Valorisation of red mud: disclosing the potential of an abundant residue

Date

2025-02-21

Authors

Vielma, Carlos A.
Svobodova-Sedlackova, Adela
Chimenos, Josep Maria
Fernández, A. Inés
Barreneche, Camila

Director

Publisher

MDPI
Acceso abierto / Sarbide irekia
Artículo / Artikulua
Versión publicada / Argitaratu den bertsioa

Project identifier

  • Gobierno de Navarra//0011-3998-2021-000006/
Impacto
Google Scholar
No disponible en Scopus

Abstract

Red mud (RM), the primary waste product of the aluminium industry, is notable for its high concentrations of metals and rare earth elements (REE). Efforts have been made to develop extraction methods for REE recovery from RM, aiming to enhance its valorisation and reduce the European reliance on external REE sources—particularly crucial for technological advancements and the transition to renewable energy. However, these methods have only been limited to low technology readiness levels (TRLs), with no economically or technically viable processing routes yet defined to enable large-scale industrialisation within a circular economy model. This study characterised RM samples from the Seydişehir region in Türkiye using different techniques and explored the experimental process for recovering metals and REE. Moreover, the study assessed the global prospective potential of RM based on technical and economic data, as well as the sustainability of the implemented process through the life cycle assessment (LCA) tool. Results showed a total REE concentration of up to 1600 ppm, with Ce, being the most abundant (426 ± 27 ppm), followed by La, Nd, and Sc. Concentration efficiencies for La and Nd ranged between 240–300%. Sc, Y, Ce, La, and Nd have significant usage in European markets and represent prime RM targets for further prospecting. The LCA revealed that the highest global warming potential of the sequential extraction process was attributed to hydroxylamine hydrochloride and hydrogen peroxide. The findings highlight the need to explore alternative, more eco-friendly reagents to improve RM valorisation.

Description

Keywords

Rare earth elements (REE), Red mud (RM), Sequential extraction, Prospectivity, Sustainability

Department

Ingeniería / Ingeniaritza / Institute for Advanced Materials and Mathematics - INAMAT2

Faculty/School

Degree

Doctorate program

item.page.cita

Vielma, C. A., Svobodova-Sedlackova, A., Chimenos, J. M., Fernández, A. I., Berlanga, C., Rodriguez, R., Barreneche, C. (2025) Valorisation of red mud: disclosing the potential of an abundant residue. Sustainability, 17(5), 1-24. https://doi.org/10.3390/su17051849.

item.page.rights

© 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.

Licencia

Los documentos de Academica-e están protegidos por derechos de autor con todos los derechos reservados, a no ser que se indique lo contrario.