Open Access
Design and experimental development of thermoelectric generators for shallow geothermal anomalies of volcanic origin
(2020) Catalán Ros, Leyre; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
En el contexto energético actual, caracterizado por un incesante aumento en el consumo de energía y una gran dependencia de los combustibles fósiles, resulta imprescindible apostar por sistemas eficientes y basados en energías renovables que contribuyan a un mejor aprovechamiento de los recursos y sean respetuosos con el medio ambiente. En este sentido, la energía geotérmica destaca entre otras fuentes renovables por su carácter permanente, al no depender de las condiciones meteorológicas. Sin embargo, su contribución al sistema energético mundial es mínimo, sobre todo en generación de electricidad. Como alternativa a los ciclos que tradicionalmente se emplean para la generación eléctrica geotérmica, esta tesis doctoral propone la utilización de generadores termoeléctricos debido a sus numerosas ventajas tales como fiabilidad, durabilidad y escalabilidad. Concretamente, la tesis se centra en anomalías geotérmicas superficiales de origen volcánico para dos aplicaciones distintas: la generación eléctrica de media escala en yacimientos de roca caliente seca y el abastecimiento autónomo de estaciones de vigilancia volcánica. Dada la importancia de los intercambiadores de calor en la eficiencia total del sistema, en ambas aplicaciones se ha realizado un profundo estudio para determinar qué tipo de intercambiadores de calor son los más adecuados. En ambos casos, se ha demostrado experimentalmente que los intercambiadores de calor más propicios son aquellos basados en el cambio de fase, ya que aparte de presentar bajas esistencias térmicas, no tienen partes móviles ni requieren de equipos auxiliares, minimizando así el mantenimiento. Asimismo, también ha resultado de gran importancia el desarrollo de un modelo computacional rápido y fiable que tenga en cuenta los intercambiadores de calor, la fuente de calor y el sumidero, sin despreciar ningún efecto termoeléctrico, y considerando los contactos térmicos y eléctricos y la influencia de la temperatura en las propiedades. Este modelo, programado en base al método de las diferencias finitas, se ha convertido en una verdadera herramienta de diseño y optimización para las dos aplicaciones objeto de estudio en esta tesis doctoral, gracias a su error relativo menor al 8%. Los resultados derivados de esta tesis doctoral demuestran que la termoelectricidad puede solucionar las problemáticas de generación eléctrica en los yacimientos de roca caliente seca y en las estaciones de monitorización volcánica, dos aplicaciones inéditas de generación termoeléctrica que pueden hacer que esta tecnología se convierta por fin en una realidad en el ámbito civil.
Open Access
Study of the degradation of heat exchanger materials in the acidic environment of Teide National Park
(2019) Catalán Ros, Leyre; Pérez Artieda, Miren Gurutze; Berlanga Labari, Carlos; Garacochea Sáenz, Amaia; Rodríguez García, Antonio; Domínguez, Vidal; Montañez, Ana Carolina; Padilla, Germán D.; Pérez, Nemesio M.; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Ingeniería
Supplying power to volcanic monitoring stations constitutes a challenge due to both the access difficulties and the acidic environment associated with volcanoes. ELECTROVOLCAN project is developing thermoelectric generators that make use of the temperature of the available fumaroles to directly supply electricity to the stations in a robust, compact and reliable way. The main element of thermoelectric generators are the thermoelectric modules, based on Seebeck effect. Nonetheless, since the efficiency of these modules increases with the temperature difference between their sides, the introduction of heat exchangers becomes essential. The present study analyses the behavior of different materials used in the construction of the heat exchangers in the acidic environment of Teide National Park.
Open Access
Prospects of autonomous volcanic monitoring stations: experimental investigation on thermoelectric generation from fumaroles
(MDPI, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Padilla, Germán D.; Hernández, Pedro A.; Pérez, Nemesio M.; García de la Noceda, Celestino; Albert, José F.; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 °C. Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 °C. The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 °C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.
Open Access
Geothermal thermoelectric generator for Timanfaya National Park
(2019) Catalán Ros, Leyre; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In the case of shallow Hot Dry Rock (HDR) fields, thermoelectric generators can entail a sustainable alternative to Enhanced Geothermal Systems (EGS). The present work studies two configurations of thermoelectric generators for Timanfaya National Park (Spain), one of the most important Hot Dry Rock fields in the world, with temperatures of 500°C at only 3 meters deep. The first configuration includes biphasic thermosyphons as heat exchangers for both sides, leading to a completely passive thermoelectric generator. The second configuration uses fin dissipators as cold-side heat exchangers.
Open Access
Energía sostenible: sin malos humos
(Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, 2019) Samanes Pascual, Javier; Pascual Miqueleiz, Julio María; Berrueta Irigoyen, Alberto; Araiz Vega, Miguel; Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Arricibita de Andrés, David; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniería; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Ingeniaritza
¿Puede España ser sostenible energéticamente? Si alguna vez te has planteado esta pregunta, o quieres saber en qué gastamos la energía y de dónde podría ser obtenida, aquí encontrarás respuestas. Nuestros recursos renovables son inmensos, pero también lo es nuestro consumo. Este libro no solo se centra en analizar la situación actual y las posibilidades que las energías renovables tienen en nuestro país, sino que, presentando de forma clara los datos sobre nuestro gasto energético, permite a cada lector identificar sus mayores consumos, de tal forma que pueda considerar cómo reducirlos. Energía sostenible. Sin malos humos es la adaptación al caso español, actualizando los datos, del libro publicado hace una década por David MacKay en el Reino Unido. La sostenibilidad es hoy en día una preocupación creciente en la sociedad. Pero a menudo este interés se ve contaminado por cifras enormes que resultan muy complicadas de comprender. Además, todos hemos oído hablar en algún momento sobre pequeños gestos al alcance de nuestra mano que podrían permitir un cambio hacia un modelo sostenible. Nada más lejos de la realidad, pequeñas acciones solo permiten pequeños cambios, y el cambio de modelo energético al que nos enfrentamos requiere grandes acciones. Para deshacernos de todo este ruido, en este libro se presentan los números de forma clara y sencilla, utilizando unidades a nuestro alcance y que son comprensibles por todas las personas. Esto permite identificar de una forma mucho más personal los consumos energéticos de nuestro día a día. A lo largo de la primera parte del libro se van construyendo dos columnas: una de color rojo, que representa la agregación de consumos, y otra de color verde, que representa la capacidad de generación. Estas columnas ofrecen una comparación muy visual de la infraestructura renovable que sería necesaria para mantener nuestro ritmo de consumo energético actual. Además, utiliza números «gordos» obtenidos de la experiencia del día a día. Por ejemplo, para calcular la capacidad de generación eólica se parte de una velocidad de viento estimada a partir de la velocidad típica de un ciclista urbano. Toda esta información se encuentra en la primera parte del libro, en los capítulos del 1 al 18. Sin embargo, este libro no se centra únicamente en el análisis de la situación actual, sino que da un paso más y propone alternativas al modelo energético actual con el fin de alcanzar un modelo 100% renovable a medio plazo. Estas medidas incluyen un aumento importante en la potencia renovable instalada, un aumento en la eficiencia energética y algunos ligeros cambios en nuestro estilo de vida que permitan una reducción del consumo. Por supuesto, los tres frentes deben ser atacados al mismo tiempo. Estas propuestas se recogen en la segunda parte del libro, en los capítulos 19 a 32. Por último, este es un libro divulgativo al alcance de todas las personas, que busca transmitir toda la información de forma clara e intuitiva sin perderse en complicados cálculos. Pero si eres de los que les gustan las cuentas, al final del libro encontrarás un apartado en el que se explica de forma rigurosa muchos de los cálculos simples realizados en las primeras partes del libro. Estos apéndices técnicos forman la tercera parte del libro, son los apéndices de la A hasta la H.
Open Access
Thermoelectric generator with passive biphasic thermosyphon heat exchanger for waste heat recovery: design and experimentation
(MDPI, 2021) Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
One of the measures to fight against the current energy situation and reduce the energy consumption at an industrial process is to recover waste heat and transform it into electric power. Thermoelectric generators can be used for that purpose but there is a lack of experimental studies that can bring this technology closer to reality. This work presents the design, optimizations and development of two devices that are experimented and compared under the same working conditions. The hot side heat exchanger of both generators has been designed using a computational fluid dynamics software and for the cold side of the generators two technologies have been analysed: a finned dissipater that uses a fan and free convection biphasic thermosyphon. The results obtained show a maximum net generation of 6.9 W in the thermoelectric generator with the finned dissipater; and 10.6 W of power output in the generator with the biphasic thermosyphon. These results remark the importance of a proper design of the heat exchangers, trying to get low thermal resistances at both sides of the thermoelectric modules, as well as, the necessity of considering the auxiliary consumption of the equipment employed.
Open Access
Gamification and a low-cost laboratory equipment aimed to boost vapor compresion refrigeration learning
(OmniaScience, 2022) Aranguren Garacochea, Patricia; Sánchez, Daniel; Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Catalán Ros, Leyre; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The nowadays European educational framework boosts applying the learned theoretical concepts to real situations. Hence, practice sessions are key resources to present students direct applications of the theoretical concepts shown in class. Thus, developing new educational equipment and practice sessions oriented to bringing theoretical knowledge closer to practice should be one of the objectives of teachers. The present work describes a solution proposed by lectures of two Spanish universities looking to increase the knowledge of their engineering students. Along the years, these docents have noticed the lack of connection between the theoretical and practical knowledge among their students, drastically harming their learning procedure. Thus, in order to deepen into practical learning, a teaching methodology involving low-cost prototypes of vapor compression systems and a gamification method to help the students understand the concepts is proposed. The proposed methodology is expected to make a big positive impact on the results obtained by the students, taking into account the preliminary results reached.
Open Access
Corrosion behavior in volcanic soils: in search of candidate materials for thermoelectric devices
(MDPI, 2021-12-21) Berlanga Labari, Carlos; Catalán Ros, Leyre; Palacio, José F.; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Institute for Advanced Materials and Mathematics - INAMAT2
Thermoelectric generators have emerged as an excellent solution for the energy supply of volcanic monitoring stations due to their compactness and continuous power generation. Nevertheless, in order to become a completely viable solution, it is necessary to ensure that their materials are able to resist in the acidic environment characteristic of volcanoes. Hence, the main objective of this work is to study the resistance to corrosion of six different metallic materials that are candidates for use in the heat exchangers. For this purpose, the metal probes have been buried for one year in the soil of the Teide volcano (Spain) and their corrosion behavior has been evaluated by using different techniques (OM, SEM, and XRD). The results have shown excessive corrosion damage to the copper, brass, and galvanized steel tubes. After evaluating the corrosion behavior and thermoelectric performance, AISI 304 and AISI 316 stainless steels are proposed for use as heat exchangers in thermoelectric devices in volcanic environments.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(Elsevier, 2022) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Rodríguez García, Antonio; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Nowadays, geothermal energy in shallow hot dry rock fields is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. However, the efficiency of a thermoelectric generator depends highly on the heat exchangers. In this work, a novel geothermal thermoelectric generator is experimentally developed, characterizing different configurations of biphasic heat exchangers to obtain low thermal resistances that allow the maximum efficiency in the thermoelectric modules. As a result, robust and passive heat exchangers were obtained with thermal resistances of 0.07 K/W and 0.4 K/W in the hot and cold sides, respectively. The geothermal thermoelectric generator was built with the most effective heat exchangers and was experimented under different temperature and convection conditions, generating 36 W (17 W by a prototype with 10 modules and 19 W by a prototype with 6 modules) for a temperature difference of 160 °C between the heat source and the environment. Furthermore, the experimental development showed that it is possible to increase electricity generation with a more compact generator, since a decrease in the number of modules from 10 to 6 increases the efficiency from 3.72% to 4.06%. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Prospects of waste-heat recovery from a real industry using thermoelectric generators: economic and power output analysis
(Elsevier, 2020) Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Catalán Ros, Leyre; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2018-000101
One of the options to reduce industrial energy costs and the environmental impact is to recover the waste-heat produce in some processes. This paper proposes the use of thermoelectric generators at a stone wool manufacturing plant to transform waste-heat from a hot gas flow into useful electricity. A combination of two computational models, previously developed and validated, has been used to perform the optimization from a double point of view: power output and economic cost. The proposed thermoelectric generator includes fin dissipaters and biphasic thermosyphons as the hot and cold side heat exchangers respectively. The model takes into account the temperature drop along the duct where the gases flow, the electric consumption of the auxiliary equipment, and the configuration and geometry of the heat exchangers. After the simulations a maximum net power production of 45 838 W is achieved considering an occupancy ratio of 0.40 and a fin spacing of 10 mm. The installation cost is minimized to 10.6 €/W with an occupancy ratio of 0.24. Besides, the Levelised Cost of Electricity, LCOE, is estimated for a thermoelectric generator for the first time. It is necessary to use standar methodologies to compare this technology to others. The LCOE estimated for the proposed design is around 15 c€/kWh within the ranges of current energy sources, proving, in this way, the capabilities of waste-heat recovery from industrial processes at reasonable prices with thermoelectric generators.