Open Access
Electrospinnig of superhydrophobic nanocomposite films for corrosion protection of aluminum substrates
(2019) Iribarren Zabalegui, Álvaro; Rivero Fuente, Pedro J.; Berlanga Labari, Carlos; Escuela Técnica Superior de Ingenieros Industriales y de Telecomunicación; Telekomunikazio eta Industria Ingeniarien Goi Mailako Eskola Teknikoa
In this work, the electrospinning technique is used for the synthesis of micro/nanofibers using a polymeric precursor with hydrophobic (even superhydrophobic) behaviour such as polystyrene (PS) or polyvinyl chloride (PVC). These electrospun fibers are deposited onto aluminum substrates (6061T6). The effect of varying the different electrospinning deposition parameters (mostly applied voltage and flow-rate) will be exhaustively analyzed in order to optimize the resultant electrospun coatings. Several fiber characterization tests have been performed, including Field Emission Scanning Electron Microscopy (FE-SEM), Atomic Force Microscopy (AFM), Thermogravimetric analysis (TGA), Differential Scanning Calorimetry (DSC), Optical Microscopy (OM) and Water Contact Angle (WCA) measurements. Furthermore, the anti-corrosion properties of these electrospun coatings can be enhanced by the addition of metal oxide nanoparticles (ZnO) that act as corrosion inhibitors. Finally, electrochemical corrosion tests (Tafel and pitting tests) have been performed, showing an improvement in the resultant corrosion resistance of the aluminum alloys coated by the combination of both polymeric films with metal oxide inorganic nanoparticles.
Open Access
Asymmetrical firing angle modulation for 12-pulse thyristor rectifiers supplying high-power electrolyzers
(IEEE, 2023) Iribarren Zabalegui, Álvaro; Barrios Rípodas, Ernesto; Elizondo Martínez, David; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
This paper presents an asymmetrical firing angle modulation strategy for 12-pulse thyristor rectifiers aimed at supplying high-power electrolyzers, which allows to reduce the size of the passive filter and the static compensator (STATCOM) required to comply with grid harmonic regulations and achieve unity power factor. Usually, 12-pulse thyristor rectifiers follow a symmetric modulation strategy in which the same firing angle is applied to both 6-pulse bridges. In this case, large passive ac-side inductances are required to reduce grid current harmonics, which increase the reactive power consumption and thus the required STATCOM size. However, this paper demonstrates that by applying different firing angles to the two 6-pulse bridges it is possible to comply with the harmonic regulation limits using smaller filtering inductances and therefore reducing the STATCOM size. The methodology to find the optimal firing angle values that should be applied in order to minimize the filtering inductance and the STATCOM size for a given electrolyzer is explained. This strategy is validated by simulation, and results show that the required filtering inductance and the apparent power of the STATCOM can be effectively reduced by 62% and 31%, respectively, using this asymmetrical firing angle modulation.
Open Access
Dynamic modeling and simulation of a pressurized alkaline water electrolyzer: a multiphysics approach
(IEEE, 2021) Iribarren Zabalegui, Álvaro; Barrios Rípodas, Ernesto; Ibaiondo, Harkaitz; Sánchez Ruiz, Alain; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación
In this paper a dynamic model for the simulation of pressurized alkaline water electrolyzers is presented. The model has been developed following a multiphysics approach, integrating electrochemical, thermodynamic, heat transfer and gas evolution processes in order to faithfully reproduce the complete dynamical behavior of these systems. The model has been implemented on MATLAB/Simulink and validated through experimental data from a 1 Nm3h-1 commercial alkaline water electrolyzer, and the simulated results have been found to be consistent with the real measured values. This model has a great potential to predict the behavior of alkaline water electrolyzers coupled with renewable energy sources, making it a very useful tool for designing efficient green hydrogen production systems.
Open Access
On the impact of high-power grid-connected thyristor rectifiers on the efficiency of hydrogen electrolyzers
(IEEE, 2024-08-30) Iribarren Zabalegui, Álvaro; Barrios Rípodas, Ernesto; Rivera, Marco; Wheeler, Patrick; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
This paper investigates the impact of power supply and dc current ripple on the efficiency of water electrolyzers and demonstrates that optimally sized thyristor rectifiers meeting grid power quality regulations can effectively supply high-power electrolyzers with minimal impact on electrolyzer efficiency. Firstly, an equivalent electrical model for the electrolyzer is developed, and the efficiency reduction caused by dc current ripple is analyzed. This is validated by means of experimental data from a 5-kW alkaline electrolyzer operated with both thyristor- and IGBT-based rectifiers. Next, the paper explores the operation of high-power electrolyzers supplied by 6- and 12-pulse thyristor rectifiers complying with grid power quality standards. Results show that with optimal sizing of ac-side source voltage and filtering inductances, these solutions exhibit negligible dc current ripple impact on electrolyzer efficiency. These findings, validated through simulation of a 5.5 MW electrolyzer, highlight the viability of thyristor rectifiers in high-power electrolysis applications, and emphasize the importance of an optimal power supply design and sizing for enhancing water electrolyzers' performance.
Open Access
Multifunctional protective PVC-ZnO nanocomposite coatings deposited on aluminum alloys by electrospinning
(MDPI, 2019) Iribarren Zabalegui, Álvaro; Rivero Fuente, Pedro J.; Berlanga Labari, Carlos; Larumbe Abuin, Silvia; Miguel, Adrián; Rodríguez Trías, Rafael; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, PRO-UPNA 18 (6107)
This paper reports the use of the electrospinning technique for the synthesis of nanocomposite micro/nanofibers by combining a polymeric precursor with hydrophobic behavior like polyvinyl chloride (PVC) with nanoparticles of a corrosion inhibitor like ZnO. These electrospun fibers were deposited on substrates of the aluminum alloy 6061T6 until forming a coating around 100 m. The effect of varying the different electrospinning deposition parameters (mostly applied voltage and flow-rate) was exhaustively analyzed in order to optimize the coating properties. Several microscopy and analysis techniques have been employed, including optical microscopy (OM), field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Water contact angle (WCA) measurements have been carried out in order to corroborate the coating hydrophobicity. Finally, their corrosion behavior has been evaluated by electrochemical tests (Tafel curves and pitting potential measurements), showing a relevant improvement in the resultant corrosion resistance of the coated aluminum alloys.
Open Access
Dynamic modeling of a pressurized alkaline water electrolyzer: a multiphysics approach
(IEEE, 2023) Iribarren Zabalegui, Álvaro; Elizondo Martínez, David; Barrios Rípodas, Ernesto; Ibaiondo, Harkaitz; Sánchez Ruiz, Alain; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
In this paper a dynamic model for the simulation of pressurized alkaline water electrolyzers is presented. The model has been developed following a multiphysics approach, integrating electrochemical, thermodynamic, heat transfer and gas evolution processes in order to faithfully reproduce the complete dynamical behavior of these systems. The model has been implemented on MATLAB/Simulink and validated through experimental data from a 1 Nm3/h commercial alkaline water electrolyzer. Validations have been performed under real scenarios where the electrolyzer is working with power profiles characteristic from renewable sources, wind and photovoltaic. The simulated results have been found to be consistent with the real measured values. This model has a great potential to predict the behavior of alkaline water electrolyzers coupled with renewable energy sources, making it a very useful tool for designing efficient green hydrogen production systems.
Open Access
Integration of second-life battery packs for self-consumption applications: analysis of a real experience
(IEEE, 2021) Soto Cabria, Adrián; Berrueta Irigoyen, Alberto; Zorrilla, Pablo; Iribarren Zabalegui, Álvaro; Castillo, Diego H.; Rodríguez Rodríguez, Wenceslao Eduardo; Rodríguez, Adolfo J.; Vargas Requena, Dávid Tomás; Matías Maestro, Ignacio; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren; Institute of Smart Cities - ISC; Ingeniería Eléctrica, Electrónica y de Comunicación; Gobierno de Navarra / Nafarroako Gobernua, 0011–1411–2018–000029 GERA; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, ReBMS PJUPNA1904
This contribution presents a methodology for the integration of Li-ion batteries discarded from electric vehicle into a collective self-consumption installation, showing the technical feasibility of such battery second use. In this regard, the state of charge (SOC) estimation is a relevant issue for the energy management of the second-life battery. Therefore, a SOC estimator is proposed in this contribution and tested in field. Moreover, the revealed costs analysis allows an economic comparison between the integration of a discarded battery pack in a second-life application or a remanufacture of these packs, thereby selecting the most suitable cells to build second-life batteries. This is a crucial issue for companies focused on the development of second-life batteries. The results obtained after testing the second-life battery pack in a real installation make it possible to extol the benefits of including this type of batteries in a self-consumption system, reaching a self-consumption ratio of 69 % and reducing by 36 % the maximum power peak demanded from the grid.
Open Access
Modelling and operation of 6-pulse thyristor rectifiers for supplying high power electrolyzers
(IEEE, 2022) Iribarren Zabalegui, Álvaro; Barrios Rípodas, Ernesto; Ibaiondo, Harkaitz; Sánchez Ruiz, Alain; Arza, Joseba; Sanchis Gúrpide, Pablo; Ursúa Rubio, Alfredo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
This paper presents a detailed analysis of a 6-pulse thyristor rectifier aimed at supplying high power electrolyzers. For this purpose, an analytical model of the three-phase controlled rectifier with AC-side inductance and constant-voltage load has been developed. The different operating modes are identified and characterized. The derived equations are then combined with the electrical model of the electrolyzer, which allows to predict the operating point of the system. This model may serve as a useful tool for dimensioning thyristor rectifiers when operating with high power electrolyzers.
Open Access
A comparative study of multifunctional coatings based on electrospun fibers with incorporated ZnO nanoparticles
(MDPI, 2019) Rivero Fuente, Pedro J.; Iribarren Zabalegui, Álvaro; Larumbe Abuin, Silvia; Rodríguez Trías, Rafael; Ingeniaritza; Institute for Advanced Materials and Mathematics - INAMAT2; Ingeniería; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa, PRO-UPNA 18 (6107)
In this work, polymeric fibers of polystyrene (PS) with incorporated ZnO nanoparticles have been deposited onto an aluminum alloy substrate (6061T6) by using the electrospinning technique. In order to optimize the deposition process, the applied voltage and flow rate have been evaluated in order to obtain micrometric electrospun fibers with a high average roughness and superhydrophobic behavior. Thermogravimetric analysis (TGA) has also been employed in order to corroborate the amount of ZnO incorporated into the electrospun fibers, whereas differential scanning calorimetry (DSC) has been performed in order to determine the glass transition temperature (Tg) of the polymeric electrospun fibers. In addition, a specific thermal treatment (Tg + 20 °C) of the synthesized electrospun fibers has been evaluated in the resultant corrosion resistance. A comparative study with previously reported results corresponding to polyvinyl chloride (PVC) fibers is carried out along this paper to show the changes in behavior due to the different compositions and fiber diameters. The coating has produced an important reduction of the corrosion current of the aluminum substrate in two orders of magnitude, showing also an important enhancement against pitting corrosion resistance. Finally, this deposition technique can be used as an innovative way for the design of both superhydrophobic and anticorrosive surfaces in one unique step over metallic substrates with arbitrary geometry.