Open Access
Corrosion behavior in volcanic soils: in search of candidate materials for thermoelectric devices
(MDPI, 2021-12-21) Berlanga Labari, Carlos; Catalán Ros, Leyre; Palacio, José F.; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Institute for Advanced Materials and Mathematics - INAMAT2
Thermoelectric generators have emerged as an excellent solution for the energy supply of volcanic monitoring stations due to their compactness and continuous power generation. Nevertheless, in order to become a completely viable solution, it is necessary to ensure that their materials are able to resist in the acidic environment characteristic of volcanoes. Hence, the main objective of this work is to study the resistance to corrosion of six different metallic materials that are candidates for use in the heat exchangers. For this purpose, the metal probes have been buried for one year in the soil of the Teide volcano (Spain) and their corrosion behavior has been evaluated by using different techniques (OM, SEM, and XRD). The results have shown excessive corrosion damage to the copper, brass, and galvanized steel tubes. After evaluating the corrosion behavior and thermoelectric performance, AISI 304 and AISI 316 stainless steels are proposed for use as heat exchangers in thermoelectric devices in volcanic environments.
Open Access
Prospects of waste-heat recovery from a real industry using thermoelectric generators: economic and power output analysis
(Elsevier, 2020) Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Catalán Ros, Leyre; Martínez Echeverri, Álvaro; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2018-000101
One of the options to reduce industrial energy costs and the environmental impact is to recover the waste-heat produce in some processes. This paper proposes the use of thermoelectric generators at a stone wool manufacturing plant to transform waste-heat from a hot gas flow into useful electricity. A combination of two computational models, previously developed and validated, has been used to perform the optimization from a double point of view: power output and economic cost. The proposed thermoelectric generator includes fin dissipaters and biphasic thermosyphons as the hot and cold side heat exchangers respectively. The model takes into account the temperature drop along the duct where the gases flow, the electric consumption of the auxiliary equipment, and the configuration and geometry of the heat exchangers. After the simulations a maximum net power production of 45 838 W is achieved considering an occupancy ratio of 0.40 and a fin spacing of 10 mm. The installation cost is minimized to 10.6 €/W with an occupancy ratio of 0.24. Besides, the Levelised Cost of Electricity, LCOE, is estimated for a thermoelectric generator for the first time. It is necessary to use standar methodologies to compare this technology to others. The LCOE estimated for the proposed design is around 15 c€/kWh within the ranges of current energy sources, proving, in this way, the capabilities of waste-heat recovery from industrial processes at reasonable prices with thermoelectric generators.
Open Access
Initiative to increment the number of women in STEM degrees: women, science and technology chair of the Public University of Navarre
(IEEE, 2020) Aranguren Garacochea, Patricia; San Martín Biurrun, Idoia; Catalán Ros, Leyre; Martínez Ramírez, Alicia; Jurío Munárriz, Aránzazu; Díaz Lucas, Silvia; Pérez Artieda, Miren Gurutze; Gómez Fernández, Marisol; Barrenechea Tartas, Edurne; Estadística, Informática y Matemáticas; Ingeniería; Ingeniería Eléctrica, Electrónica y de Comunicación; Estatistika, Informatika eta Matematika; Ingeniaritza; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Gobierno de Navarra / Nafarroako Gobernua; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
The Public University of Navarre joined with Navarre Government has created the Women, Science and Technology Chair. This chair arises due to the plummeting tendency of the percentage of women in STEM degrees with the aim of reversing this trend. The programme of activities is defined throughout this contribution by six activities: a Theatre Play, a Poster Award on Final Degree/Masters Project, The 1st Week of Women, Science and Technology, the Promotion of Technical Degrees in schools and high-schools, a Workshop about Gender Stereotypes and the Fostering of Women among Science and Environment. Each activity gained great success and the preset goals were highly accomplished, especially, the 1st Week of Women, Science and Technology activity. The latter achieved a great success both in participation and in repercussion, contributing to visualize the role of women in science and technology.
Open Access
Experimental evidence of the viability of thermoelectric generators to power volcanic monitoring stations
(MDPI, 2020) Catalán Ros, Leyre; Garacochea Sáenz, Amaia; Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Although there is an important lack of commercial thermoelectric applications mainly due to their low efficiency, there exist some cases in which thermoelectric generators are the best option thanks to their well-known advantages, such as reliability, lack of maintenance and scalability. In this sense, the present paper develops a novel thermoelectric application in order to supply power to volcanic monitoring stations, making them completely autonomous. These stations become indispensable in any volcano since they are able to predict eruptions. Nevertheless, they present energy supply difficulties due to the absence of power grid, the remote access, and the climatology. As a solution, this work has designed a new integral system composed of thermoelectric generators with high efficiency heat exchangers, and its associated electronics, developed thanks to Internet of Things (IoT) technologies. Thus, the heat emitted from volcanic fumaroles is transformed directly into electricity with thermoelectric generators with passive heat exchangers based on phase change, leading to a continuous generation without moving parts that powers different sensors, the information of which is emitted via LoRa. The viability of the solution has been demonstrated both at the laboratory and at a real volcano, Teide (Canary Islands, Spain), where a compact prototype has been installed in an 82 C fumarole. The results obtained during more than eight months of operation prove the robustness and durability of the developed generator, which has been in operation without maintenance and under several kinds of meteorological conditions, leading to an average generation of 0.49W and a continuous emission over more than 14 km.
Open Access
The promising combination of thermoelectric generators with IoT technologies for autonomous monitoring systems
(2019) Garacochea Sáenz, Amaia; Catalán Ros, Leyre; Casi Satrústegui, Álvaro; Gubía Villabona, Eugenio; Astrain Ulibarrena, David; Ingeniaritza; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería; Ingeniería Eléctrica, Electrónica y de Comunicación
Monitoring stations becomes essential in any volcanic system in the world but, because of their remote location, both the electricity supply and the communications represent a technological challenge. The present work studies the feasibility of an autonomous volcanic monitoring system powered by thermoelectric generators for one of the monitoring stations of the Teide National Park (Canary Island), where temperatures of 80°C at few centimeters from the surface are found. The stable generation and robustness of thermoelectricity in combination with a new communication system based on LoRa (a low power wireless technology) make this solution a good alternative.
Open Access
Thermoelectric generator with passive biphasic thermosyphon heat exchanger for waste heat recovery: design and experimentation
(MDPI, 2021) Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua
One of the measures to fight against the current energy situation and reduce the energy consumption at an industrial process is to recover waste heat and transform it into electric power. Thermoelectric generators can be used for that purpose but there is a lack of experimental studies that can bring this technology closer to reality. This work presents the design, optimizations and development of two devices that are experimented and compared under the same working conditions. The hot side heat exchanger of both generators has been designed using a computational fluid dynamics software and for the cold side of the generators two technologies have been analysed: a finned dissipater that uses a fan and free convection biphasic thermosyphon. The results obtained show a maximum net generation of 6.9 W in the thermoelectric generator with the finned dissipater; and 10.6 W of power output in the generator with the biphasic thermosyphon. These results remark the importance of a proper design of the heat exchangers, trying to get low thermal resistances at both sides of the thermoelectric modules, as well as, the necessity of considering the auxiliary consumption of the equipment employed.
Open Access
Role of student associations in the acquisition of competences in university engineering programs
(IEEE, 2023) Samanes Pascual, Javier; Parra Laita, Íñigo de la; Berrueta Irigoyen, Alberto; Rosado Galparsoro, Leyre; Soto Cabria, Adrián; Elizondo Martínez, David; Catalán Ros, Leyre; Sanchis Gúrpide, Pablo; Institute of Smart Cities - ISC
Students in the STEM field (Science, Technology, Engineering and Mathematics), do not only require deep technical knowledge, but a complete set of global skills related to management, teamwork, lifelong learning, personal development, communications skills or proactiveness, abilities often referred as soft-skills. Student-led organizations, and specifically, university student associations, are one of the best alternatives to promote the acquisition of soft-skills in STEM high education fields. These skills are competences already included in official university programs that can hardly be addressed or acquired from traditional university education. This article studies how student enrollment in student led organizations (SLOs), with an active participation on their organization and activities, allows engineering students to achieve a better development of these soft skills. As case study, a medium size university, with 9000-students and eleven SLOs, six of them focused on STEM related fields, is used in this paper. A survey is conducted among the university community to identify their degree of participation in SLOs, and to test whether participation in these initiatives increases students' self-perception of their soft skill acquisition during their university studies. This survey shows how students of engineering programs, with a high degree of involvement in SLOs, demonstrated greater confidence in their soft skills at the end of their university years.
Open Access
New opportunities for electricity generation in shallow hot dry rock fields: a study of thermoelectric generators with different heat exchangers
(Elsevier, 2019) Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Institute of Smart Cities - ISC
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In order to leverage shallow hot dry rock (HDR) fields, the present paper proposes an alternative to enhanced geothermal systems (EGS): thermoelectric generators. Based on the conditions of Timanfaya National Park, a prototype has been built to experimentally analyze the feasibility of the proposed solution. The prototype is composed by a two phase closed thermosyphon (TPCT) as hot side heat exchanger, two thermoelectric modules, and it considers different cold side heat exchangers: fin dissipators assisted by a fan and loop thermosyphons, both with various geometries. Experiments have demonstrated that loop thermosyphons represent the best alternative due to their low thermal resistance and, especially, due to their lack of auxiliary consumption, leading to a maximum net power generation of 3.29 W per module with a temperature difference of 180 °C (200 °C in the hot side and 20 °C as ambient temperature), 54% more than with fin dissipators. Hence, there exists a new opportunity for electricity generation in shallow hot dry rock fields: thermoelectric generators with biphasic thermosyphons as heat exchangers, a patented and robust solution.
Open Access
Prospects of autonomous volcanic monitoring stations: experimental investigation on thermoelectric generation from fumaroles
(MDPI, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Padilla, Germán D.; Hernández, Pedro A.; Pérez, Nemesio M.; García de la Noceda, Celestino; Albert, José F.; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 °C. Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 °C. The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 °C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(Elsevier, 2022) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Rodríguez García, Antonio; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Nowadays, geothermal energy in shallow hot dry rock fields is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. However, the efficiency of a thermoelectric generator depends highly on the heat exchangers. In this work, a novel geothermal thermoelectric generator is experimentally developed, characterizing different configurations of biphasic heat exchangers to obtain low thermal resistances that allow the maximum efficiency in the thermoelectric modules. As a result, robust and passive heat exchangers were obtained with thermal resistances of 0.07 K/W and 0.4 K/W in the hot and cold sides, respectively. The geothermal thermoelectric generator was built with the most effective heat exchangers and was experimented under different temperature and convection conditions, generating 36 W (17 W by a prototype with 10 modules and 19 W by a prototype with 6 modules) for a temperature difference of 160 °C between the heat source and the environment. Furthermore, the experimental development showed that it is possible to increase electricity generation with a more compact generator, since a decrease in the number of modules from 10 to 6 increases the efficiency from 3.72% to 4.06%. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.