Embargo
Desarrollo de sensores basados en el efecto de magnetoimpedancia gigante empleando materiales magnéticos amorfos obtenidos mediante técnicas de enfriamiento ultrarrápido
(2018) Beato López, Juan Jesús; Gómez Polo, Cristina; Pérez de Landazábal Berganzo, José Ignacio; Ciencias; Zientziak
El presente trabajo tiene un claro carácter práctico y aplicado. El principal objetivo es el desarrollo de sensores basados en el efecto de magnetoimpedancia gigante (o efecto GMI) empleando materiales magnéticos amorfos obtenidos mediante técnicas de enfriamiento ultrarrápido, para su aplicación en ámbitos tecnológicos de interés. La elección de este efecto como principio de operación de los sensores se fundamenta en la necesidad de desarrollar dispositivos que muestren una alta sensibilidad, rapidez en el tiempo de respuesta, bajo consumo y bajo coste. El efecto GMI se basa en las grandes variaciones de impedancia, tanto en su parte real como imaginaria, de un conductor ferromagnético blando al pasar una corriente eléctrica de alta frecuencia, tras la aplicación de un campo magnético estático externo. Dichos cambios son debidos a la modificación de la profundidad de penetración de la corriente eléctrica, como consecuencia de la variación de la permeabilidad magnética de la muestra. No obstante, el campo magnético no es el único parámetro capaz de modificar la impedancia de la muestra. Entre otros, las tensiones mecánicas aplicadas a la muestra son capaces de producir modificaciones cuantificables de la impedancia, fenómeno conocido como efecto Giant Stress Impedance, GSI. Los sensores diseñados se basarán en las variaciones de impedancia experimentadas bajo el efecto de ambos parámetros. En este trabajo se han desarrollado los siguientes sensores: sensor magnetoelástico (sensor μDiaS-ME); sensor de posición no contacto (sensor μDiaS-NC); sensor para la detección y cuantificación de nanopartículas magnéticas (Sensor NanoMagS)
Open Access
A lock-in amplifier for magnetic nanoparticle detection using GMI sensors
(IEEE, 2024-09-30) Algueta-Miguel, Jose M.; Beato López, Juan Jesús; López Martín, Antonio; Gómez Polo, Cristina; Ciencias; Zientziak; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC
A digital lock-in amplifier (LIA) for contactless magnetic nanoparticle (MNP) detection using giant magnetoimpedance (GMI) sensors is presented. The proposed approach is based on the simultaneous detection of the second harmonic amplitude and phase. A Xilinx Artix-7 field-programmable gate array (FPGA) has been employed for efficiently implementing the phase-sensitive detection (PSD) and the subsequent digital processing. The analog GMI sensor interface has been designed for minimizing the dependence of the excitation current on the GMI sensor impedance, also enhancing the rejection of the parasitic second-order distortion produced by the setup. A subsampling process of the analog outputs has been applied, both increasing the effective resolution of the analog-to-digital converter (ADC) and facilitating signal recovery. The proposed system improves the MNP detection capability reported in previous works using the second harmonic amplitude. Moreover, a characterization of the phase response, which had not been previously studied in the literature, is also provided.
Open Access
Study of optical fiber sensors for cryogenic temperature measurements
(MDPI, 2017) Miguel Soto, Verónica de; Leandro González, Daniel; López Aldaba, Aitor; Beato López, Juan Jesús; Pérez de Landazábal Berganzo, José Ignacio; Auguste, Jean-Louis; Jamier, Raphael; Roy, Philippe; López-Amo Sáinz, Manuel; Ingeniaritza Elektrikoa eta Elektronikoa; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica; Física; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In this work, the performance of five different fiber optic sensors at cryogenic temperatures has been analyzed. A photonic crystal fiber Fabry-Pérot interferometer, two Sagnac interferometers, a commercial fiber Bragg grating (FBG), and a -phase shifted fiber Bragg grating interrogated in In this work, the performance of five different fiber optic sensors at cryogenic temperatures has been analyzed. A photonic crystal fiber Fabry-Pérot interferometer, two Sagnac interferometers, a commercial fiber Bragg grating (FBG), and a π-phase shifted fiber Bragg grating interrogated in a random distributed feedback fiber laser have been studied. Their sensitivities and resolutions as sensors for cryogenic temperatures have been compared regarding their advantages and disadvantages. Additionally, the results have been compared with the given by a commercial optical backscatter reflectometer that allowed for distributed temperature measurements of a single mode fiber.
Open Access
Tailoring the structural and magnetic properties of Co-Zn nanosized ferrites for hyperthermia applications
(Elsevier, 2018) Gómez Polo, Cristina; Recarte Callado, Vicente; Cervera Gabalda, Laura María; Beato López, Juan Jesús; López García, Javier; Rodríguez Velamazán, José Alberto; Ugarte Martínez, María Dolores; Mendonça, E. C.; Duque, J. G. S.; Zientziak; Estatistika, Informatika eta Matematika; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias; Estadística, Informática y Matemáticas; Gobierno de Navarra / Nafarroako Gobernua
A comparative study of the magnetic properties (magnetic moment, magnetocrystalline anisotropy) and hyperthermia response in Co-Zn spinel nanoparticles is presented. The CoxZn1-xFe2O4 nanoparticles (x = 1, 0.5, 0.4, 0.3, 0.2 and 0.1) were synthesized by co-precipitated method and the morphology and mean crystallite size (around 10 nm) of the nanoparticles were analysed by TEM Microscopy. Regarding the magnetic characterization (SQUID magnetometry), Co-Zn nanoparticles display at room temperature anhysteretic magnetization curves, characteristic of the superparamagnetic behavior. A decrease in the blocking temperature, T-B, with Zn content is experimentally detected that can be ascribed to the reduction in the mean nanoparticle size as x decreases. Furthermore, the reduction in the magnetocrystalline anisotropy with Zn inclusion is confirmed through the analysis of TB versus the mean volume of the nanoparticles and the law of approach to saturation. Maximum magnetization is achieved for x = 0.5 as a result of the cation distribution between octahedral and tetrahedral spinel sites, analysed by neutron diffraction studies. The occurrence of a canted spin arrangement (Yafet-Kittel angle) is introduced to properly fit the magnetic spinel structures. Finally, the heating capacity of these spinel ferrites is analyzed under ac magnetic field (magnetic hyperthermia). Maximum SAR (Specific Absorption Rate) values are achieved for x = 0.5 that should be correlated to the maximum magnetic moment of this composition.
Open Access
Contactless magnetic nanoparticle detection platform based on non-linear GMI effect
(Elsevier, 2021) Beato López, Juan Jesús; Algueta-Miguel, Jose M.; Gómez Polo, Cristina; Zientziak; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Ciencias; Ingeniería Eléctrica, Electrónica y de Comunicación
A detection platform based on non-linear Giant Magnetoimpedance Effect was analyzed for the design of a contactless and low-cost detector of magnetic nanoparticles. The sensor consists of two soft magnetic amorphous wires (Co66Fe2Si13B15Cr4, 1.5 cm in length) placed in parallel and connected electrically in series. Initially, a simple voltage divider was employed to characterize the variations of the first, V1fand second harmonic, V2f, voltages. Their response was analyzed under the effect of the remnant magnetic field generated by different amounts of Fe3O4 nanoparticles (mean diameter 140 nm) as a function of an external magnetic field, H. Due to the larger relative variations showed by V2f, the second harmonic was chosen for the final prototype development. An electronic interface was designed for both current excitation and V2f detection. The designed detection platform, characterized by high detection sensitivity, low-cost, portable, and reusable features, can be employed to efficiently detect magnetic nanoparticles.
Open Access
Thrust actuator with passive restoration force for wide gap magnetic bearings
(Elsevier, 2019) Royo Silvestre, Isaac; Beato López, Juan Jesús; Castellano Aldave, Jesús Carlos; Gómez Polo, Cristina; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias
Active thrust magnetic bearings provide an axial force to balance the moving parts of machines. However, most devices produce null or unbalancing passive forces. Furthermore, reported designs usually feature very small axial and radial gaps. This paper presents a thrust actuator for wide axial gaps that produces both passive and active restoring axial forces. It features a long biconical rotor and a stator housing a single winding and two permanent magnets. Simulations are done using finite-element-analysis (FEA) and compared to magnetic circuit analysis and experimental results from a prototype with a diameter of 48 mm and 20 mm axial displacement.
Open Access
Magnetically activated 3D printable polylactic acid/polycaprolactone/magnetite composites for magnetic induction heating generation
(Springer, 2023) Galarreta Rodríguez, Itziar; López Ortega, Alberto; Garayo Urabayen, Eneko; Beato López, Juan Jesús; La Roca, Paulo Matías; Sánchez-Alarcos Gómez, Vicente; Recarte Callado, Vicente; Gómez Polo, Cristina; Pérez de Landazábal Berganzo, José Ignacio; Ciencias; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Additive manufacturing technology has attracted the attention of industrial and technological sectors due to the versatility of the design and the easy manufacture of structural and functional elements based on composite materials. The embedding of magnetic nanoparticles in the polymeric matrix enables the development of an easy manufacturing process of low-cost magnetically active novel polymeric composites. In this work, we report a series of magnetic composites prepared by solution casting method combining 5 to 60 wt.% of 140 ± 50 nm commercial Fe3O4 nanoparticles, with a semi-crystalline, biocompatible, and biodegradable polymeric blend made of polylactic acid (PLA) and polycaprolactone (PCL). The composites were extruded, obtaining 1.5 ± 0.2 mm diameter continuous and flexible filaments for fused deposition modelling 3D printing. The chemical, magnetic, and calorimetric properties of the obtained filaments were investigated by differential scanning calorimetry, thermogravimetric analysis, magnetometry, and scanning electron microscopy. Furthermore, taking advantage of the magnetic character of the filaments, their capability to generate heat under the application of low-frequency alternating magnetic fields (magnetic induction heating) was analyzed. The obtained results expose the versatility of these easy manufacturing and low-cost filaments, where selecting a desired composition, the heating capacity can be properly adjusted for those applications where magnetic induction plays a key role (i.e., magnetic hyperthermia, drug release, heterogeneous catalysis, water electrolysis, gas capture, or materials synthesis).
Open Access
Magnetocaloric effect enhancement driven by intrinsic defects in a Ni45Co5Mn35Sn15 alloy
(Elsevier, 2019) Sánchez-Alarcos Gómez, Vicente; López García, Javier; Unzueta, Iraultza; Pérez de Landazábal Berganzo, José Ignacio; Recarte Callado, Vicente; Beato López, Juan Jesús; García, José Ángel; Plazaola, Fernando; Rodríguez Velamazán, José Alberto; Fisika; Institute for Advanced Materials and Mathematics - INAMAT2; Física
The influence of mechanically-induced defects on the magnetostructural properties is analyzed in a Ni-Co-Mn-Sn alloy subjected to soft milling and subsequent annealing treatments. It is found that, opposite to what occurs in Ni-Mn-Sn ternary alloys, the annealing treatment affects the magnetic properties in a different way in martensite and in austenite. In particular, the saturation magnetization significantly increases in martensite after annealing whereas just a very slight variation is observed in austenite. This leads to the interesting fact that the presence of microstructural defects, far for worsening, makes the magnetocaloric effect to be higher in the as-milled state than after annealing. This behavior is explained as the result of the combination of the effect of defects on the Mn-Mn distance, the effect of Co on the magnetic exchange coupling between Mn atoms, and the effect of defects on the vibrational entropy change at the martensitic transformation.
Open Access
Optimized pattern design of a light guide using 2D ray-tracing simulation
(SPIE, 2023) Medrano Gurrea, Mario; Jiménez Martínez, Unai; Tainta Ausejo, Santiago; Erro Betrán, María José; Arnedo Gil, Israel; Beato López, Juan Jesús; Izura, J.; Zabala, Silvia; Institute of Smart Cities - ISC
We propose the use of a simplified model for the analysis of the scattering elements used in edge-lit systems. By modelling their behaviour as lambertian light sources whose properties depend on the size and geometry of the scatterer and LGP, it is possible to simulate the illuminance map of the edge-lit structure using only 2D ray-traced simulation. This reduces the computational complexity in the optimisation process used to calculate the scatterers distribution to achieve maximum uniformity in light extraction. The results obtained by comparison between the proposed algorithm and a commercial software demonstrate the validity of the proposal.
Open Access
Glutathione-magnetite nanoparticles: synthesis and physical characterization for application as MRI contrast agent
(Springer, 2020) Beato López, Juan Jesús; Domínguez, M.; Ramírez del Solar, M.; Litrán, R.; Zientziak; Institute for Advanced Materials and Mathematics - INAMAT2; Ciencias
In this work a one-pot synthesis of water soluble glutathione capped magnetite nanoparticles is reported. The magnetic characterization of the samples shows the expected superparamagnetic behavior, but a wide range of blocking temperatures is found, since the size and interparticle interactions are very sensitive to preparation conditions. These properties are correlated with the glutathione-iron ratio and oxidant dose, in order to optimize the aqueous colloidal stability and magnetic properties of the superparamagnetic iron oxide nanoparticles for Magnetic Resonance Imaging applications. The efficiency of the glutathione coated nanoparticles as contrast agent is then evaluated by means of the determination of the relaxation times T1 and T2 in H-1 Nuclear Magnetic Resonance experiments. Moreover, the influence of the thickness of the glutathione capping layer on the colloidal stability and, thus, on relaxation times has been studied. Finally, the relaxitivity of the sample that shows the best performance has been determined.