Open Access
Computational study of geothermal thermoelectric generators with phase change heat exchangers
(Elsevier, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
The use of thermoelectric generators with phase change heat exchangers has demonstrated to be an interesting and environmentally friendly alternative to enhanced geothermal systems (EGS) in shallow hot dry rock fields (HDR), since rock fracture is avoided. The present paper studies the possibilities of the former proposal in a real location: Timanfaya National Park (Canary Islands, Spain), one of the greatest shallow HDR fields in the world, with 5000 m2 of characterized geothermal anomalies presenting temperatures up to 500 °C at only 2 m deep. For this purpose, a computational model based on the thermal-electrical analogy has been developed and validated thanks to a real prototype, leading to a relative error of less than 8%. Based on this model, two prototypes have been designed and studied for two different areas within the park, varying the size of the heat exchangers and the number of thermoelectric modules installed. As a result, the potential of the solution is demonstrated, leading to an annual electricity generation of 681.53 MWh thanks to the scalability of thermoelectric generators. This generation is obtained without moving parts nor auxiliary consumption, thus increasing the robustness of the device and removing maintenance requirements.
Open Access
The importance of the assembly in thermoelectric generators
(IntechOpen, 2018) Araiz Vega, Miguel; Catalán Ros, Leyre; Herrero Mola, Óscar; Pérez Artieda, Miren Gurutze; Rodríguez García, Antonio; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Generally, in the optimization of thermoelectric generators, only the heat exchangers or the thermoelectric modules themselves are taken into account. However, the assembly of the generator as a whole is of vital importance since a bad contact or a thermal bridge can waste the performance of an optimal generator. In this sense, the present chapter analyzes experimentally the use of different interface materials to reduce the thermal contact resistance between the modules and the heat exchangers, the influence of the pressure distribution in the assembly as well as the effect of different insulating materials in order to reduce the thermal bridge between the exchangers. Thus, it has been demonstrated that a good assembly requires the implementation of thermal interface materials to ensure the microscopic contact between the heat exchangers and the modules, besides a uniform clamping pressure. Nevertheless, since this is normally achieved with screws, they represent a source of thermal bridges in conjunction with the small distance between the exchangers. In order to reduce heat losses due to thermal bridges, which can represent up to one-third of the incoming heat, an increment of the distance between the exchangers and the use of an insulator is recommended.
Open Access
New opportunities for electricity generation in shallow hot dry rock fields: a study of thermoelectric generators with different heat exchangers
(Elsevier, 2019) Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Institute of Smart Cities - ISC
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In order to leverage shallow hot dry rock (HDR) fields, the present paper proposes an alternative to enhanced geothermal systems (EGS): thermoelectric generators. Based on the conditions of Timanfaya National Park, a prototype has been built to experimentally analyze the feasibility of the proposed solution. The prototype is composed by a two phase closed thermosyphon (TPCT) as hot side heat exchanger, two thermoelectric modules, and it considers different cold side heat exchangers: fin dissipators assisted by a fan and loop thermosyphons, both with various geometries. Experiments have demonstrated that loop thermosyphons represent the best alternative due to their low thermal resistance and, especially, due to their lack of auxiliary consumption, leading to a maximum net power generation of 3.29 W per module with a temperature difference of 180 °C (200 °C in the hot side and 20 °C as ambient temperature), 54% more than with fin dissipators. Hence, there exists a new opportunity for electricity generation in shallow hot dry rock fields: thermoelectric generators with biphasic thermosyphons as heat exchangers, a patented and robust solution.
Open Access
Thermoelectric generator for high temperature geothermal anomalies: experimental development and field operation
(Elsevier, 2023) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In the current climate and energy context, it is important to develop technologies that permit increase the use of renewable sources such as geothermal energy. Enhancing the use of this renewable source is particularly important in some places, due to its availability and the enormous dependence on fossil fuels, as is the case of the Canary Islands. This work proposes the use of thermoelectric generators with heat exchangers working by phase change to transform the heat from the shallow high temperature geothermal anomalies on the island of Lanzarote directly into electricity, since the use of conventional geothermal power plants would not be possible because they would damage the protected environment. To bring this proposal to reality, this work has succeeded in developing and field-installing a geothermal thermoelectric generator that operates without moving parts thanks to its phase-change heat exchangers. This robust generator do not require maintenance nor auxiliary consumption, and produces a minimal environmental impact, it is noiseless, and the use of water as working fluid makes it completely harmless. The developed device consists of a thermosyphon as hot side heat exchanger, thermoelectric modules and cold side heat exchangers also based in phase change. Tests were carried out in the laboratory at various heat source temperatures and varying the number of thermoelectric modules. It was determined that installing more modules decreases the efficiency per module (from 4.83% with 4 modules to 4.59% with 8 modules at a temperature difference between sources of 235 °C), but for the number of modules tested the total power increases, so the field installation was carried out with 8 modules. After the good results in the laboratory, it was satisfactorily installed at Timanfaya National Park (Lanzarote, Spain) in a borehole with gases at 465 °C. This generator presents a maximum output power of 36 W (4.5 W per module), and is generating 286.94 kWh per year, demonstrating the great potential of the developed thermoelectric generators to build a larger-scale renewable installation.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(Elsevier, 2022) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Rodríguez García, Antonio; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Nowadays, geothermal energy in shallow hot dry rock fields is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. However, the efficiency of a thermoelectric generator depends highly on the heat exchangers. In this work, a novel geothermal thermoelectric generator is experimentally developed, characterizing different configurations of biphasic heat exchangers to obtain low thermal resistances that allow the maximum efficiency in the thermoelectric modules. As a result, robust and passive heat exchangers were obtained with thermal resistances of 0.07 K/W and 0.4 K/W in the hot and cold sides, respectively. The geothermal thermoelectric generator was built with the most effective heat exchangers and was experimented under different temperature and convection conditions, generating 36 W (17 W by a prototype with 10 modules and 19 W by a prototype with 6 modules) for a temperature difference of 160 °C between the heat source and the environment. Furthermore, the experimental development showed that it is possible to increase electricity generation with a more compact generator, since a decrease in the number of modules from 10 to 6 increases the efficiency from 3.72% to 4.06%. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Corrosion behavior in volcanic soils: in search of candidate materials for thermoelectric devices
(MDPI, 2021-12-21) Berlanga Labari, Carlos; Catalán Ros, Leyre; Palacio, José F.; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Institute for Advanced Materials and Mathematics - INAMAT2
Thermoelectric generators have emerged as an excellent solution for the energy supply of volcanic monitoring stations due to their compactness and continuous power generation. Nevertheless, in order to become a completely viable solution, it is necessary to ensure that their materials are able to resist in the acidic environment characteristic of volcanoes. Hence, the main objective of this work is to study the resistance to corrosion of six different metallic materials that are candidates for use in the heat exchangers. For this purpose, the metal probes have been buried for one year in the soil of the Teide volcano (Spain) and their corrosion behavior has been evaluated by using different techniques (OM, SEM, and XRD). The results have shown excessive corrosion damage to the copper, brass, and galvanized steel tubes. After evaluating the corrosion behavior and thermoelectric performance, AISI 304 and AISI 316 stainless steels are proposed for use as heat exchangers in thermoelectric devices in volcanic environments.
Open Access
Role of student associations in the acquisition of competences in university engineering programs
(IEEE, 2023) Samanes Pascual, Javier; Parra Laita, Íñigo de la; Berrueta Irigoyen, Alberto; Rosado Galparsoro, Leyre; Soto Cabria, Adrián; Elizondo Martínez, David; Catalán Ros, Leyre; Sanchis Gúrpide, Pablo; Institute of Smart Cities - ISC
Students in the STEM field (Science, Technology, Engineering and Mathematics), do not only require deep technical knowledge, but a complete set of global skills related to management, teamwork, lifelong learning, personal development, communications skills or proactiveness, abilities often referred as soft-skills. Student-led organizations, and specifically, university student associations, are one of the best alternatives to promote the acquisition of soft-skills in STEM high education fields. These skills are competences already included in official university programs that can hardly be addressed or acquired from traditional university education. This article studies how student enrollment in student led organizations (SLOs), with an active participation on their organization and activities, allows engineering students to achieve a better development of these soft skills. As case study, a medium size university, with 9000-students and eleven SLOs, six of them focused on STEM related fields, is used in this paper. A survey is conducted among the university community to identify their degree of participation in SLOs, and to test whether participation in these initiatives increases students' self-perception of their soft skill acquisition during their university studies. This survey shows how students of engineering programs, with a high degree of involvement in SLOs, demonstrated greater confidence in their soft skills at the end of their university years.
Open Access
Thermoelectric heat recovery in a real industry: from laboratory optimization to reality
(Elsevier, 2021) Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Catalán Ros, Leyre; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2018-000101
Thermoelectricity, in the form of thermoelectric generators, holds a great potential in waste heat recovery, this potential has been studied and proved in several laboratory and theoretical works. By the means of a thermoelectric generator, part of the energy that normally is wasted in a manufacturing process, can be transformed into electricity, however, implementing this technology in real industries still remains a challenge and on-site tests need to be performed in order to prove the real capabilities of this technology. In this work, a computational model to simulate the behaviour of a thermoelectric generator that harvest waste heat from hot fumes is developed. Using the computational model an optimal configuration for a thermoelectric generator is obtained, also an experimental study of the performance of different heat pipes working as cold side heat exchangers is carried out in order to optimize the performance of the whole thermoelectric generator, thermal resistances of under 0,25 K/W are obtained. The optimized configuration of the thermoelectric generator has been built, installed and tested under real conditions at a rockwool manufacturing plant and experimental data has been obtained during the 30 days field test period. Results show that 4.6 W of average electrical power are produced during the testing period with an efficiency of 2.38%. Moreover, the computational model is validated using this experimental data. Furthermore, the full harvesting potential of an optimized designed that takes advantage of the whole pipe is calculated using the validated computational model, resulting in 30.8 MWh of energy harvested during a sample year which could meet the demand of 8.34 Spanish average households.
Open Access
Prospects of autonomous volcanic monitoring stations: experimental investigation on thermoelectric generation from fumaroles
(MDPI, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Padilla, Germán D.; Hernández, Pedro A.; Pérez, Nemesio M.; García de la Noceda, Celestino; Albert, José F.; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 °C. Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 °C. The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 °C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.
Open Access
Thermoelectric generator with passive biphasic thermosyphon heat exchanger for waste heat recovery: design and experimentation
(MDPI, 2021) Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
One of the measures to fight against the current energy situation and reduce the energy consumption at an industrial process is to recover waste heat and transform it into electric power. Thermoelectric generators can be used for that purpose but there is a lack of experimental studies that can bring this technology closer to reality. This work presents the design, optimizations and development of two devices that are experimented and compared under the same working conditions. The hot side heat exchanger of both generators has been designed using a computational fluid dynamics software and for the cold side of the generators two technologies have been analysed: a finned dissipater that uses a fan and free convection biphasic thermosyphon. The results obtained show a maximum net generation of 6.9 W in the thermoelectric generator with the finned dissipater; and 10.6 W of power output in the generator with the biphasic thermosyphon. These results remark the importance of a proper design of the heat exchangers, trying to get low thermal resistances at both sides of the thermoelectric modules, as well as, the necessity of considering the auxiliary consumption of the equipment employed.