Open Access
Characterization and capacity dispersion of lithium-ion second-life batteries from electric vehicles
(IEEE, 2019) Braco Sola, Elisa; San Martín Biurrun, Idoia; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
Nowadays, electric vehicle batteries reutilization is considered such as a feasible alternative to recycling, as it allows to benefit from their remaining energy and to enlarge their lifetime. Stationary applications as self-consumption or isolated systems support are examples of possible second life uses for these batteries. However, the modules that compose these batteries have very heterogeneous properties, and therefore condition their performance. This paper aims to characterize and analyze the existing capacity dispersion of Nissan Leaf modules that have reached the end of their lifetime on their original application and of new modules of this Electric Vehicle, in order to establish a comparison between them.
Open Access
Integration of second-life batteries in residential microgrids and fast charging stations
(IEEE, 2022) San Martín Biurrun, Idoia; Braco Sola, Elisa; Martín Castilla, Álvaro; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Gobierno de Navarra / Nafarroako Gobernua
The potential of batteries from electric vehicles to be given a second life in stationary applications could be starting to become a reality in few years. However, the technical and economic feasibility of such second-life batteries (SLBs) is still uncertain. In this context, this paper analyses the real operation of a SLB in three scenarios: two of residential microgrids with photovoltaic generation under different strategies, and a fast charging station for electric mobility. To this end, three energy management strategies are developed, the first of which seeks to maximise the self-consumption of a typical household with photovoltaic generation; the second, in addition to maximising self-consumption, presents a night-time charge and peak shaving of the contract power from the grid; and the last refers to an urban bus charging station in which the aim is to reduce the contract power from the grid. Experimental validation of SLB during more than three weeks of operation in each of the scenarios have proved the technical viability of these batteries in the applications analysed.
Open Access
Lithium-ion second-life batteries: aging modeling and experimental validation
(IEEE, 2024-08-30) Pérez Ibarrola, Ane; San Martín Biurrun, Idoia; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, PJUPNA2023-11380; Gobierno de Navarra / Nafarroako Gobernua
Re-utilizing lithium-ion batteries from electric vehicles reduces their environmental impact. To ensure their optimal sizing and safe use, identifying the current state of the battery and predicting its remaining useful life is essential. This work analyzes the degradation mechanisms involved and proposes an aging model that utilizes a semi-empirical approach to accurately reproduce the battery's state of health within a range of 75-45 %. Calendar aging includes dependencies on temperature and state of charge while cycling aging is modeled based on depth of discharge, medium SOC, temperature, and Crate. The model is validated against experimental data from 14 LMO/LNO cells previously used in actual Nissan Leaf vehicles and an RMSE bellow 2.5 % is achieved in every case.
Open Access
Static and dynamic characterization of a supercapacitor
(2014) Berrueta Irigoyen, Alberto; San Martín Biurrun, Idoia; Ursúa Rubio, Alfredo; Sanchis Gúrpide, Pablo; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa
Supercapacitors (SCs) have recently received a major boost as a result of the development of multiple applications, such as the electric vehicle and electric microgrids. Storage systems consisting of SCs combined with batteries or fuel cells have been proposed in multiple applications. Since SCs store energy as an electric field, they are able to efficiently manage high power and high frequency charge‐discharge cycles. This ability to handle high power in a wide frequency range grants them a wide advantage against other energy‐storage technologies. A static and dynamic characterization of the Maxwell SC BMOD0083 has been accomplished in this study.
Open Access
Incremental capacity analysis of lithium-ion second-life batteries from electric vehicles under cycling ageing
(IEEE, 2021) Braco Sola, Elisa; San Martín Biurrun, Idoia; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa; Gobierno de Navarra / Nafarroako Gobernua
Nowadays, the reuse of batteries from electric vehicles is considered a promising solution to benefit from their remaining energy and extend their lifespan. Yet, the economic viability of these second-life batteries is still uncertain, and the optimization of testing at their reconfiguration stage and during their lifetime is the key to ensure their success. This paper aims to assess Incremental Capacity Analysis technique in Nissan Leaf modules during their second-life use, in order to evaluate both its potential as an State of Health estimator and as a tool to identify underlying degradation mechanisms. Despite the different internal state and ageing rates observed between the tested modules, ICA is found to be consistent at similar SOH levels. The influence of ageing, current and temperature on ICA is evaluated through an accelerated cycling test. Results show that ICA is a promising alternative to estimate SOH during second life even at currents up to C/2 and testing temperatures of 45 °C. However, testing by accelerated currents and temperatures is not recommended for the identification of degradation mechanisms.
Open Access
Health indicator selection for state of health estimation of second-life lithium-ion batteries under extended ageing
(Elsevier, 2022) Braco Sola, Elisa; San Martín Biurrun, Idoia; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Stroe, Daniel-Ioan; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Nowadays, the economic viability of second-life (SL) Li-ion batteries from electric vehicles is still uncertain. Degradation assessment optimization is key to reduce costs in SL market not only at the repurposing stage, but also during SL lifetime. As an indicator of the ageing condition of the batteries, state of health (SOH) is currently a major research topic, and its estimation has emerged as an alternative to traditional characterization tests. In an initial stage, all SOH estimation methods require the extraction of health indicators (HIs), which influence algorithm complexity and on-board implementation. Nevertheless, a literature gap has been identified in the assessment of HIs for reused Li-ion batteries. This contribution targets this issue by analysing 58 HIs obtained from incremental capacity analysis, partial charging, constant current and constant voltage stage, and internal resistance. Six Nissan Leaf SL modules were aged under extended cycling testing, covering a SOH range from 71.2 % to 24.4 %. Results show that the best HI at the repurposing stage was obtained through incremental capacity analysis, with 0.2 % of RMSE. During all SL use, partial charge is found to be the best method, with less than 2.0 % of RMSE. SOH is also estimated using the best HI and different algorithms. Linear regression is found to overcome more complex options with similar estimation accuracy and significantly lower computation times. Hence, the importance of analysing and selecting a good SL HI is highlighted, given that this made it possible to obtain accurate SOH estimation results with a simple algorithm.
Open Access
Initiative to increment the number of women in STEM degrees: women, science and technology chair of the Public University of Navarre
(IEEE, 2020) Aranguren Garacochea, Patricia; San Martín Biurrun, Idoia; Catalán Ros, Leyre; Martínez Ramírez, Alicia; Jurío Munárriz, Aránzazu; Díaz Lucas, Silvia; Pérez Artieda, Miren Gurutze; Gómez Fernández, Marisol; Barrenechea Tartas, Edurne; Estadística, Informática y Matemáticas; Ingeniería; Ingeniería Eléctrica, Electrónica y de Comunicación; Estatistika, Informatika eta Matematika; Ingeniaritza; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The Public University of Navarre joined with Navarre Government has created the Women, Science and Technology Chair. This chair arises due to the plummeting tendency of the percentage of women in STEM degrees with the aim of reversing this trend. The programme of activities is defined throughout this contribution by six activities: a Theatre Play, a Poster Award on Final Degree/Masters Project, The 1st Week of Women, Science and Technology, the Promotion of Technical Degrees in schools and high-schools, a Workshop about Gender Stereotypes and the Fostering of Women among Science and Environment. Each activity gained great success and the preset goals were highly accomplished, especially, the 1st Week of Women, Science and Technology activity. The latter achieved a great success both in participation and in repercussion, contributing to visualize the role of women in science and technology.
Open Access
Hydrogen-based energy storage for a distributed generation system
(Spanish Hydrogen Association, 2016) San Martín Biurrun, Idoia; Berrueta Irigoyen, Alberto; Ursúa Rubio, Alfredo; Sanchis Gúrpide, Pablo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC
One of the most typical distributed generation systems are electrical microgrid, which consist on small electrical grids, generally connected to the main grid, with a decentralized management structure. Electrical microgrids allow higher renewable energy integration in the grid, achieving a cost decrease and improving the grid quality [1]. These mi- crogrids incorporate renewable generation systems and energy consumers. Moreover, they have storage systems to balance generation and consumption as well as the exchanged power with the main grid. Traditionally, lead-acid batter- ies have been used in microgrids. However, these batteries have some drawbacks, being the most important its poor performance in partial state of charge, which is critical for a microgrid. A suitable option for the storage system is hy- drogen technology. These systems have high energy density, which makes the storage system able to assume seasonal variability of renewable resources. This paper proposes a sizing methodology for storage systems based on hydrogen for grid-tied electrical microgrids. This methodology optimizes the relationship between the storage system size and the consumption of grid power.
Open Access
On the requirements of the power converter for second-life lithium-ion batteries
(IEEE, 2019) Berrueta Irigoyen, Alberto; San Martín Biurrun, Idoia; Pascual Miqueleiz, Julio María; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
The use of lithium-ion batteries is increasing year after year, especially in the automotive sector. Given the high requirements of electric vehicles, their energy storage systems are discarded when they still have around 70% of its initial capacity. These discarded batteries are being studied as a low-price option for stationary systems, mostly related to renewable energy generation, with lower battery requirements. However, the increasing dispersion of cell capacity detailed in this contribution limits the use of second-life cells if regular battery management systems and power converters. We present in this contribution an experimental comparison of the capacity dispersion between fresh and second-life cells, and detail the relationship between the capacity dispersion and the required BMS functionality. Furthermore, we include the ageing phenomena in the analysis by means of experimental ageing results, given that the capacity dispersion is enlarged as the battery ages. After this, we use this data to quantify advantages and disadvantages of a combined BMS and power converter, based on a multilevel topology, compared to a conventional BMS. The most relevant result, when a 55-cell battery is analysed, is a 65% increase in capacity during its whole second life if the BMS and power converter are combined by means of a multilevel topology. The increased level of complexity required by the combined BMS-power converter architecture is analysed in this contribution, providing a convenient tool for the selection of the most suitable option for each application.
Open Access
Modelling of PEM fuel cell performance: steady-state and dynamic experimental validation
(MDPI, 2014) San Martín Biurrun, Idoia; Ursúa Rubio, Alfredo; Sanchis Gúrpide, Pablo; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Gobierno de Navarra / Nafarroako Gobernua
This paper reports on the modelling of a commercial 1.2 kW proton exchange membrane fuel cell (PEMFC), based on interrelated electrical and thermal models. The electrical model proposed is based on the integration of the thermodynamic and electrochemical phenomena taking place in the FC whilst the thermal model is established from the FC thermal energy balance. The combination of both models makes it possible to predict the FC voltage, based on the current demanded and the ambient temperature. Furthermore, an experimental characterization is conducted and the parameters for the models associated with the FC electrical and thermal performance are obtained. The models are implemented in Matlab Simulink and validated in a number of operating environments, for steady-state and dynamic modes alike. In turn, the FC models are validated in an actual microgrid operating environment, through the series connection of 4 PEMFC. The simulations of the models precisely and accurately reproduce the FC electrical and thermal performance.