineral-associated, defined by granulodensimetric fractionation, and active C vs. stable C defined by Rock-Eval® thermal analysis coupled to the machine learning PARTYsoc v2.0 model) on the tilled layer (0–30 cm). Three soil functioning indicators (crops yield, soil microbial biomass C and aggregate stability) were also quantified. We found that SS application, which slightly increased SOC concentration when SS was added, resulted in a net SOC stock gain only with the highest dose used (80 tons/ha), compared to mineral fertilization, suggesting that most of the C added was mineralized. An uneven response of soil fractions was however detected. The coarsest heavy physical fractions > 250 μm and 50–250 μm in size were the most enriched in their C concentration with SS addition, whereas SOC was mostly accumulated as mineral-associated C in the silt-size (2–50 μm) and the 50–250 μm fractions. Regarding thermal fractionation, SS treatments showed C gains between 57 % and 35 % in the active C pool, compared to mineral fertilization. This can be explained considering that the accumulated SOM in mineral-associated fractions corresponded to mean-residence times in the order of 20–40 years. The consequences on soil functioning indicators were not directly related to the amount of SOC stored in the soil, as the highest SOC gains corresponded to the highest dose, but not the highest yields, and some negative correlations were observed between SOC fractions and soil structural stability and microbial biomass. This can be related to some deleterious effects of excessive SS application reducing yields, the soil biological activity and soil structure, and represents an example of the need to decouple the assessment of soil health from that of SOC storage for certain soil management practices. The overall evaluation of the net consequences of long-term SS application indicated that low doses (10 tons/ha) seem a better choice, as they resulted in the highest efficiency in C incorporation, and in a slightly greater increase in SOC concentration than intermediate doses, and equal yields than mineral fertilization, but did not have the negative effects observed in soil functioning with higher doses.
Open Access
Effects of long-term sewage sludge application to a calcareous soil structure
(British Society of Soil Science, 2022) Simoes da Mota, Ana Claudia; Virto Quecedo, Íñigo; Poch, Rosa María; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Ciencias
Soil degradation is a growing challenge to global agriculture and the United Nations' Sustainable Development Goals (SDGs). This has prompted calls for less use of mineral fertilizer and greater reliance on organic fertilizers. However, we need to understand better the long-term effects of organic fertilizer usage on soil structure to guide soil management practice, as many soil functions are sensitive to pore morphology and connectivity. In this study, we characterized topsoil (0–30 cm) pore architecture in relation to soil physical properties in a long-term experiment (LTE) site where calcareous soil had received 25 years of sewage sludge application. Two dosage rates (SSa, 20 and SSe, 80 Mg ha−1) were compared to mineral fertilization treatment and a control (no fertilization) in a random factorial block design. Soil microstructure and the types of pores were characterized using micromorphological methods and image analysis, in soil thin sections. Long-term sewage sludge SSa application improved soil microstructure (crumb and sub-angular-blocky type) and increased the presence of biopores, while mineral fertilized soil showed a platy to apedal microstructure, with more elongated pores and lower faunal activity. Mineral fertilized soil had the lowest total porosity values, with differences found in the aspect ratio of pores of equivalent diameter 100–200 μm. These findings suggest a relation between the different types of fertilization and soil pore shape and network. Further exploration of these changes in soil functioning is needed for a complete assessment of the consequences of SS application.
Open Access
Evaluation of the use of a material with struvite from a wastewater treatment plant as n fertilizer in acid and basic agricultural soils
(MDPI, 2023) De Soto García, Isabel Sonsoles; Itarte Basterra, Miguel Julián; Virto Quecedo, Íñigo; López, Andrea; Gómez, Jairo; Enrique Martín, Alberto; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Struvite (MgNH4PO4 · 6H2O) has been widely studied as an emerging recycled phosphorous fertilizer despite its low solubility. However, there are few studies on the use of this mineral as an N fertilizer. This article evaluates the use of two powder struvite-containing materials from wastewater treatment as an N fertilizer in agricultural soils. A 9-week soil incubation experiment was conducted to compare the effectiveness of this mineral as an N fertilizer in two soils with different pH values (8.2 and 6.7), using two different doses and a control soil. The use of these materials has a positive effect on soil fertility, especially in acidic soils where struvite seems to be more soluble. Thus, struvite can be a potential N fertilizer for agricultural soils and can promote circular economy opportunities for the wastewater industry, especially in acid soils (concentrations of mineral N between 453–339 mg/kg were obtained in the mixtures with acid soil, and values between 408–212 mg/kg in the mixtures with the basic soil after 6 weeks of soil incubation). However, associated with this process, an increase in soil salt content was observed (EC values reaching 3.9 dS/cm in mixtures with the acid soil and 2.8 dS/cm in the mixtures with the basic soil after nine weeks of soil incubation). Therefore, this parameter should be controlled in the case of continuous applications of the amendments, especially in conditions of poor drainage and/or non-percolating water regime, since it can be a limiting factor in crop development. These processes should be studied in detail in the future considering that the N soil cycle has a significant impact on soil chemistry and fertility and on the soil microbiological community.
Open Access
Evolución de la enseñanza de las aguas subterráneas en los libros de texto y diseño de una propuesta didáctica para su enseñanza en la educación secundaria
(SGE, 2023) Pedro Rodríguez, Manuel de; De Soto García, Isabel Sonsoles; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
A pesar de que las aguas subterráneas son la mayor fuente de agua dulce líquida en la Tierra, su naturaleza abstracta ha ocasionado que sea el concepto más complicado de entender dentro del ciclo del agua, siendo uno de los principales obstáculos para conseguir una alfabetización científica de la sociedad. En este trabajo, revisamos la relevancia de las aguas subterráneas y sus amenazas en los libros de texto de la Educación Secundaria Obligatoria (ESO) debido a que son el principal recurso didáctico en las aulas y una explicación deficiente puede dificultar su aprendizaje. Asimismo, presentamos una situación de aprendizaje diseñada para 4º curso de la ESO siguiendo la nueva ley educativa, LOMLOE. Las actividades intentan fomentar la competencia científica mediante la modelización, la argumentación y las salidas de campo, con el fin de mejorar la enseñanza del funcionamiento de las aguas subterráneas y formar una ciudadanía crítica ante las amenazas que presentan: sobreexplotación y contaminación. En definitiva, pretendemos promover la alfabetización científica de la sociedad desde la educación obligatoria que ponga en valor uno de los recursos más importantes que tenemos en la Tierra.
Open Access
A fertilisation strategy combining mineral fertiliser and biosolid improves long-term yield and carbon storage in a calcareous soil
(MDPI, 2023) Zaragüeta, Armelle; Enrique Martín, Alberto; Portell Canal, Xavier; Antón Sobejano, Rodrigo; Virto Quecedo, Íñigo; Orcaray Echeverría, Luis; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
At a strategic moment for agricultural soils, which are expected to contribute to climate change mitigation through carbon storage while safely feeding a growing world population, the fertiliser strategies used will be key. In a calcareous soil with extensive rainfed agricultural use and straw removal, different fertiliser strategies were evaluated with the aim of determining their effects on crop yield, nitrogen agronomic efficiency, and the storage of organic carbon and total nitrogen in the soil. Different doses of mineral fertiliser, expressed as kg of mineral nitrogen ha−1 year−1 (0, 60, 120, 180, and 240 nitrogen fertilising units (NFUs)), were applied to plots with and without biosolid amendment. The biosolid, applied at a rate of 40 Mg ha−1 every 3 years for 18 years, complied with national and European regulations to be applied on agricultural soil. The use of combined fertilisation reduced the amount of mineral fertiliser applied between 33 and 67% and the total fertiliser units between 7 and 40%, while maintaining similar yields to the reference mineral fertilisation (180 NFUs). These results could be related to a higher nitrogen agronomic efficiency in the combined fertilisation treatments that do not exceed the total NFUs required by the crop. Combined fertilisation was also an effective fertiliser technique to store total nitrogen and organic carbon in the soil. However, compared to the reference mineral fertilisation (180 NFUs), no significant changes in the soil organic carbon were observed, probably due to the crop management method in which the straw is removed and to higher gas emissions. Our results support the need to assess the efficacy of each agricultural technique at local scales in order not to overestimate or underestimate the potential of each agricultural technique to store soil organic carbon.
Open Access
Global data on earthworm abundance, biomass, diversity and corresponding environmental properties
(Nature Research, 2021) Phillips, Helen R.P.; Bach, Elizabeth M.; Bartz, Marie L. C.; Bennett, Joanne M.; Beugnon, Rémy; Briones, Maria J.I.; Brown, George G.; Ferlian, Olga; Gongalsky, Konstantin B.; Guerra Errea, Carlos; König-Ries, Birgitta; Krebs, Julia J.; Orgiazzi, Alberto; Ramirez, Kelly S.; Russell, David J.; Schwarz, Benjamin; Wall, Diana H.; Brose, Ulrich; Decaëns, Thibaud; Lavelle, Patrick; Loreau, Michel; Mathieu, Jérôme; Mulder, Christian; Van der Putten, Wim H.; Rillig, Matthias C.; Thakur, Madhav P.; Vries, Franciska T. de; Wardle, David A.; Ammer, Christian; Ammer, Sabine; Arai, Miwa; Ayuke, Fredrick O.; Baker, Geoff H.; Baretta, Dilmar; Barkusky, Dietmar; Beauséjour, Robin; Bedano, Jose C.; Birkhofer, Klaus; Blanchart, Eric; Blossey, Bernd; Bolger, Thomas; Bradley, Robert L.; Brossard, Michel; Burtis, James C.; Capowiez, Yvan; Cavagnaro, Timothy R.; Choi, Amy; Clause, Julia; Cluzeau, Daniel; Coors, Anja; Crotty, Felicity V.; Crumsey, Jasmine M.; Dávalos, Andrea; Díaz Cosín, Darío J.; Dobson, Annise M.; Domínguez, Anahí; Duhour, Andrés Esteban; Van Eekeren, Nick; Emmerling, Christoph; Falco, Liliana B.; Fernández, Rosa; Fonte, Steven J.; Fragoso, Carlos; Franco, André L.C.; Fusilero, Abegail; Geraskina, Anna P.; Gholami, Shaieste; González, Grizelle; Gundale, Michael J.; Gutiérrez López, Mónica; Hackenberger, Branimir K.; Hackenberger, Davorka K.; Hernández, Luis M.; Hirth, Jeff R.; Hishi, Takuo; Holdsworth, Andrew R.; Holmstrup, Martin; Hopfensperger, Kristine N.; Huerta Lwanga, Esperanza; Huhta, Veikko; Hurisso, Tunsisa T.; Iannone III, Basil V.; Lordache, Madalina; Irmler, Ulrich; Ivask, Mari; Jesús, Juan B.; Johnson-Maynard, Jodi L.; Joschko, Monika; Kaneko, Nubiro; Kanianska, Radoslava; Keith, Aidan M.; Kernecker, Maria L.; Koné, Armand W.; Kooch, Yahya; Kukkonen, Sanna T.; Lalthanzara, H.; Lammel, Daniel R.; Lebedev, Iurii M.; Le Cadre, Edith; Lincoln, Noa K.; López-Hernández, Danilo; Loss, Scott R.; Marichal, Raphael; Matula, Radim; Minamiya, Yukio; Moos, Jan Hendrik; Moreno, Gerardo; Morón-Ríos, Alejandro; Motohiro, Hasegawa; Muys, Bart; Neirynck, Johan; Norgrove, Lindsey; Novo, Marta; Nuutinen, Visa; Nuzzo, Victoria; Mujeeb, Rahman P.; Pansu, Johan; Paudel, Shishir; Pérès, Guénola; Pérez-Camacho, Lorenzo; Ponge, Jean-François; Prietzel, Jörg; Rapoport, Irina B.; Rashid, Muhammad Imtiaz; Rebollo, Salvador; Rodríguez, Miguel Á.; Roth, Alexander M.; Rousseau, Guillaume X.; Rozen, Anna; Sayad, Ehsan; Van Schaik, Loes; Scharenbroch, Bryant; Schirrmann, Michael; Schmidt, Olaf; Schröder, Boris; Seeber, Julia; Shashkov, Maxim P.; Singh, Jaswinder; Smith, Sandy M.; Steinwandter, Michael; Szlavecz, Katalin; Talavera, José Antonio; Trigo, Dolores; Tsukamoto, Jiro; Uribe-López, Sheila; Valença, Anne W. de; Virto Quecedo, Íñigo; Wackett, Adrian A.; Warren, Matthew W.; Webster, Emily R.; Wehr, Nathaniel H.; Whalen, Joann K.; Wironen, Michael B.; Wolters, Volkmar; Wu, Pengfei; Zenkova, Irina V.; Zhang, Weixin; Cameron, Erin K.; Eisenhauer, Nico; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD; Ciencias
Earthworms are an important soil taxon as ecosystem engineers, providing a variety of crucial ecosystem functions and services. Little is known about their diversity and distribution at large spatial scales, despite the availability of considerable amounts of local-scale data. Earthworm diversity data, obtained from the primary literature or provided directly by authors, were collated with information on site locations, including coordinates, habitat cover, and soil properties. Datasets were required, at a minimum, to include abundance or biomass of earthworms at a site. Where possible, site-level species lists were included, as well as the abundance and biomass of individual species and ecological groups. This global dataset contains 10,840 sites, with 184 species, from 60 countries and all continents except Antarctica. The data were obtained from 182 published articles, published between 1973 and 2017, and 17 unpublished datasets. Amalgamating data into a single global database will assist researchers in investigating and answering a wide variety of pressing questions, for example, jointly assessing aboveground and belowground biodiversity distributions and drivers of biodiversity change.
Embargo
Global relevance of Argentinean rainfed crops in a climatic variability context: a water footprint assessment in Buenos Aires province
(Elsevier, 2024-06-01) Rodríguez, Corina Iris; Arrien, María Macarena; Hernán Silva, Santiago; Martínez Aldaya, Maite; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
Argentina has a relevant international role as a producer of agricultural commodities. Buenos Aires is the province with the largest cultivated area of cereals and oilseeds of the country. Rainfed crops depend exclusively on green water, meaning a comparative advantage for Buenos Aires province. The green virtual water content in the crops produced in Buenos Aires has implications for water allocation at international level. A great amount of countries depends on the Argentinean rainfed agriculture. Therefore, it is important to understand the effects of climate variations on Argentinean crop production at local level and the role of rainfed crops in regional and international trade. We analysed the temporal and territorial variations of crops green water demand in a climatic variability context and their influence on the water footprint. The green water footprint of the main crops of Buenos Aires was assessed, including soybeans, maize, sunflower, wheat and barley, in different climatic conditions: for the period 2008¿2018, which include a dry year, a humid year and an ordinary year. A dataset about the green water footprint at municipality level was provided, and the results were presented on maps for each crop and for the different climatic conditions. The relevance of green water of main crops in the world water-dependent supply chains was shown. This comprehensive green water footprint assessment provides a useful database for researchers, companies and policy makers in Argentina and beyond.
Open Access
La huella litológica de los verracos vetones: análisis geoquímicos de las esculturas zoomorfas de la meseta nordoccidental
(Ediciones Universidad de Salamanca, 2023) Manglano Valcárcel, Gregorio Ramón; Sánchez de Oro, Pablo; García Giménez, Rosario; Berrocal Rangel, Luis; De Soto García, Isabel Sonsoles; Ciencias; Zientziak; Institute on Innovation and Sustainable Development in Food Chain - ISFOOD
Arqueológicamente, el término verraco se aplica a las esculturas zoomorfas vettonas que representan toros o cerdos. El pueblo vetón ocupó un espacio impreciso entre las cuencas de los ríos Tajo y Duero en la Península Ibérica desde la Protohistoria hasta la época romana. Estas esculturas de animales, cuya utilidad aún es muy discutida, suelen tener grandes dimensiones, pero han sido desplazadas de sus ubicaciones originales. Por lo tanto, es necesario estudiar su origen para dilucidar su uso. Los análisis mineralógicos mediante microscopía óptica de polarización y espectroscopia de difracción de rayos X, así como análisis químicos mediante espectrometría de plasma acoplado inductivamente, han permitido atribuir determinados verracos a zonas de producción concretas. Coinciden con muestras de referencia tomadas en afloramientos rocosos actuales de naturaleza granítica. Con ello, se han trazado patrones de producción y distribución de estas esculturas, identificando talleres y definiendo pautas de comportamiento que ayudan a caracterizar sus funciones originales.