Open Access
Study of the degradation of heat exchanger materials in the acidic environment of Teide National Park
(2019) Catalán Ros, Leyre; Pérez Artieda, Miren Gurutze; Berlanga Labari, Carlos; Garacochea Sáenz, Amaia; Rodríguez García, Antonio; Domínguez, Vidal; Montañez, Ana Carolina; Padilla, Germán D.; Pérez, Nemesio M.; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Institute of Smart Cities - ISC; Ingeniería
Supplying power to volcanic monitoring stations constitutes a challenge due to both the access difficulties and the acidic environment associated with volcanoes. ELECTROVOLCAN project is developing thermoelectric generators that make use of the temperature of the available fumaroles to directly supply electricity to the stations in a robust, compact and reliable way. The main element of thermoelectric generators are the thermoelectric modules, based on Seebeck effect. Nonetheless, since the efficiency of these modules increases with the temperature difference between their sides, the introduction of heat exchangers becomes essential. The present study analyses the behavior of different materials used in the construction of the heat exchangers in the acidic environment of Teide National Park.
Open Access
Thermoelectric generator for high temperature geothermal anomalies: experimental development and field operation
(Elsevier, 2023) Alegría Cía, Patricia; Catalán Ros, Leyre; Araiz Vega, Miguel; Casi Satrústegui, Álvaro; Astrain Ulibarrena, David; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
In the current climate and energy context, it is important to develop technologies that permit increase the use of renewable sources such as geothermal energy. Enhancing the use of this renewable source is particularly important in some places, due to its availability and the enormous dependence on fossil fuels, as is the case of the Canary Islands. This work proposes the use of thermoelectric generators with heat exchangers working by phase change to transform the heat from the shallow high temperature geothermal anomalies on the island of Lanzarote directly into electricity, since the use of conventional geothermal power plants would not be possible because they would damage the protected environment. To bring this proposal to reality, this work has succeeded in developing and field-installing a geothermal thermoelectric generator that operates without moving parts thanks to its phase-change heat exchangers. This robust generator do not require maintenance nor auxiliary consumption, and produces a minimal environmental impact, it is noiseless, and the use of water as working fluid makes it completely harmless. The developed device consists of a thermosyphon as hot side heat exchanger, thermoelectric modules and cold side heat exchangers also based in phase change. Tests were carried out in the laboratory at various heat source temperatures and varying the number of thermoelectric modules. It was determined that installing more modules decreases the efficiency per module (from 4.83% with 4 modules to 4.59% with 8 modules at a temperature difference between sources of 235 °C), but for the number of modules tested the total power increases, so the field installation was carried out with 8 modules. After the good results in the laboratory, it was satisfactorily installed at Timanfaya National Park (Lanzarote, Spain) in a borehole with gases at 465 °C. This generator presents a maximum output power of 36 W (4.5 W per module), and is generating 286.94 kWh per year, demonstrating the great potential of the developed thermoelectric generators to build a larger-scale renewable installation.

Catalán Ros, Leyre

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