Open Access
Experimental evidence of the viability of thermoelectric generators to power volcanic monitoring stations
(MDPI, 2020) Catalán Ros, Leyre; Garacochea Sáenz, Amaia; Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Although there is an important lack of commercial thermoelectric applications mainly due to their low efficiency, there exist some cases in which thermoelectric generators are the best option thanks to their well-known advantages, such as reliability, lack of maintenance and scalability. In this sense, the present paper develops a novel thermoelectric application in order to supply power to volcanic monitoring stations, making them completely autonomous. These stations become indispensable in any volcano since they are able to predict eruptions. Nevertheless, they present energy supply difficulties due to the absence of power grid, the remote access, and the climatology. As a solution, this work has designed a new integral system composed of thermoelectric generators with high efficiency heat exchangers, and its associated electronics, developed thanks to Internet of Things (IoT) technologies. Thus, the heat emitted from volcanic fumaroles is transformed directly into electricity with thermoelectric generators with passive heat exchangers based on phase change, leading to a continuous generation without moving parts that powers different sensors, the information of which is emitted via LoRa. The viability of the solution has been demonstrated both at the laboratory and at a real volcano, Teide (Canary Islands, Spain), where a compact prototype has been installed in an 82 C fumarole. The results obtained during more than eight months of operation prove the robustness and durability of the developed generator, which has been in operation without maintenance and under several kinds of meteorological conditions, leading to an average generation of 0.49W and a continuous emission over more than 14 km.
Open Access
Thermoelectric heat recovery in a real industry: from laboratory optimization to reality
(Elsevier, 2021) Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Catalán Ros, Leyre; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Gobierno de Navarra / Nafarroako Gobernua, 0011-1365-2018-000101
Thermoelectricity, in the form of thermoelectric generators, holds a great potential in waste heat recovery, this potential has been studied and proved in several laboratory and theoretical works. By the means of a thermoelectric generator, part of the energy that normally is wasted in a manufacturing process, can be transformed into electricity, however, implementing this technology in real industries still remains a challenge and on-site tests need to be performed in order to prove the real capabilities of this technology. In this work, a computational model to simulate the behaviour of a thermoelectric generator that harvest waste heat from hot fumes is developed. Using the computational model an optimal configuration for a thermoelectric generator is obtained, also an experimental study of the performance of different heat pipes working as cold side heat exchangers is carried out in order to optimize the performance of the whole thermoelectric generator, thermal resistances of under 0,25 K/W are obtained. The optimized configuration of the thermoelectric generator has been built, installed and tested under real conditions at a rockwool manufacturing plant and experimental data has been obtained during the 30 days field test period. Results show that 4.6 W of average electrical power are produced during the testing period with an efficiency of 2.38%. Moreover, the computational model is validated using this experimental data. Furthermore, the full harvesting potential of an optimized designed that takes advantage of the whole pipe is calculated using the validated computational model, resulting in 30.8 MWh of energy harvested during a sample year which could meet the demand of 8.34 Spanish average households.
Open Access
Enhanced behaviour of a passive thermoelectric generator with phase change heat exchangers and radiative cooling
(Elsevier, 2023) Astrain Ulibarrena, David; Jaramillo-Fernández, Juliana; Araiz Vega, Miguel; Francone, Achille; Catalán Ros, Leyre; Jacobo-Martín, Alejandra; Alegría Cía, Patricia; Sotomayor-Torres, Clivia M.; Ingeniería; Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Heat exchangers are essential to optimize the efficiency of Thermoelectric Generators (TEGs), and heat pipes without fans have proven to be an advantageous design as it maintains the characteristic robustness of thermoelectricity, low maintenance and lack of moving parts. However, the efficiency of these heat exchangers decreases under natural convection conditions, reducing their heat transfer capacity and thus thermoelectric power production. This work reports on a novel heat exchanger that combines for the first time, phase change and radiative cooling in a thermoelectric generator to improve its efficiency and increase the production of electrical energy, specially under natural convection. For this, two thermoelectric generators with heat-pipes on their cold sides have been tested: one with the radiative coating and the other without it. Their thermal resistances have been determined and the electric power output was compared under different working conditions, namely, natural convection and forced convection indoors and outdoors. The experimental tests show a clear reduction of the heat exchanger thermal resistance thanks to the radiative coating and consequently, an increase of electric production 8.3 % with outdoor wind velocities of 1 m/s, and up to 54.8 % under free convection conditions. The application of the radiative surface treatment is shown to result in a more stable electrical energy production, suppressing the drastic decrease in the generated electric power that occurs in thermoelectric generators when they work under free convection.
Open Access
Prospects of autonomous volcanic monitoring stations: experimental investigation on thermoelectric generation from fumaroles
(MDPI, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Padilla, Germán D.; Hernández, Pedro A.; Pérez, Nemesio M.; García de la Noceda, Celestino; Albert, José F.; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 °C. Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 °C. The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 °C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(2021) Alegría Cía, Patricia; Rodríguez García, Antonio; Catalán Ros, Leyre; Astrain Ulibarrena, David; Araiz Vega, Miguel; Ingeniería; Institute of Smart Cities - ISC; Ingeniaritza
Nowadays, geothermal energy in shallow hot dry rocks is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
400 W facility of geothermal thermoelectric generators from hot dry rocks on the Canary Islands
(Elsevier, 2025-06-01) Alegría Cía, Patricia; Pascual Lezaun, Nerea; Catalán Ros, Leyre; Araiz Vega, Miguel; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Geothermal energy has a great potential to be harnessed and requires a boost in technologies to enhance its use. The Canary Islands have a great dependence on fossil fuels, and Lanzarote has important geothermal anomalies currently unexploited due to the absence of water in the soil, what hinders the use of vapour turbines. This work presents the development of the first facility of geothermal thermoelectric generators operating in the world. This novel generators are producing 400 W of power in Timanfaya National Park. It has three geothermal thermoelectric generators, each with 4 thermosyphons per borehole and 40 thermoelectric modules that directly transform heat into electricity. This facility, with the advantages of geothermal energy such as continuity and independence on the weather, requires low maintenance because it does not require moving parts nor water consumption. That makes feasible for the first time to harness the geothermal potential in Lanzarote, producing an electric energy of 9.4 kWh per day, which means 3.42 MWh per year. The field installation of this novel technology has enabled to accurately calculate the Levelized Cost of Energy, which is 0.22 €/kWh. Although a 29% decrease in the power generated by thermoelectric module was detected when installing a GTEG with 40 modules with respect to a GTEG with 10 modules, this decrease is compensated by the fact that by installing more modules, the electrical production per borehole is optimized, reducing the LCOE. The developed facility will avoid the emission of 2.3 tons of CO2 and is totally respectful with the environment if compared to conventional geothermal power plants.
Open Access
Experimental development of a novel thermoelectric generator without moving parts to harness shallow hot dry rock fields
(Elsevier, 2022) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Rodríguez García, Antonio; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Nowadays, geothermal energy in shallow hot dry rock fields is not exploited enough due to the high economic and environmental impact as well as the lack of scalability of the existing technologies. Here, thermoelectricity has a great future potential due to its robustness, absence of moving parts and modularity. However, the efficiency of a thermoelectric generator depends highly on the heat exchangers. In this work, a novel geothermal thermoelectric generator is experimentally developed, characterizing different configurations of biphasic heat exchangers to obtain low thermal resistances that allow the maximum efficiency in the thermoelectric modules. As a result, robust and passive heat exchangers were obtained with thermal resistances of 0.07 K/W and 0.4 K/W in the hot and cold sides, respectively. The geothermal thermoelectric generator was built with the most effective heat exchangers and was experimented under different temperature and convection conditions, generating 36 W (17 W by a prototype with 10 modules and 19 W by a prototype with 6 modules) for a temperature difference of 160 °C between the heat source and the environment. Furthermore, the experimental development showed that it is possible to increase electricity generation with a more compact generator, since a decrease in the number of modules from 10 to 6 increases the efficiency from 3.72% to 4.06%. With this research, the feasibility of a novel and robust geothermal thermoelectric generator whose working principle is phase change has been experimentally demonstrated, as well as the importance of compactness to maximize its efficiency and thus, power generation.
Open Access
Corrosion behavior in volcanic soils: in search of candidate materials for thermoelectric devices
(MDPI, 2021-12-21) Berlanga Labari, Carlos; Catalán Ros, Leyre; Palacio, José F.; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Institute for Advanced Materials and Mathematics - INAMAT2
Thermoelectric generators have emerged as an excellent solution for the energy supply of volcanic monitoring stations due to their compactness and continuous power generation. Nevertheless, in order to become a completely viable solution, it is necessary to ensure that their materials are able to resist in the acidic environment characteristic of volcanoes. Hence, the main objective of this work is to study the resistance to corrosion of six different metallic materials that are candidates for use in the heat exchangers. For this purpose, the metal probes have been buried for one year in the soil of the Teide volcano (Spain) and their corrosion behavior has been evaluated by using different techniques (OM, SEM, and XRD). The results have shown excessive corrosion damage to the copper, brass, and galvanized steel tubes. After evaluating the corrosion behavior and thermoelectric performance, AISI 304 and AISI 316 stainless steels are proposed for use as heat exchangers in thermoelectric devices in volcanic environments.
Open Access
Role of student associations in the acquisition of competences in university engineering programs
(IEEE, 2023) Samanes Pascual, Javier; Parra Laita, Íñigo de la; Berrueta Irigoyen, Alberto; Rosado Galparsoro, Leyre; Soto Cabria, Adrián; Elizondo Martínez, David; Catalán Ros, Leyre; Sanchis Gúrpide, Pablo; Institute of Smart Cities - ISC
Students in the STEM field (Science, Technology, Engineering and Mathematics), do not only require deep technical knowledge, but a complete set of global skills related to management, teamwork, lifelong learning, personal development, communications skills or proactiveness, abilities often referred as soft-skills. Student-led organizations, and specifically, university student associations, are one of the best alternatives to promote the acquisition of soft-skills in STEM high education fields. These skills are competences already included in official university programs that can hardly be addressed or acquired from traditional university education. This article studies how student enrollment in student led organizations (SLOs), with an active participation on their organization and activities, allows engineering students to achieve a better development of these soft skills. As case study, a medium size university, with 9000-students and eleven SLOs, six of them focused on STEM related fields, is used in this paper. A survey is conducted among the university community to identify their degree of participation in SLOs, and to test whether participation in these initiatives increases students' self-perception of their soft skill acquisition during their university studies. This survey shows how students of engineering programs, with a high degree of involvement in SLOs, demonstrated greater confidence in their soft skills at the end of their university years.
Open Access
New opportunities for electricity generation in shallow hot dry rock fields: a study of thermoelectric generators with different heat exchangers
(Elsevier, 2019) Catalán Ros, Leyre; Aranguren Garacochea, Patricia; Araiz Vega, Miguel; Pérez Artieda, Miren Gurutze; Astrain Ulibarrena, David; Institute of Smart Cities - ISC
Despite being one of the largest renewable sources, geothermal energy is not widely utilized for electricity generation. In order to leverage shallow hot dry rock (HDR) fields, the present paper proposes an alternative to enhanced geothermal systems (EGS): thermoelectric generators. Based on the conditions of Timanfaya National Park, a prototype has been built to experimentally analyze the feasibility of the proposed solution. The prototype is composed by a two phase closed thermosyphon (TPCT) as hot side heat exchanger, two thermoelectric modules, and it considers different cold side heat exchangers: fin dissipators assisted by a fan and loop thermosyphons, both with various geometries. Experiments have demonstrated that loop thermosyphons represent the best alternative due to their low thermal resistance and, especially, due to their lack of auxiliary consumption, leading to a maximum net power generation of 3.29 W per module with a temperature difference of 180 °C (200 °C in the hot side and 20 °C as ambient temperature), 54% more than with fin dissipators. Hence, there exists a new opportunity for electricity generation in shallow hot dry rock fields: thermoelectric generators with biphasic thermosyphons as heat exchangers, a patented and robust solution.