Open Access
Prospects of autonomous volcanic monitoring stations: experimental investigation on thermoelectric generation from fumaroles
(MDPI, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Padilla, Germán D.; Hernández, Pedro A.; Pérez, Nemesio M.; García de la Noceda, Celestino; Albert, José F.; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 °C. Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 °C. The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 °C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.
Open Access
Computational study of geothermal thermoelectric generators with phase change heat exchangers
(Elsevier, 2020) Catalán Ros, Leyre; Araiz Vega, Miguel; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
The use of thermoelectric generators with phase change heat exchangers has demonstrated to be an interesting and environmentally friendly alternative to enhanced geothermal systems (EGS) in shallow hot dry rock fields (HDR), since rock fracture is avoided. The present paper studies the possibilities of the former proposal in a real location: Timanfaya National Park (Canary Islands, Spain), one of the greatest shallow HDR fields in the world, with 5000 m2 of characterized geothermal anomalies presenting temperatures up to 500 °C at only 2 m deep. For this purpose, a computational model based on the thermal-electrical analogy has been developed and validated thanks to a real prototype, leading to a relative error of less than 8%. Based on this model, two prototypes have been designed and studied for two different areas within the park, varying the size of the heat exchangers and the number of thermoelectric modules installed. As a result, the potential of the solution is demonstrated, leading to an annual electricity generation of 681.53 MWh thanks to the scalability of thermoelectric generators. This generation is obtained without moving parts nor auxiliary consumption, thus increasing the robustness of the device and removing maintenance requirements.
Open Access
Experimental evidence of the viability of thermoelectric generators to power volcanic monitoring stations
(MDPI, 2020) Catalán Ros, Leyre; Garacochea Sáenz, Amaia; Casi Satrústegui, Álvaro; Araiz Vega, Miguel; Aranguren Garacochea, Patricia; Astrain Ulibarrena, David; Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería
Although there is an important lack of commercial thermoelectric applications mainly due to their low efficiency, there exist some cases in which thermoelectric generators are the best option thanks to their well-known advantages, such as reliability, lack of maintenance and scalability. In this sense, the present paper develops a novel thermoelectric application in order to supply power to volcanic monitoring stations, making them completely autonomous. These stations become indispensable in any volcano since they are able to predict eruptions. Nevertheless, they present energy supply difficulties due to the absence of power grid, the remote access, and the climatology. As a solution, this work has designed a new integral system composed of thermoelectric generators with high efficiency heat exchangers, and its associated electronics, developed thanks to Internet of Things (IoT) technologies. Thus, the heat emitted from volcanic fumaroles is transformed directly into electricity with thermoelectric generators with passive heat exchangers based on phase change, leading to a continuous generation without moving parts that powers different sensors, the information of which is emitted via LoRa. The viability of the solution has been demonstrated both at the laboratory and at a real volcano, Teide (Canary Islands, Spain), where a compact prototype has been installed in an 82 C fumarole. The results obtained during more than eight months of operation prove the robustness and durability of the developed generator, which has been in operation without maintenance and under several kinds of meteorological conditions, leading to an average generation of 0.49W and a continuous emission over more than 14 km.
Open Access
Design and experimental development of thermoelectric generators for shallow geothermal anomalies of volcanic origin
(2020) Catalán Ros, Leyre; Astrain Ulibarrena, David; Aranguren Garacochea, Patricia; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
En el contexto energético actual, caracterizado por un incesante aumento en el consumo de energía y una gran dependencia de los combustibles fósiles, resulta imprescindible apostar por sistemas eficientes y basados en energías renovables que contribuyan a un mejor aprovechamiento de los recursos y sean respetuosos con el medio ambiente. En este sentido, la energía geotérmica destaca entre otras fuentes renovables por su carácter permanente, al no depender de las condiciones meteorológicas. Sin embargo, su contribución al sistema energético mundial es mínimo, sobre todo en generación de electricidad. Como alternativa a los ciclos que tradicionalmente se emplean para la generación eléctrica geotérmica, esta tesis doctoral propone la utilización de generadores termoeléctricos debido a sus numerosas ventajas tales como fiabilidad, durabilidad y escalabilidad. Concretamente, la tesis se centra en anomalías geotérmicas superficiales de origen volcánico para dos aplicaciones distintas: la generación eléctrica de media escala en yacimientos de roca caliente seca y el abastecimiento autónomo de estaciones de vigilancia volcánica. Dada la importancia de los intercambiadores de calor en la eficiencia total del sistema, en ambas aplicaciones se ha realizado un profundo estudio para determinar qué tipo de intercambiadores de calor son los más adecuados. En ambos casos, se ha demostrado experimentalmente que los intercambiadores de calor más propicios son aquellos basados en el cambio de fase, ya que aparte de presentar bajas esistencias térmicas, no tienen partes móviles ni requieren de equipos auxiliares, minimizando así el mantenimiento. Asimismo, también ha resultado de gran importancia el desarrollo de un modelo computacional rápido y fiable que tenga en cuenta los intercambiadores de calor, la fuente de calor y el sumidero, sin despreciar ningún efecto termoeléctrico, y considerando los contactos térmicos y eléctricos y la influencia de la temperatura en las propiedades. Este modelo, programado en base al método de las diferencias finitas, se ha convertido en una verdadera herramienta de diseño y optimización para las dos aplicaciones objeto de estudio en esta tesis doctoral, gracias a su error relativo menor al 8%. Los resultados derivados de esta tesis doctoral demuestran que la termoelectricidad puede solucionar las problemáticas de generación eléctrica en los yacimientos de roca caliente seca y en las estaciones de monitorización volcánica, dos aplicaciones inéditas de generación termoeléctrica que pueden hacer que esta tecnología se convierta por fin en una realidad en el ámbito civil.

Catalán Ros, Leyre

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